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Topics in Catalysis
Published in: Topics in Catalysis 11/2009

01-10-2009 | Original Paper

On the Use of Silicon Nitride in Catalysis

Authors: F. J. Cadete Santos Aires, J. C. Bertolini

Published in: Topics in Catalysis | Issue 11/2009

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Abstract

Silicon nitride has very good thermal and chemical stability, as well as high thermal conductivity compared to oxide materials, which are commonly used as catalyst supports. In exothermic reactions working at high temperature, this facilitates heat transfer and thus limits the formation of local hot spots, which are often responsible for structural modification of the support in addition to sintering of active phases. However, it is only recently that this material has been considered for application as a catalyst support for high temperature reactions. It is now established that silicon nitride can be a good support for catalytically active phases. Its range of application is continually expanding (e.g., partial/total oxidation of methane, hydrogenation and dehydrogenation reactions, photocatalysis, base catalysis, etc.).
previous article H/D Exchange on Silica-Grafted Tantalum(V) Imido Amido [(≡SiO)2Ta(V)(NH)(NH2)] Synthesized from Either Ammonia or Dinitrogen: IR and DFT Evidence for Heterolytic Splitting of D2
next article Studies of the Kinetics of Reaction Between Iron Catalysts and Ammonia—Nitriding of Nanocrystalline Iron with Parallel Catalytic Ammonia Decomposition

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Metadata
Title
On the Use of Silicon Nitride in Catalysis
Authors
F. J. Cadete Santos Aires
J. C. Bertolini
Publication date
01-10-2009
Publisher
Springer US
Published in
Topics in Catalysis / Issue 11/2009
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-009-9296-z

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Preface

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