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Nanocrystalline Spinel Catalysts for Volatile Organic Compounds Abatement Read chapter Read first chapter

2021 | OriginalPaper | Chapter

5. Nanostructured Bimetallic Pd-based Catalysts for the Valorization of Lignocellulosic Biomasses

Authors : Emilia Paone, Francesco Mauriello

Published in: Nanostructured Catalysts for Environmental Applications

Publisher: Springer International Publishing

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Abstract

This chapter is focused on the sustainable valorization of lignin and its derived molecules, through the application of the transfer hydrogenolysis technology, by using nanostructured bimetallic Pd-based catalysts, in order to achieve high added-value products. In particular, nanostructured bimetallic co-precipitated Pd-based catalysts (Pd-M systems), such as Pd/Fe3O4, Pd/Co and Pd/Ni, were used and their textural and structural properties have been deeply elucidated through several characterization techniques (XRD, TEM, SEM, H2-TPR, XPS and EXAFS) in order to highlight the key factors that influence the peculiar catalytic activity in the reductive upgrading of lignin-derived aromatic ethers. Hydrogenolysis and transfer hydrogenolysis processes were focused on three model molecules of lignin: Benzyl Phenyl Ether (BPE), Phenethyl Phenyl Ether (PPE) and Diphenyl Ether (DPE) that mimic typical C-O lignin linkages, such as α-O-4, β-O-4 and 4-O-5 bonds. A comparison between the performance of bimetallic Pd-M catalysts and that of the commercial Pd/C is also included.

