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Topics in Catalysis
Published in: Topics in Catalysis 7-10/2012

01-07-2012 | Original Paper

Palladium Containing Catalysts Based on Hypercrosslinked Polystyrene for Selective Hydrogenation of Acetylene Alcohols

Authors: Esfir M. Sulman, Linda Zh. Nikoshvili, Valentina G. Matveeva, Irina Yu. Tyamina, Alexander I. Sidorov, Alexey V. Bykov, Galina N. Demidenko, Barry D. Stein, Lyudmila M. Bronstein

Published in: Topics in Catalysis | Issue 7-10/2012

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Abstract

This paper reports palladium nanoparticle formation and stabilization by hypercrosslinked polystyrene and the catalytic properties of the nanocomposites obtained. The nanocomposites were characterized using low-temperature nitrogen physisorption, X-ray photoelectron spectroscopy and transmission electron microscopy. The inorganic nanoparticle size was found to depend on the Na2PdCl4 loading with the smallest nanoparticles formed at 0.1 wt% of Pd. The nanocomposites synthesized showed high activity [up to 27 mol/(mol Pd s)] and selectivity (up to 98.5 % at 100 % conversion) in selective hydrogenation of acetylene alcohols.
previous article Shape and Size-Tailored Pd Nanocrystals to Study the Structure Sensitivity of 2-Methyl-3-butyn-2-ol Hydrogenation: Effect of the Stabilizing Agent
next article Effect of Supports on the Catalytic Hydrogenation of Polystyrene

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Metadata
Title
Palladium Containing Catalysts Based on Hypercrosslinked Polystyrene for Selective Hydrogenation of Acetylene Alcohols
Authors
Esfir M. Sulman
Linda Zh. Nikoshvili
Valentina G. Matveeva
Irina Yu. Tyamina
Alexander I. Sidorov
Alexey V. Bykov
Galina N. Demidenko
Barry D. Stein
Lyudmila M. Bronstein
Publication date
01-07-2012
Publisher
Springer US
Published in
Topics in Catalysis / Issue 7-10/2012
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-012-9810-6

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