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Published in:
Introduction to 2D Transition Metal Carbides and Nitrides (MXenes) Read chapter Read first chapter

2019 | OriginalPaper | Chapter

25. MXenes for Transparent Conductive Electrodes and Transparent Energy Storage Devices

Authors : Chuanfang (John) Zhang, Valeria Nicolosi

Published in: 2D Metal Carbides and Nitrides (MXenes)

Publisher: Springer International Publishing

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Abstract

The rapid development of portable smart electronics demands advanced components including displays and power sources. Central to these components is the quest of novel materials that can perform well as both transparent conductive electrodes (TCEs) and transparent energy storage devices. This is quite challenging, as the sheet resistance dramatically increases when thinning down the film thickness, leading to poor optoelectronic and electrochemical charge storage properties, known as percolation effects. Producing TCEs without percolation problems is quite crucial for the development of high-performance touch screens, displays, etc. This chapter briefly introduces some typical TCEs, outlines the fundamentals, and focuses on MXenes as potential TCE material. Based on that, this chapter also discusses the fabrication of transparent energy storage devices, specifically transparent solid-state supercapacitors. The excellent optoelectronic properties coupled with impressively performance on capacitive charge storage indicate that MXenes are great candidates for producing state-of-the-art TCEs and transparent energy storage devices.