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previous chapter Supported Nickel Nanocatalysts for the Dry Reforming of Methane: Effect of SBA-15’s Pore Sizes on the Catalytic Performances of Nickel Nanoparticles
next chapter The Issue of Solid-Solid Contact in Catalytic Soot Oxidation and the Benefits of Catalyst Nanostructuring to Regeneration of Catalytic Diesel Particulate Filters
Literature
1.
C.O. Tuck, E. Pérez, I.T. Horváth, R.A. Sheldon, M. Poliakoff, Valorization of biomass: deriving more value from waste. Science 337, 695–699 (2012)CrossRef
2.
R.A. Sheldon, Green and sustainable manufacture of chemicals from biomass: state of the art. Green Chem. 16, 950–963 (2014)CrossRef
3.
F.H. Isikgor, C.R. Becer, Lignocellulosic biomass: a sustainable platform for the production of bio-based chemicals and polymers. Polym. Chem. 6, 4497–4559 (2015)CrossRef
4.
Q. Jin, L. Yang, N. Poe, H. Huang, Integrated processing of plant-derived waste to produce value-added products based on the biorefinery concept. Trends Food Sci. Technol. 74, 119–131 (2018)CrossRef
5.
A.M. Ruppert, K. Weinberg, R. Palkovits, Hydrogenolysis goes bio: from carbohydrates and sugar alcohols to platform chemicals. Angew. Chem. Int. Ed. 51, 2564–2601 (2012)CrossRef
6.
A. Fasolini, R. Cucciniello, E. Paone, F. Mauriello, T. Tabanelli, A short overview on the hydrogen production via aqueous phase reforming (APR) of cellulose, C6-C5 sugars and polyols. Catalysts 9(11), 917 (2019)CrossRef
7.
C.-H. Zhou, X. Xia, C.-X. Lin, D.-S. Tong, J. Beltramini, Catalytic conversion of lignocellulosic biomass to fine chemicals and fuels. Chem. Soc. Rev. 40, 5588–5617 (2011)CrossRef
8.
C. Xu, E. Paone, D. Rodríguez-Padròn, R. Luque, F. Mauriello, Recent catalytic routes for the preparation and the upgrading of biomass derived furfural and 5-hydroxymethylfurfural. Chem. Soc. Rev. 49, 4273–4306 (2020)CrossRef
9.
H. Chen, Chemical composition and structure of natural lignocellulose, in Biotechnology of Lignocellulose: Theory and Practice, (Springer, Cham, 2014)CrossRef
10.
D. Klemm, B. Heublein, H.-P. Fink, A. Bohn, Cellulose: fascinating biopolymer and sustainable raw material. Angew. Chem. Int. Ed. 44, 3358–3393 (2005)CrossRef
11.
C. Xu, R.A.D. Arancon, J. Labidi, R. Luque, Lignin depolymerisation strategies: towards valuable chemicals and fuels. Chem. Soc. Rev. 43, 7485–7500 (2014)CrossRef
12.
M. Besson, P. Gallezot, C. Pinel, Conversion of biomass into chemicals over metal catalysts. Chem. Rev. 114, 1827–1870 (2014)CrossRef
13.
A. Corma, S. Iborra, A. Velty, Chemical routes for the transformation of biomass into chemicals. Chem. Rev. 107, 2411–2502 (2007)CrossRef
14.
J.B. Binder, R.T. Raines, Simple chemical transformation of lignocellulosic biomass into furans for fuels and chemicals. J. Am. Chem. Soc. 131, 1979–1985 (2009)CrossRef
15.
P.J. Deuss, K. Barta, From models to lignin: transition metal catalysis for selective bond cleavage reactions. Coord. Chem. Rev. 306, 510–532 (2016)CrossRef
16.
M. Zaheer, R. Kempe, Catalytic hydrogenolysis of aryl ethers: a key step in lignin valorization to valuable chemicals. ACS Catal. 5, 1675–1684 (2015)CrossRef
17.
J. Zakzeski, P.C.A. Bruijnincx, A.L. Jongerius, B.M. Weckhuysen, The catalytic valorization of lignin for the production of renewable chemicals. Chem. Rev. 110, 3552–3599 (2010)CrossRef
