Skip to main content
Top
Published in: Environmental Earth Sciences 20/2016

01-10-2016 | Original Article

Multi-methodological approach to evaluate trace elements and major components in wetland system with subsaline and freshwater characteristics

Authors: Vlado Cuculić, Stanislav Frančišković-Bilinski, Halka Bilinski, Krešimir Maldini, Damir Tomas, Nenad Tomašić

Published in: Environmental Earth Sciences | Issue 20/2016

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

In this study, the present status of the transboundary wetlands in Central Europe was evaluated using complementary experimental and statistical methods. Detailed characterization of the complex, subsaline/freshwater system in this study is aimed to be the contribution to the global wetland inventory. The distribution and behaviour of major and trace elements in water from the Neusiedler Lake Basin (Austria) were investigated. Two water types were proposed: CaNaHCO3 and CaHCO3. Toxic metals were discussed in comparison with the sediment quality criteria, and Ni was above the value that might cause severe toxic effects. TOC/TN ratio in sediments suggested terrestrial origin of organic matter. Significant variation of trace elements in water was noticed among the sampling sites. Although the Wulka River was anthropogenically influenced, only dissolved Zn, As and U were above world average values. This was the consequence of precipitation and metal adsorption onto suspended particles. Cd, Zn, Mn and Fe were the highest in acidic spring, where low pH maintains metals in a dissolved form. Uranium amounts near closed coalmine exceeded maximum allowed concentration (20 µg L−1). Majority of elements in water and sediment have normal statistical distribution, with a small number of anomalies, thus indicating moderate anthropogenic influence.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
go back to reference Ágoston-Szabó E, Dinka M (2006) Changes in sediment and sediment interstitial water characteristics in Lake Fertő/Neusiedler See. Opusc Zool 35:3–17 Ágoston-Szabó E, Dinka M (2006) Changes in sediment and sediment interstitial water characteristics in Lake Fertő/Neusiedler See. Opusc Zool 35:3–17
go back to reference Ágoston-Szabó E, Dinka M (2009) Some characteristics of the sediments of healthy and degraded reed stands at Lake Fertő/Neusiedler See. Opusc Zool 40:5–15 Ágoston-Szabó E, Dinka M (2009) Some characteristics of the sediments of healthy and degraded reed stands at Lake Fertő/Neusiedler See. Opusc Zool 40:5–15
go back to reference Ascherson P (1865) The drying up of Lake Neusiedl. Miscellen—Zeitschrift für allgemeine Erdkunde—N.F 19:278–281 (in German) Ascherson P (1865) The drying up of Lake Neusiedl. Miscellen—Zeitschrift für allgemeine Erdkunde—N.F 19:278–281 (in German)
go back to reference Becker R, Buge H-G, Bremser W, Nehls I (2006) Mineral oil content in sediments and soils: comparability, traceability and a certified reference material for quality assurance. Anal Bioanal Chem 385:645–651CrossRef Becker R, Buge H-G, Bremser W, Nehls I (2006) Mineral oil content in sediments and soils: comparability, traceability and a certified reference material for quality assurance. Anal Bioanal Chem 385:645–651CrossRef
go back to reference Bilinski H, Kozar S, Plavšić M, Kwokal Ž, Branica M (1991) Trace-metal adsorption on inorganic solid-phases under estuarine conditions. Mar Chem 32:225–233CrossRef Bilinski H, Kozar S, Plavšić M, Kwokal Ž, Branica M (1991) Trace-metal adsorption on inorganic solid-phases under estuarine conditions. Mar Chem 32:225–233CrossRef
