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Journal of Nanoparticle Research

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01-06-2010 | Research Paper

Peroxide-based route assisted with inverse microemulsion process to well-dispersed Bi₄Ti₃O₁₂ nanocrystals

Authors: Jungang Hou, Yuanfang Qu, Dalibor Krsmanovic, R. V. Kumar

Published in: Journal of Nanoparticle Research | Issue 5/2010

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Abstract

Well-dispersed bismuth titanate (BIT) nanocrystals with an average size ranged from 3 to 60 nm were synthesized via a peroxide-based route assisted with an inverse microemulsion process. The crystallite size and lattice parameter of BIT upon variable-temperature were determined by X-ray diffraction (XRD). The particle size was confirmed by transmission electron microscopy (TEM). Thermal decomposition behaviour of Ti-peroxy and BIT gel and crystallization kinetics of BIT nanocrystals were investigated by differential scanning calorimetry/thermogravimetry (DSC/TG) and Fourier-Transform infrared spectroscopy (FTIR). Analysis of nonisothermal DSC data yielded a value of 220.84 ± 2.73 KJ/mol and 2.25 ± 0.26 for the activation energy of crystallization (E _a) and the Avrami exponent (n), respectively.

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Title: Peroxide-based route assisted with inverse microemulsion process to well-dispersed Bi4Ti3O12 nanocrystals
Authors: Jungang Hou
Yuanfang Qu
Dalibor Krsmanovic
R. V. Kumar
Publication date: 01-06-2010
Publisher: Springer Netherlands
Published in: Journal of Nanoparticle Research / Issue 5/2010
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-009-9737-4

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