18.
M.V. Galkin, J.S.M. Samec, Lignin valorization through catalytic lignocellulose fractionation: a fundamental platform for the future biorefinery. ChemSusChem 9, 1–16 (2016)CrossRef
19.
C. Espro, B. Gumina, T. Szumelda, E. Paone, F. Mauriello, Catalytic transfer hydrogenolysis as an effective tool for the reductive upgrading of cellulose, hemicellulose, lignin and their derived platform molecules. Catalysts 8(8), 313 (2018)CrossRef
20.
E. Paone, T. Tabanelli, F. Mauriello, The rise of lignin biorefinery. Curr. Opin. Green Sustain. Chem. 24, 1–6 (2020)CrossRef
21.
T. Tabanelli, E. Paone, P.B. Vàsquez, R. Pietropaolo, F. Cavani, F. Mauriello, Transfer hydrogenation of methyl and ethyl levulinate promoted by a ZrO2 catalyst: a comparison of batch vs continuous gas-flow conditions. ACS Sustain. Chem. Eng. 7, 9937–9947 (2019)CrossRef
22.
M. Grilc, B. Likozar, J. Levec, Hydrodeoxygenation and hydrocracking of solvolysed lignocellulosic biomass by oxide, reduced and sulphide form of NiMo, Ni, Mo and Pd catalysts. Appl. Catal. B Environ. 150-151, 275–287 (2014)CrossRef
23.
M. Grilc, B. Likozar, J. Levec, Simultaneous liquefaction and hydrodeoxygenation of lignocellulosic biomass over NiMo/Al2O3, Pd/Al2O3, and zeolite Y catalysts in hydrogen donor solvents. ChemCatChem 8, 180–191 (2015)CrossRef
24.
Y. Zhang, H. Cao, J. Zhang, B. Xia, Synthesis of LiNi0.6Co0.2Mn0.2O2 cathode material by a carbonate co-precipitation method and its electrochemical characterization. Solid State Ionics 177, 3303–3307 (2006)CrossRef
25.
T.H. Cho, Y. Shiosaki, H. Noguchi, Preparation and characterization of layered LiMn1/3Ni1/3Co1/3O2 as a cathode material by an oxalate co-precipitation method. J. Power Sources 159, 1322–1327 (2006)CrossRef
26.
C. Espro, B. Gumina, E. Paone, F. Mauriello, Upgrading lignocellulosic biomasses: hydrogenolysis of platform derived molecules promoted by heterogeneous Pd-Fe catalysts. Catalysts 7, 78 (2017)CrossRef
27.
F. Mauriello, H. Ariga, M.G. Musolino, R. Pietropaolo, S. Takakusagi, K. Asakura, Exploring the catalytic properties of supported palladium catalysts in the transfer hydrogenolysis of glycerol. Appl. Catal. B Environ. 166–167, 121–131 (2015)CrossRef
28.
F. Liao, T.W.B. Lo, S.C.E. Tsang, Recent developments in palladium-based bimetallic catalysts. ChemCatChem 7, 1998–2014 (2015)CrossRef
29.
J. Liu, B. Sun, J. Hu, Y. Pei, H. Li, M. Qiao, Aqueous-phase reforming of ethylene glycol to hydrogen on Pd/Fe3O4 catalyst prepared by co-precipitation: metal–support interaction and excellent intrinsic activity. J. Catal. 274, 287–295 (2010)CrossRef
30.
M.G. Musolino, L.A. Scarpino, F. Mauriello, R. Pietropaolo, Glycerol hydrogenolysis promoted by supported Palladium catalysts. ChemSusChem 4, 1143–1150 (2011)CrossRef
31.
L.S.F. Feio, C.E. Hori, L.V. Mattos, D. Zanchet, F.B. Noronha, J.M.C. Bueno, Partial oxidation and autothermal reforming of methane on Pd/CeO2–Al2O3 catalysts. Appl. Catal. A Gen. 348, 183–192 (2008)CrossRef
32.
G. Neri, G. Rizzo, L. De Luca, A. Donato, M.G. Musolino, R. Pietropaolo, Supported Pd catalysts for the hydrogenation of campholenic aldehyde: influence of support and preparation method. Appl. Catal. A Gen. 356, 113–120 (2009)CrossRef
33.
J. Sun, S. Zhou, P. Hou, Y. Yang, J. Weng, X. Li, M. Li, Synthesis and characterization of biocompatible Fe3O4 nanoparticles. J. Biomed. Mater. Res. A 80, 333–341 (2007)CrossRef