go back to reference Boldrin A, Juračić M, Menagazzo V, Rabitti S, Rampazzo G (1992) Sedimentation of riverborne material in a shallow shelf sea: adige River, Adriatic Sea. Mar Geol 103:473–485CrossRef Boldrin A, Juračić M, Menagazzo V, Rabitti S, Rampazzo G (1992) Sedimentation of riverborne material in a shallow shelf sea: adige River, Adriatic Sea. Mar Geol 103:473–485CrossRef
go back to reference Bordowsky OK (1965) Accumulation of organic matter in bottom sediments. Mar Geol 3:33–82CrossRef Bordowsky OK (1965) Accumulation of organic matter in bottom sediments. Mar Geol 3:33–82CrossRef
go back to reference Canada Health (2009) Guidelines for Canadian drinking water quality: guideline technical document—radiological parameters. Radiation Protection Bureau, Healthy Environments and Consumer Safety Branch, Health Canada, Ottawa Canada Health (2009) Guidelines for Canadian drinking water quality: guideline technical document—radiological parameters. Radiation Protection Bureau, Healthy Environments and Consumer Safety Branch, Health Canada, Ottawa
go back to reference Casiot C, Egal M, Bruneel O, Bancon-Montigny C, Cordier MA et al (2009) Hydrological and geochemical controls on metals and arsenic in a Mediterranean river contaminated by acid mine drainage (the Amous river, France); preliminary assessment of impacts on fish (Leuciscus cephalus). Appl Geochem 24:787–799CrossRef Casiot C, Egal M, Bruneel O, Bancon-Montigny C, Cordier MA et al (2009) Hydrological and geochemical controls on metals and arsenic in a Mediterranean river contaminated by acid mine drainage (the Amous river, France); preliminary assessment of impacts on fish (Leuciscus cephalus). Appl Geochem 24:787–799CrossRef
go back to reference Cuculić V, Branica M (1996) Trace metals adsorption from seawater onto solid surfaces: analysis by anodic stripping voltammetry. Analyst 121:1127–1131CrossRef Cuculić V, Branica M (1996) Trace metals adsorption from seawater onto solid surfaces: analysis by anodic stripping voltammetry. Analyst 121:1127–1131CrossRef
go back to reference Cuculić V, Cukrov N, Kwokal Ž, Mlakar M (2009) Natural and anthropogenic sources of Hg, Cd, Pb, Cu and Zn in seawater and sediment of Mljet National Park, Croatia. Estuar Coast Shelf Sci 81:311–320CrossRef Cuculić V, Cukrov N, Kwokal Ž, Mlakar M (2009) Natural and anthropogenic sources of Hg, Cd, Pb, Cu and Zn in seawater and sediment of Mljet National Park, Croatia. Estuar Coast Shelf Sci 81:311–320CrossRef
go back to reference Cukrov N, Cmuk P, Mlakar M, Omanović D (2008) Spatial distribution of trace metals in the Krka river, Croatia. Ex Self-Purif. Chemos 72:1559–1566 Cukrov N, Cmuk P, Mlakar M, Omanović D (2008) Spatial distribution of trace metals in the Krka river, Croatia. Ex Self-Purif. Chemos 72:1559–1566
go back to reference Eitzinger J, Kubu G, Formayer H, Haas P, Gerersdorfer T et al (2009) Impacts of climate change on the water balance of Lake Neusiedl. Final report on behalf of the Office of the Burgenland government-county Schützen am Gebirge. Institute of Meteorology (BOKU-Met) Department of Water—Atmosphere—Environment, University of Agricultural Sciences, Vienna (in German) Eitzinger J, Kubu G, Formayer H, Haas P, Gerersdorfer T et al (2009) Impacts of climate change on the water balance of Lake Neusiedl. Final report on behalf of the Office of the Burgenland government-county Schützen am Gebirge. Institute of Meteorology (BOKU-Met) Department of Water—Atmosphere—Environment, University of Agricultural Sciences, Vienna (in German)
