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Published in: Journal of Nanoparticle Research 11/2019

01-11-2019 | Research Paper

Ordered mesoporous alumina with ultra-large pore size catalyze cinnamaldehyde to cinnamyl alcohol with high selectivity

Authors: Jianzheng Zhang, Xiaofei Xing, Jiaren Zhang, Junmei Chu, Zhenxing Li, Qiuyu Zhang, Rumin Wang, Songhua Wu

Published in: Journal of Nanoparticle Research | Issue 11/2019

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Abstract

At present, most of mesoporous alumina are synthesized by a soft template method with pore diameters of less than 10 nm, which tends to cause an amorphous structure and great limitations for the catalytic reaction. Therefore, we chose to use triblock copolymer as a template and self-assembly by solvent evaporation to synthesize an ultra-large mesoporous alumina without any pore expanding agents. The synthesized mesoporous alumina is used for the hydrogenation reaction of 4-methoxy cinnamaldehyde, and the mesoporous alumina exhibited high conversion and excellent selectivity. Compared with industrial synthesis of 4-methoxy cinnamyl alcohol, the reaction can be a complete conversion of 4-methoxy cinnamaldehyde to 4-methoxy cinnamyl alcohol without any by-products.

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Appendix
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Metadata
Title
Ordered mesoporous alumina with ultra-large pore size catalyze cinnamaldehyde to cinnamyl alcohol with high selectivity
Authors
Jianzheng Zhang
Xiaofei Xing
Jiaren Zhang
Junmei Chu
Zhenxing Li
Qiuyu Zhang
Rumin Wang
Songhua Wu
Publication date
01-11-2019
Publisher
Springer Netherlands
Published in
Journal of Nanoparticle Research / Issue 11/2019
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-019-4682-3

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