34.
H. Itoh, T. Sugimoto, Systematic control of size, shape, structure, and magnetic properties of uniform magnetite and maghemite particles. J. Colloid Interface Sci. 265, 283–295 (2003)CrossRef
35.
W. Voit, D.K. Kim, W. Zapka, M. Muhammed, K.V. Rao, Magnetic behavior of coated superparamagnetic iron oxide nanoparticles in ferrofluids. Mater. Res. Soc. 676, 781–786 (2001)CrossRef
36.
International Center for Diffraction Data, Powder Diffraction Database. Pennsylvania, PA (1997).
37.
B.A. Sexton, A.E. Hughes, T.W. Turney, An XPS and TPR study of the reduction of promoted cobalt-kieselguhr Fischer-Tropsch catalysts. J. Catal. 97, 390–406 (1986)CrossRef
38.
T. Jiang, Q. Huai, T. Geng, W. Ying, T. Xiao, F. Cao, Catalytic performance of Pd-Ni bimetallic catalyst for glycerol hydrogenolysis. Biomass Bioenergy 78, 71–79 (2015)CrossRef
39.
M.G. Musolino, C. Busacca, F. Mauriello, R. Pietropaolo, Aliphatic carbonyl reduction promoted by palladium catalysts under mild conditions. Appl. Catal. A Gen. 379, 77–86 (2010)CrossRef
40.
D. Li, L. Zhang, H. Chen, L.-X. Ding, S. Wanga, H. Wang, Nitrogen-doped bamboo-like carbon nanotubes: promising anode materials for sodium-ion batteries. Chem. Commun. 51, 16045–16048 (2015)CrossRef
41.
S. Nandi, P. Patel, N.H. Khan, A.V. Biradar, R.I. Kureshy, Nitrogen-rich graphitic-carbon stabilized cobalt nanoparticles for chemoselective hydrogenation of nitroarenes at milder conditions. Inorgan. Chem. Front. 5, 806–813 (2018)CrossRef
42.
Y. Yao, L.L. Gu, W. Jiang, H.C. Sun, Q. Su, J. Zhao, W.J. Ji, C.T. Au, Enhanced low temperature CO oxidation by pretreatment: specialty of the Au–Co3O4 oxide interfacial structures. Cat. Sci. Technol. 6, 2349–2360 (2016)CrossRef
43.
D. Scholz, C. Aellig, I. Hermans, Catalytic transfer hydrogenation/hydrogenolysis for reductive upgrading of furfural and 5-(hydroxymethyl) furfural. ChemSusChem 7, 268–275 (2014)CrossRef
44.
A.J.R. Hensley, Y. Hong, R. Zhang, H. Zhang, J. Sun, Y. Wang, J.S. McEwen, Enhanced Fe2O3 reducibility via surface modification with pd: characterizing the synergy within Pd/Fe catalysts for hydrodeoxygenation reactions. ACS Catal. 4, 3381–3392 (2014)CrossRef
45.
Q. Liu, L.-C. Wang, M. Chen, Y. Cao, H.-Y. He, K.-N. Fan, Dry citrate-precursor synthesized nanocrystalline cobalt oxide as highly active catalyst for total oxidation of propane. J. Catal. 263, 104–113 (2009)CrossRef
46.
F.B. Noronha, M. Schmal, C. Nicot, B. Moraweck, R. Fréty, Characterization of graphite-supported palladium–cobalt catalysts by temperature-programmed reduction and magnetic measurements. J. Catal. 168, 42–50 (1997)CrossRef
47.
M.L. Cubeiro, J.L.G. Fierro, Selective production of hydrogen by partial oxidation of methanol over ZnO-supported palladium catalysts. J. Catal. 179, 150–162 (1998)CrossRef
48.
X. Liu, Y. Zuo, L.P. Li, X.S. Huang, G.S. Li, Heterostructure NiO/Ce−xNixO2: synthesis and synergistic effect of simultaneous surface modification and internal doping for superior catalytic performance. RSC Adv. 4, 6397–6406 (2014)CrossRef
49.
C. Song, J. Zhao, H. Li, S. Luo, Y. Tang, D. Wang, Design, controlled synthesis, and properties of 2D CeO2/NiO heterostructure assemblies. Cryst. Eng. Comm 19, 7339–7346 (2017)CrossRef
50.