go back to reference Environmental Protection Agency (1998) Method 1664, revision A. n-Hexane extractable material (HEM; oil and grease) and silica gel treated n-hexane extractable material by extraction and gravimetry. EPA-821-R-98-002. US Environmental Protection Agency, Washington, DC Environmental Protection Agency (1998) Method 1664, revision A. n-Hexane extractable material (HEM; oil and grease) and silica gel treated n-hexane extractable material by extraction and gravimetry. EPA-821-R-98-002. US Environmental Protection Agency, Washington, DC
go back to reference Finlayson CM (2003) The challenge of integrating wetland inventory, assessment and monitoring. Freshw Ecosyst 13:281–286CrossRef Finlayson CM (2003) The challenge of integrating wetland inventory, assessment and monitoring. Freshw Ecosyst 13:281–286CrossRef
go back to reference Finlayson CM, Davidson NC, Spiers AG, Stevenson NJ (1999) Global wetland inventory—current status and future priorities. Mar Freshw Res 50:717–727CrossRef Finlayson CM, Davidson NC, Spiers AG, Stevenson NJ (1999) Global wetland inventory—current status and future priorities. Mar Freshw Res 50:717–727CrossRef
go back to reference Frančišković-Bilinski S, Cuculić V, Bilinski H, Häusler H, Stadler P (2013) Geochemical and stable isotopic variability within two rivers rising under the same mountain, but belonging to two distant watersheds. Chemie der Erde-Geochem 73:293–308CrossRef Frančišković-Bilinski S, Cuculić V, Bilinski H, Häusler H, Stadler P (2013) Geochemical and stable isotopic variability within two rivers rising under the same mountain, but belonging to two distant watersheds. Chemie der Erde-Geochem 73:293–308CrossRef
go back to reference Gaillardet J, Viers J, Dupre B (2003) Trace elements in river waters. In: Holland HD, Turekian KK (eds) Treatise on geochemistry: surface and ground water, weathering, and soils. Elsevier, Amsterdam, pp 225–272CrossRef Gaillardet J, Viers J, Dupre B (2003) Trace elements in river waters. In: Holland HD, Turekian KK (eds) Treatise on geochemistry: surface and ground water, weathering, and soils. Elsevier, Amsterdam, pp 225–272CrossRef
go back to reference Guagliardi I, Apollaro C, Scarciglia F, De Rosa R (2013) Influence of particle-size on geochemical distribution of stream sediments in the Lese river catchment, southern Italy. Biotechnol Agron Soc Environ 17(1):43–55 Guagliardi I, Apollaro C, Scarciglia F, De Rosa R (2013) Influence of particle-size on geochemical distribution of stream sediments in the Lese river catchment, southern Italy. Biotechnol Agron Soc Environ 17(1):43–55
go back to reference Gulia L, Guidi M, Bonadonna FP, Macera P (2004) A preliminary geochemical study of two cores from Massaciuccoli eutrophic lake, Northern Tuscany, and paleoclimatic implications. Atti Soc Tosc Sci Nat Mem Serie A 109:97–102 Gulia L, Guidi M, Bonadonna FP, Macera P (2004) A preliminary geochemical study of two cores from Massaciuccoli eutrophic lake, Northern Tuscany, and paleoclimatic implications. Atti Soc Tosc Sci Nat Mem Serie A 109:97–102
go back to reference Hagras MA (2013) Water quality assessment and hydrochemical characteristics of groundwater in Punjab, Pakistan. Int J Res Rev Appl Sci 16:254–262 Hagras MA (2013) Water quality assessment and hydrochemical characteristics of groundwater in Punjab, Pakistan. Int J Res Rev Appl Sci 16:254–262
go back to reference Häusler H (1992) Research report 16: water resources study for the lake neusiedl with the help of geophysics and geochemistry report of the research project in the framework of the agreement on scientific and technological cooperation between Austria and Hungary. Technical University Vienna (in German) Häusler H (1992) Research report 16: water resources study for the lake neusiedl with the help of geophysics and geochemistry report of the research project in the framework of the agreement on scientific and technological cooperation between Austria and Hungary. Technical University Vienna (in German)