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previous chapter MXenes for Sensors
next chapter Biomedical Applications of MXenes
Literature
1.
Kim, Y. H., et al. (2015). Self-activated transparent all-graphene gas sensor with endurance to humidity and mechanical bending. ACS Nano, 9, 10453–10460.CrossRef
2.
Bae, S., et al. (2010). Roll-to-roll production of 30-inch graphene films for transparent electrodes. Nature Nanotechnology, 5, 574–578.CrossRef
3.
King, P. J., Higgins, T. M., De, S., Nicoloso, N., & Coleman, J. N. (2012). Percolation effects in supercapacitors with thin, transparent carbon nanotube electrodes. ACS Nano, 6, 1732–1741.CrossRef
4.
Naguib, M., et al. (2011). Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Advanced Materials, 23, 4248–4253.CrossRef
5.
Naguib, M., & Gogotsi, Y. (2015). Synthesis of two-dimensional materials by selective extraction. Accounts of Chemical Research, 48, 128–135.CrossRef
6.
Naguib, M., et al. (2012). Two-dimensional transition metal carbides. ACS Nano, 6, 1322–1331.CrossRef
7.
Ghidiu, M., Lukatskaya, M. R., Zhao, M.-Q., Gogotsi, Y., & Barsoum, M. W. (2014). Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance. Nature, 516, 78–81.CrossRef
8.
Dong, Y., et al. (2017). Metallic MXenes: A new family of materials for flexible triboelectric nanogenerators. Nano Energy, 44, 103–110.CrossRef
9.
Zhang, C. J., et al. (2017). Transparent, Flexible, and Conductive 2D Titanium Carbide (MXene) Films with High Volumetric Capacitance. Advanced Materials, 29, 1702678.CrossRef
10.
Lukatskaya, M. R., et al. (2015). Probing the mechanism of high capacitance in 2D titanium carbide using in situ X-ray absorption spectroscopy. Advanced Energy Materials, 5, 1500589.CrossRef
11.
Yu, L., Shearer, C., & Shapter, J. (2016). Recent development of carbon nanotube transparent conductive films. Chemical Reviews, 116, 13413–13453.CrossRef
12.
De, S., & Coleman, J. N. (2011). The effects of percolation in nanostructured transparent conductors. MRS Bulletin, 36, 774–781.CrossRef
13.
De, S., et al. (2009). Silver nanowire networks as flexible, transparent, conducting films: Extremely high DC to optical conductivity ratios. ACS Nano, 3, 1767–1774.CrossRef
14.
Jiang, S., et al. (2018). Ultrahigh-performance transparent conductive films of carbon-welded isolated single-wall carbon nanotubes. Science Advances, 4, eaap9264.CrossRef
15.
Zheng, Q., Li, Z., Yang, J., & Kim, J.-K. (2014). Graphene oxide-based transparent conductive films. Progress in Materials Science, 64, 200–247.CrossRef
16.
Eda, G., Fanchini, G., & Chhowalla, M. (2008). Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material. Nature Nanotechnology, 3, 270–274.CrossRef
17.
Wu, Z., et al. (2004). Transparent, conductive carbon nanotube films. Science, 305, 1273–1276.CrossRef
18.
Feng, C., et al. (2010). Flexible, stretchable, transparent conducting films made from superaligned carbon nanotubes. Advanced Functional Materials, 20, 885–891.CrossRef
19.
La Notte, L., et al. (2017). Laser-patterned functionalized CVD-graphene as highly transparent conductive electrodes for polymer solar cells. Nanoscale, 9, 62–69.CrossRef
20.
Simien, D., et al. (2008). Influence of nanotube length on the optical and conductivity properties of thin single-wall carbon nanotube networks. ACS Nano, 2, 1879–1884.CrossRef
21.
Becerril, H. A., et al. (2008). Evaluation of solution-processed reduced graphene oxide films as transparent conductors. ACS Nano, 2, 463–470.CrossRef
22.
Hecht, D. S., Hu, L., & Irvin, G. (2011). Emerging transparent electrodes based on thin films of carbon nanotubes, graphene, and metallic nanostructures. Advanced Materials, 23, 1482–1513.CrossRef
23.
De, S., & Coleman, J. N. (2010). Are there fundamental limitations on the sheet resistance and transmittance of thin graphene films? ACS Nano, 4, 2713–2720.CrossRef
24.
De, S., et al. (2010). Flexible, transparent, conducting films of randomly stacked graphene from surfactant-stabilized, oxide-free graphene dispersions. Small, 6, 458–464.CrossRef
25.
De, S., et al. (2009). Transparent, flexible, and highly conductive thin films based on polymer-nanotube composites. ACS Nano, 3, 714–720.CrossRef
26.
Higgins, T. M., & Coleman, J. N. (2015). Avoiding resistance limitations in high-performance transparent supercapacitor electrodes based on large-area, high-conductivity PEDOT:PSS films. ACS Applied Materials & Interfaces, 7, 16495–16506.CrossRef
27.
Lukatskaya, M. R., et al. (2017). Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides. Nature Energy, 2, 17105.CrossRef
28.
Luo, J., et al. (2016). Sn4+ ion decorated highly conductive Ti3C2 MXene: Promising lithium-ion anodes with enhanced volumetric capacity and cyclic performance. ACS Nano, 10, 2491–2499.CrossRef
29.
Naguib, M., et al. (2012). MXene: A promising transition metal carbide anode for lithium-ion batteries. Electrochemistry Communications, 16, 61–64.CrossRef
30.
Xie, X., et al. (2016). Porous heterostructured MXene/carbon nanotube composite paper with high volumetric capacity for sodium-based energy storage devices. Nano Energy, 26, 513–523.CrossRef
31.
Shahzad, F., et al. (2016). Electromagnetic interference shielding with 2D transition metal carbides (MXenes). Science, 353, 1137–1140.CrossRef
32.
Sun, R., et al. (2017). Highly conductive transition metal carbide/carbonitride(MXene)@polystyrene nanocomposites fabricated by electrostatic assembly for highly efficient electromagnetic interference shielding. Advanced Functional Materials, 27, 1702807.CrossRef
33.