Y.-S. Fenga, X.-Y. Lina, J. Hao, H.-J. Xu, Pd–Co bimetallic nanoparticles supported on graphene as a highly active catalyst for Suzuki–Miyaura and Sonogashira cross-coupling reactions. Tetrahedron 70, 5249–5253 (2014)CrossRef
51.
C.D. Wanger, W.M. Riggs, L.E. Davis, J.F. Moulder, G.E. Muilenberg, Handbook of X-ray Photoelectron Spectroscopy (Perkin-Elmer Corp, Minneapolis, MN, 1979)
52.
B. Mierzwa, Z. Kaszkur, B. Moraweck, J. Pielaszek, In situ EXAFS study of the alloy catalyst Pd-Co (50%/50%)/SiO2. J. Alloys Compd. 286, 93–97 (1999)CrossRef
53.
M.C. Biesinger, B.P. Payne, L.W.M. Lau, A. Gerson, R.S.C. Smart, X-ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems. Surf. Interface Anal. 41, 324–332 (2009)CrossRef
54.
N. Seshu Babu, N. Lingaiah, P.S. Sai Prasad, Characterization and reactivity of Al2O3 supported Pd-Ni bimetallic catalysts for hydrodechlorination of chlorobenzene. Appl. Catal. B Environ. 111−112, 309–316 (2012)CrossRef
55.
L. Chen, H. Guo, T. Fujita, A. Hirata, W. Zhang, A. Inoue, M. Chen, Nanoporous PdNi bimetallic catalyst with enhanced electrocatalytic performances for electro-oxidation and oxygen reduction reactions. Adv. Funct. Mater. 21, 4364–4370 (2011)CrossRef
56.
F. Liao, T.W.B. Lo, J. Qu, A. Kroner, A. Dent, S.C.E. Tsang, Tunability of catalytic properties of Pd-based catalysts by rational control of strong metal and support interaction (SMSI) for selective hydrogenolyic C–C and C–O bond cleavage of ethylene glycol units in biomass molecules. Cat. Sci. Technol. 5, 3491–3495 (2015)CrossRef
57.
L. Nguyen, S. Zhang, L. Wang, Y. Li, H. Yoshida, A. Patlolla, A.I. Frenkel, S. Takeda, F.F. Tao, Reduction of nitric oxide with hydrogen on catalysts of singly dispersed bimetallic sites Pt1Com and Pd1Con. ACS Catal. 6, 840–850 (2016)CrossRef
58.
J.K. Kim, J.K. Lee, K.H. Kang, J.W. Lee, I.K. Song, Catalytic decomposition of phenethyl phenyl ether to aromatics over Pd–Fe bimetallic catalysts supported on ordered mesoporous carbon. J. Mol. Catal. A Chem. 410, 184–192 (2015)CrossRef
59.
J.K. Kim, J.K. Lee, K.H. Kang, J.W. Lee, I.K. Song, Selective cleavage of CO bond in benzyl phenyl ether to aromatics over Pd–Fe bimetallic catalyst supported on ordered mesoporous carbon. Appl. Catal. A Gen. 498, 142–149 (2015)CrossRef
60.
B. Gumina, F. Mauriello, R. Pietropaolo, S. Galvagno, C. Espro, Hydrogenolysis of sorbitol into valuable C3-C2 alcohols at low H2 pressure promoted by the heterogeneous Pd/Fe3O4 catalyst. Mol. Catal. 446, 152–160 (2018)CrossRef
61.
J. Sun, A.M. Karim, H. Zhang, L. Kovarik, X.S. Li, A.J. Hensley, J.-S. McEwen, Y. Wang, Carbon-supported bimetallic Pd-Fe catalysts for vapor-phase hydrodeoxygenation of guaiacol. J. Catal. 306, 47–57 (2013)CrossRef
62.
Y. Hong, H. Zhang, J. Sun, K.M. Ayman, A.J.R. Hensley, M. Gu, M.H. Engelhard, J.-S. McEwen, Y. Wang, Synergistic catalysis between Pd and Fe in gas phase dydrodeoxygenation of m-cresol. ACS Catal. 4, 3335–3345 (2014)CrossRef
63.
A.J.R. Hensley, R. Zhang, Y. Wang, J.-S. McEwen, Tailoring the adsorption of benzene on PdFe surfaces: a density functional theory study. J. Phys. Chem. C 117, 24317–24328 (2013)CrossRef
64.
N. Mahata, V. Vishwanathan, Gas phase hydrogenation of phenol over supported palladium catalysts. Catal. Today 49, 65–69 (1999)CrossRef
65.