go back to reference Häusler H, Frank C, Figdor H, Lenhardt W (2007) Geological map of the Republic of Austria 1:50,000—Notes to the sheets of 79 Neusiedl am See, 80 Ungarisch-Altenburg and 109 Pamhagen. Geological Survey of Austria, Vienna (in German) Häusler H, Frank C, Figdor H, Lenhardt W (2007) Geological map of the Republic of Austria 1:50,000—Notes to the sheets of 79 Neusiedl am See, 80 Ungarisch-Altenburg and 109 Pamhagen. Geological Survey of Austria, Vienna (in German)
go back to reference Häusler H, Müllegger C, Körner W, Ottner F, Prohaska T, et al (2014) A new hydrogeological model of charging shallow and deep aquifers in the Lake Neusiedl—Seewinkel region (Northern Burgenland, Austria). In: Reichart G-J (ed) European Geosciences Union, Geophysical Research Abstracts, vol 16, Vienna, April 2014, p 3296. European Geosciences Union, Vienna Häusler H, Müllegger C, Körner W, Ottner F, Prohaska T, et al (2014) A new hydrogeological model of charging shallow and deep aquifers in the Lake Neusiedl—Seewinkel region (Northern Burgenland, Austria). In: Reichart G-J (ed) European Geosciences Union, Geophysical Research Abstracts, vol 16, Vienna, April 2014, p 3296. European Geosciences Union, Vienna
go back to reference Horowitz AJ (1997) Some thoughts on problems associated with various sampling media used for environmental monitoring. Analyst 122:1193–1200CrossRef Horowitz AJ (1997) Some thoughts on problems associated with various sampling media used for environmental monitoring. Analyst 122:1193–1200CrossRef
go back to reference Jayaprakash M, Nagarajan R, Velmurugan PM, Sathiyamoorthy J, Krishnamurthy RR et al (2012) Assessment of trace metal contamination in a historical freshwater canal (Buckingham Canal), Chennai, India. Environ Monit Assess 184:7407–7424CrossRef Jayaprakash M, Nagarajan R, Velmurugan PM, Sathiyamoorthy J, Krishnamurthy RR et al (2012) Assessment of trace metal contamination in a historical freshwater canal (Buckingham Canal), Chennai, India. Environ Monit Assess 184:7407–7424CrossRef
go back to reference Jianfei Y, Xumei M, Yanxin W, Zhide D, Leihui H (2014) Geochemistry of rare-earth elements in shallow groundwater, northeastern Guangdong province, China. Chin J Geochem 33:53–64CrossRef Jianfei Y, Xumei M, Yanxin W, Zhide D, Leihui H (2014) Geochemistry of rare-earth elements in shallow groundwater, northeastern Guangdong province, China. Chin J Geochem 33:53–64CrossRef
go back to reference Jirsa F, Gruber M, Stojanovic A, Odour Omondi S, Mader D et al (2013) Major and trace element geochemistry of lake Bogoria and lake Nakuru, Kenya, during extreme draught. Chemie der Erde-Geochem 73:275–282CrossRef Jirsa F, Gruber M, Stojanovic A, Odour Omondi S, Mader D et al (2013) Major and trace element geochemistry of lake Bogoria and lake Nakuru, Kenya, during extreme draught. Chemie der Erde-Geochem 73:275–282CrossRef
go back to reference Kim AG, Kazonich G, Dahlberg M (2003) Relative solubility of cations in class F fly ash. Environ Sci Technol 37:4507–4511CrossRef Kim AG, Kazonich G, Dahlberg M (2003) Relative solubility of cations in class F fly ash. Environ Sci Technol 37:4507–4511CrossRef
go back to reference Kogelbauer I, Loiskandl W (2015) Characterization of sediment layer composition in a shallow lake: from open water zones to reed belt areas. Hydrol Earth Syst Sci 19:1427–1438CrossRef Kogelbauer I, Loiskandl W (2015) Characterization of sediment layer composition in a shallow lake: from open water zones to reed belt areas. Hydrol Earth Syst Sci 19:1427–1438CrossRef