Liu, J., et al. (2017). Hydrophobic, flexible, and lightweight MXene foams for high-performance electromagnetic-interference shielding. Advanced Materials, 29, 1702367.CrossRef
34.
Ren, C. E., et al. (2015). Charge- and size-selective ion sieving through Ti3C2Tx MXene membranes. Journal of Physical Chemistry Letters, 6, 4026–4031.CrossRef
35.
Mashtalir, O., et al. (2013). Intercalation and delamination of layered carbides and carbonitrides. Nature Communications, 4, 1716.CrossRef
36.
Halim, J., et al. (2014). Transparent conductive two-dimensional titanium carbide epitaxial thin films. Chemistry of Materials, 26, 2374–2381.CrossRef
37.
Hantanasirisakul, K., et al. (2016). Fabrication of Ti3C2Tx MXene transparent thin films with tunable optoelectronic properties. Advanced Electronic Materials, 2, 1600050.CrossRef
38.
Ali, A., Belaidi, A., Ali, S., Helal, M. I., & Mahmoud, K. A. (2016). Transparent and conductive Ti3C2Tx (MXene) thin film fabrication by electrohydrodynamic atomization technique. Journal of Materials Science: Materials in Electronics, 27, 5440–5445.
39.
Mariano, M., et al. (2016). Solution-processed titanium carbide MXene films examined as highly transparent conductors. Nanoscale, 8, 16371–16378.CrossRef
40.
Dillon, A. D., et al. (2016). Highly conductive optical quality solution-processed films of 2D titanium carbide. Advanced Functional Materials, 26, 4162–4168.CrossRef
41.
Champagne, A., Shi, L., Ouisse, T., Hackens, B., & Charlier, J.-C. (2018). Electronic and vibrational properties of V2C-based MXenes: From experiments to first-principles modeling. Physical Review B, 97, 115439.CrossRef
42.
Ying, G., Kota, S., Dillon, A. D., Fafarman, A. T., & Barsoum, M. W. (2018). Conductive transparent V2CTx (MXene) films. FlatChem, 8, 25–30.CrossRef
43.
Ying, G., Dillon, A. D., Fafarman, A. T., & Barsoum, M. W. (2017). Transparent, conductive solution processed spincast 2D Ti2CTx (MXene) films. Materials Research Letters, 5, 391–398.CrossRef
44.
Miranda, A., Halim, J., Barsoum, M. W., & Lorke, A. (2016). Electronic properties of freestanding Ti3C2Tx MXene monolayers. Applied Physics Letters, 108, 033102.CrossRef
45.
Bruce, P. G., Scrosati, B., & Tarascon, J.-M. (2008). Nanomaterials for rechargeable lithium batteries. Angewandte Chemie International Edition, 47, 2930–2946.CrossRef
46.
Kanninen, P., et al. (2016). Transparent and flexible high-performance supercapacitors based on single-walled carbon nanotube films. Nanotechnology, 27, 235403.CrossRef
47.
Scardaci, V., Coull, R., & Coleman, J. N. (2010). Very thin transparent, conductive carbon nanotube films on flexible substrates. Applied Physics Letters, 97, 023114.CrossRef
48.
Niu, Z., et al. (2013). A repeated halving approach to fabricate ultrathin single-walled carbon nanotube films for transparent supercapacitors. Small, 9, 518–524.CrossRef
49.
Jung, H. Y., Karimi, M. B., Hahm, M. G., Ajayan, P. M., & Jung, Y. J. (2012). Transparent, flexible supercapacitors from nano-engineered carbon films. Scientific Reports, 2, 773.CrossRef
50.
Lee, K., et al. (2016). Highly transparent and flexible supercapacitors using graphene-graphene quantum dots chelate. Nano Energy, 26, 746–754.CrossRef
51.
Fan, X., Chen, T., & Dai, L. (2014). Graphene networks for high-performance flexible and transparent supercapacitors. RSC Advances, 4, 36996.CrossRef
52.
Gao, Y., et al. (2013). Transparent, flexible, and solid-state supercapacitors based on graphene electrodes. APL Materials, 1, 012101.CrossRef
53.
Liu, Y.-H., et al. (2017). High-performance, ultra-flexible and transparent embedded metallic mesh electrodes by selective electrodeposition for all-solid-state supercapacitor applications. Journal of Materials Chemistry A, 5, 9032–9041.CrossRef
54.
Chen, P., & Shen, G. (2009). Flexible and transparent supercapacitor based on In2O3 nanowire/carbon nanotube heterogeneous films. Applied Physics Letters, 94, 43113.CrossRef
55.
Ryu, I., et al. (2014). Coaxial RuO2-ITO nanopillars for transparent supercapacitor application. Langmuir, 30, 1704–1709.CrossRef
56.
Sugimoto, W., Yokoshima, K., Ohuchi, K., Murakami, Y., & Takasu, Y. (2006). Fabrication of thin-film, flexible, and transparent electrodes composed of ruthenic acid nanosheets by electrophoretic deposition and application to electrochemical capacitors. Journal of the Electrochemical Society, 153, A255.CrossRef
57.
Lin, H., et al. (2013). Conducting polymer composite film incorporated with aligned carbon nanotubes for transparent, flexible and efficient supercapacitor. Scientific Reports, 3, 1353.CrossRef
58.
Ge, J., Cheng, G., & Chen, L. (2011). Transparent and flexible electrodes and supercapacitors using polyaniline/single-walled carbon nanotube composite thin films. Nanoscale, 3, 3084–3088.CrossRef
59.
Zhang, C., et al. (2016). Highly flexible and transparent solid-state supercapacitors based on RuO2/PEDOT: PSS conductive ultrathin films. Nano Energy, 28, 495–505.CrossRef
60.
Chen, T., Peng, H., Durstock, M., & Dai, L. (2014). High-performance transparent and stretchable all-solid supercapacitors based on highly aligned carbon nanotube sheets. Scientific Reports, 4, 3612.CrossRef
61.
Yan, J., Liu, J., Fan, Z., Wei, T., & Zhang, L. (2012). High-performance supercapacitor electrodes based on highly corrugated graphene sheets. Carbon, 50, 2179–2188.CrossRef
Metadata
Title
MXenes for Transparent Conductive Electrodes and Transparent Energy Storage Devices
Authors
Chuanfang (John) Zhang
Valeria Nicolosi
Copyright Year
2019
Book
2D Metal Carbides and Nitrides (MXenes)

Print ISBN: 978-3-030-19025-5

Electronic ISBN: 978-3-030-19026-2

Copyright Year: 2019

DOI
https://doi.org/10.1007/978-3-030-19026-2_25