F. Mauriello, A. Vinci, C. Espro, B. Gumina, M.G. Musolino, R. Pietropaolo, Hydrogenolysis vs. aqueous phase reforming (APR) of glycerol promoted by a heterogeneous Pd/Fe catalyst. Cat. Sci. Technol. 5, 4466–4473 (2015)CrossRef
66.
D. Cozzula, A. Vinci, F. Mauriello, R. Pietropaolo, T.E. Müller, Directing the cleavage of ester C−O bonds by controlling the hydrogen availability on the surface of coprecipitated Pd/Fe3O4. ChemCatChem 8, 1515–1522 (2016)CrossRef
67.
H. Bernas, A. Taskinen, J. Wärnå, D.Y. Murzin, Describing the inverse dependence of hydrogen pressure by multi-site adsorption of the reactant: hydrogenolysis of hydroxymatairesinol on a Pd/C catalyst. J. Mol. Catal. A Chem. 306, 33–39 (2009)CrossRef
68.
G.W. Huber, J.W. Shabaker, S.T. Evans, J.A. Dumesic, Aqueous-phase reforming of ethylene glycol over supported Pt and Pd bimetallic catalysts. Appl. Catal. B Environ. 62, 226–235 (2006)CrossRef
69.
P. Panagiotopoulou, N. Martin, D.G. Vlachos, Effect of hydrogen donor on liquid phase catalytic transfer hydrogenation of furfural over a Ru/RuO2/C catalyst. J. Mol. Catal. A Chem. 392, 223–228 (2014)CrossRef
70.
N.S.M. Bertero, A.F. Trasarti, C.R. Apesteguía, A.J. Marchi, Solvent effect in the liquid-phase hydrogenation of acetophenone over Ni/SiO2: a comprehensive study of the phenomenon. Appl. Catal. A Gen. 394, 228–238 (2011)CrossRef
71.
J. He, C. Zhao, J.A. Lercher, Ni-catalyzed cleavage of aryl ethers in the aqueous phase. J. Am. Chem. Soc. 134, 20768–20775 (2012)CrossRef
72.
Y.R. Luo, Comprehensive Handbook of Chemical Bond Energies (CRC Press, Boca Raton, 2007)CrossRef
73.
Y.S. Choi, R. Singh, J. Zhang, G. Balasubramanian, M.R. Sturgeon, R. Katahira, G. Chupka, G.T. Beckham, B.H. Shanks, Pyrolysis reaction networks for lignin model compounds: unraveling thermal deconstruction of β-O-4 and α-O-4 compounds. Green Chem. 18, 1762–1773 (2016)CrossRef
74.
F. Mauriello, H. Ariga-Miwa, E. Paone, R. Pietropaolo, S. Takakusagi, K. Asakura, Transfer hydrogenolysis of aromatic ethers promoted by the bimetallic Pd/Co catalyst. Catal. Today (2019)
75.
E. Paone, C. Espro, R. Pietropaolo, F. Mauriello, Selective arene production from transfer hydrogenolysis of benzyl phenyl ether promoted by a co-precipitated Pd/Fe3O4 catalyst. Cat. Sci. Technol. 6, 7937–7941 (2016)CrossRef
76.
E. Dorrestijn, L.J.J. Laarhoven, I.W.C.E. Arends, P. Mulder, The occurrence and reactivity of phenoxyl linkages in lignin and low rank coal. J. Anal. Appl. Pyrolysis 54, 153–192 (2000)CrossRef
77.
R. Parthasarathi, R.A. Romero, A. Redondo, S. Gnanakaran, Theoretical study of the remarkably diverse linkages in lignin. J. Phys. Chem. Lett. 2, 2660–2666 (2011)CrossRef
78.
S. De, J. Zhang, R. Luque, N. Yan, Ni-based bimetallic heterogeneous catalysts for energy and environmental applications. Energy Environ. Sci. 9, 3314–3347 (2016)CrossRef
79.
A.G. Sergeev, J.F. Hartwig, Selective, nickel-catalyzed hydrogenolysis of aryl ethers. Science 332, 439–443 (2011)CrossRef
80.
A.G. Sergeev, J.D. Webb, J.F. Hartwig, A heterogeneous nickel catalyst for the hydrogenolysis of aryl ethers without arene hydrogenation. J. Am. Chem. Soc. 134, 20226–20229 (2012)CrossRef
81.
J. He, L. Lu, C. Zhao, D. Mei, J.A. Lercher, Mechanisms of catalytic cleavage of benzyl phenyl ether in aqueous and apolar phases. J. Catal. 311, 41–51 (2014)CrossRef
82.