go back to reference Krachler R (1992) Contributions to chemistry and water balance of the lakes of the Burgenland side of the lake Seewinkels. Ph.D. thesis, University of Vienna Krachler R (1992) Contributions to chemistry and water balance of the lakes of the Burgenland side of the lake Seewinkels. Ph.D. thesis, University of Vienna
go back to reference Last MW, Ginn FM (2005) Saline systems of the great plains of Western Canada: an overview of the limnogeology and paleolimnology. Saline Systems 1, 10, published online DOI: 10.1186/1746-1448-1-10 Last MW, Ginn FM (2005) Saline systems of the great plains of Western Canada: an overview of the limnogeology and paleolimnology. Saline Systems 1, 10, published online DOI: 10.​1186/​1746-1448-1-10
go back to reference Lenoble V, Omanović D, Garnier C, Mounier S, Đonlagić N et al (2013) Distribution and chemical speciation of arsenic and heavy metals in highly contaminated waters used for health care purposes (Srebrenica, Bosnia and Herzegovina). Sci Total Environ 443:420–428CrossRef Lenoble V, Omanović D, Garnier C, Mounier S, Đonlagić N et al (2013) Distribution and chemical speciation of arsenic and heavy metals in highly contaminated waters used for health care purposes (Srebrenica, Bosnia and Herzegovina). Sci Total Environ 443:420–428CrossRef
go back to reference Manoj K, Ghosh S, Padhy PK (2013) Characterization and classification of hydrochemistry using multivariate graphical and hydrostatistical techniques. Res J Chem Sci 3:32–42 Manoj K, Ghosh S, Padhy PK (2013) Characterization and classification of hydrochemistry using multivariate graphical and hydrostatistical techniques. Res J Chem Sci 3:32–42
go back to reference Matić N, Maldini K, Cuculić V, Frančišković-Bilinski S (2012) Investigations of karstic springs of the Biokovo Mt. from the Dinaric karst of Croatia. Chemie der Erde-Geochem 72:179–190CrossRef Matić N, Maldini K, Cuculić V, Frančišković-Bilinski S (2012) Investigations of karstic springs of the Biokovo Mt. from the Dinaric karst of Croatia. Chemie der Erde-Geochem 72:179–190CrossRef
go back to reference Matić N, Miklavčić I, Maldini K, Tomas D, Cuculić V et al (2013) Geochemical and isotopic characteristics of karstic springs in coastal mountains (Southern Croatia). J Geochem Res 132:90–110 Matić N, Miklavčić I, Maldini K, Tomas D, Cuculić V et al (2013) Geochemical and isotopic characteristics of karstic springs in coastal mountains (Southern Croatia). J Geochem Res 132:90–110
go back to reference Meyers PA (1997) Organic geochemical proxies of paleoceanographic, paleolimnologic, and paleoclimatic processes. Org Geochem 27:213–250CrossRef Meyers PA (1997) Organic geochemical proxies of paleoceanographic, paleolimnologic, and paleoclimatic processes. Org Geochem 27:213–250CrossRef
go back to reference Parnachev VP, Degermendzhy AG (2002) Geographical, geological and hydrochemical distribution of saline lakes in Khakasia, Southern Siberia. Aquat Ecol 36:107–122CrossRef Parnachev VP, Degermendzhy AG (2002) Geographical, geological and hydrochemical distribution of saline lakes in Khakasia, Southern Siberia. Aquat Ecol 36:107–122CrossRef
go back to reference Piller WE, Harzhauser M (2005) The myth of the brackish Sarmatian sea. Terra Nova 17:450–455CrossRef Piller WE, Harzhauser M (2005) The myth of the brackish Sarmatian sea. Terra Nova 17:450–455CrossRef
go back to reference Powder Diffraction File (2004) Database sets 1–54, International Centre for Diffraction Data (ICDD). Newtown Square, Pennsylvania Powder Diffraction File (2004) Database sets 1–54, International Centre for Diffraction Data (ICDD). Newtown Square, Pennsylvania
go back to reference Sampei Y, Matsumoto E (2001) C/N ratios in a sediment core from Nakaumi Lagoon, southwest Japan—usefulness as an organic source indicator. Geochem J 35:189–205CrossRef Sampei Y, Matsumoto E (2001) C/N ratios in a sediment core from Nakaumi Lagoon, southwest Japan—usefulness as an organic source indicator. Geochem J 35:189–205CrossRef
go back to reference SMSP and FALCONBRIDGE NC SAS (2005) Koniambo project, environmental and social impact assessment, Chapter 4 Mine, 4.2–7 Quality criteria for freshwater sediment SMSP and FALCONBRIDGE NC SAS (2005) Koniambo project, environmental and social impact assessment, Chapter 4 Mine, 4.2–7 Quality criteria for freshwater sediment
go back to reference State Archives of Eisenstadt (1963) General topography of the state Burgenland. Eisenstadt (in German) State Archives of Eisenstadt (1963) General topography of the state Burgenland. Eisenstadt (in German)
go back to reference Stojanovic A, Kogelnig D, Mitteregger B, Mader D, Jirsa F et al (2009) Major and trace element geochemistry of superficial sediments and suspended particulate matter of shallow saline lakes in Eastern Austria. Chemie der Erde-Geochem 69:223–234CrossRef Stojanovic A, Kogelnig D, Mitteregger B, Mader D, Jirsa F et al (2009) Major and trace element geochemistry of superficial sediments and suspended particulate matter of shallow saline lakes in Eastern Austria. Chemie der Erde-Geochem 69:223–234CrossRef
go back to reference Todd DK, Mays LW (2005) Groundwater hydrology, 3rd edn. Wiley, New York Todd DK, Mays LW (2005) Groundwater hydrology, 3rd edn. Wiley, New York
go back to reference Tukey JW (1977) Exploratory data analysis. Addison-Wesley, ISBN 0-201-07616-0. OCLC 3058187 Tukey JW (1977) Exploratory data analysis. Addison-Wesley, ISBN 0-201-07616-0. OCLC 3058187
go back to reference Tupas LM, Popp BN, Karl DM (1994) Dissolved organic carbon in oligotrophic waters: experiments on sample preservation, storage and analysis. Mar Chem 45:207–216CrossRef Tupas LM, Popp BN, Karl DM (1994) Dissolved organic carbon in oligotrophic waters: experiments on sample preservation, storage and analysis. Mar Chem 45:207–216CrossRef
go back to reference Ujević M, Duić Z, Casiot C, Sipos L, Santo V et al (2010) Occurrence and geochemistry of arsenic in the groundwater of Eastern Croatia. Appl Geochem 25:1017–1029CrossRef Ujević M, Duić Z, Casiot C, Sipos L, Santo V et al (2010) Occurrence and geochemistry of arsenic in the groundwater of Eastern Croatia. Appl Geochem 25:1017–1029CrossRef
go back to reference Von Eynatten H, Tolosana-Delgado R (2011) Geochemistry versus grain-size relations of sediments in the light of comminution, chemical alteration, and contrasting source rocks. In: Proceedings of the 4th International Workshop on Compositional Data Analysis Von Eynatten H, Tolosana-Delgado R (2011) Geochemistry versus grain-size relations of sediments in the light of comminution, chemical alteration, and contrasting source rocks. In: Proceedings of the 4th International Workshop on Compositional Data Analysis
Metadata
Title
Multi-methodological approach to evaluate trace elements and major components in wetland system with subsaline and freshwater characteristics
Authors
Vlado Cuculić
Stanislav Frančišković-Bilinski
Halka Bilinski
Krešimir Maldini
Damir Tomas
Nenad Tomašić
Publication date
01-10-2016
Publisher
Springer Berlin Heidelberg
Published in
Environmental Earth Sciences / Issue 20/2016
Print ISSN: 1866-6280
Electronic ISSN: 1866-6299
DOI
https://doi.org/10.1007/s12665-016-6156-6

Other articles of this Issue 20/2016

Environmental Earth Sciences 20/2016 Go to the issue