J. He, L. Lu, C. Zhao, D. Mei, J.A. Lercher, Mechanisms of selective cleavage of C–O bonds in di-aryl ethers in aqueous phase. J. Catal. 309, 280–290 (2014)CrossRef
83.
Q. Song, F. Wang, J. Xu, Hydrogenolysis of lignosulfonate into phenols over heterogeneous nickel catalysts. Chem. Commun. 48, 7019–7021 (2012)CrossRef
84.
J. Zhang, H. Asakura, J. van Rijn, J. Yang, P. Duchesne, B. Zhang, X. Chen, P. Zhang, M. Saeys, N. Yan, Highly efficient, NiAu-catalyzed hydrogenolysis of lignin into phenolic chemicals. Green Chem. 16, 2432–2437 (2014)CrossRef
85.
J. Zhang, J. Teo, X. Chen, H. Asakura, T. Tanaka, K. Teramura, N. Yan, A series of NiM (M = Ru, Rh, and Pd) bimetallic catalysts for effective lignin hydrogenolysis in water. ACS Catal. 4, 1574–1583 (2014)CrossRef
86.
X. Cui, H. Yuan, K. Junge, C. Topf, M. Beller, F. Shi, A stable and practical nickel catalyst for the hydrogenolysis of C–O bonds. Green Chem. 19, 305–310 (2017)CrossRef
87.
M.M. Ambursa, P. Sudarsanam, L. HweiVoon, S.B.A. Hamid, S.K. Bhargava, Bimetallic Cu-Ni catalysts supported on MCM-41 and Ti-MCM-41 porous materials for hydrodeoxygenation of lignin model compound into transportation fuels. Fuel Process. Technol. 162, 87–97 (2017)CrossRef
88.
J.-W. Zhang, Y. Cai, G.-P. Lu, C. Cai, Facile and selective hydrogenolysis of β-O-4 linkages in lignin catalyzed by Pd-Ni bimetallic nanoparticles supported on ZrO2. Green Chem. 18, 6229–6235 (2016)CrossRef
89.
K.-K. Sun, G.-P. Lu, J.-W. Zhang, C. Cai, Selective hydrogenolysis of C-O bonds in lignin model compounds by Pd-Ni bimetallic nanoparticles in ionic liquids. Dalton Trans. 46, 11884–11889 (2017)CrossRef
90.
J.-W. Zhang, G.-P. Lu, C. Cai, Self-hydrogen transfer hydrogenolysis of β-O-4 linkages in lignin catalyzed by MIL-100(Fe) supported Pd-Ni BMNPs. Green Chem. 19, 4538–4543 (2017)CrossRef
91.
X. Wang, R. Rinaldi, Exploiting H-transfer reactions with RANEY®Ni for upgrade of phenolic and aromatic biorefinery feeds under unusual, low-severity conditions. Energy Environ. Sci. 5, 8244–8260 (2012)CrossRef
92.
X. Wang, R. Rinaldi, A route for lignin and bio-oil conversion: dehydroxylation of phenols into arenes by catalytic tandem reactions. Angew. Chem. Int. Ed. 52, 11499–11503 (2013)CrossRef
93.
X. Wang, R. Rinaldi, Solvent effects on the hydrogenolysis of diphenyl ether with raney nickel and their implications for the conversion of lignin. ChemSusChem 5, 1455–1466 (2012)CrossRef
94.
X. Wang, R. Rinaldi, Bifunctional Ni catalysts for the one-pot conversion of Organosolv lignin into cycloalkanes. Catal. Today 269, 48–55 (2016)CrossRef
95.
F. Mauriello, E. Paone, R. Pietropaolo, A.M. Balu, R. Luque, Catalytic transfer hydrogenolysis of lignin-derived aromatic ethers promoted by bimetallic Pd/Ni systems. ACS Sustain. Chem. Eng. 6, 9269–9276 (2018)CrossRef
96.
C.M. Friend, E.L. Muetterties, Coordination chemistry of metal surfaces. 3. Benzene and toluene interactions with nickel surfaces. J. Am. Chem. Soc. 103, 173–779 (1981)
Metadata
Title
Nanostructured Bimetallic Pd-based Catalysts for the Valorization of Lignocellulosic Biomasses
Authors
Emilia Paone
Francesco Mauriello
Copyright Year
2021
Book
Nanostructured Catalysts for Environmental Applications

Print ISBN: 978-3-030-58933-2

Electronic ISBN: 978-3-030-58934-9

Copyright Year: 2021

DOI
https://doi.org/10.1007/978-3-030-58934-9_5

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