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Polymer Science, Series A
Published in: Polymer Science, Series A 6/2023

09-02-2024 | SOLUTIONS

Phase Transitions and Thermodynamic Interaction Parameters of Components in Poly(methyl methacrylate) and Poly(vinyl acetate)

Authors: S. A. Vshivkov, E. V. Rusinova

Published in: Polymer Science, Series A | Issue 6/2023

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Abstract

Phase diagrams with UCST are constructed for systems poly(methyl methacrylate)–butanol, poly(vinyl acetate)–methanol, and poly(vinyl acetate)–2-propanol. The boundary curve of the PMMA–о-xylene system is unusual in shape, which is explained by the fact that polymer macromolecules form stereo complexes that appear during solution cooling. The thermodynamic interaction parameters χ of components and the values of χcr and critical concentration of the systems under study are calculated. With increasing temperature the value of χ decreases, which indicates that the interaction of components is improved under heating and agrees with the phase diagrams of the systems.
previous article Hydrodynamic and Conformational Behavior of N-Vinylformamide–Sodium 4-Styrenesulfonate Copolymers in Aqueous Solutions
next article Thermo- and pH-Sensitive Copolymers of N-(3-(Diethylamino)Propyl)-N-methylacrylamide and N,N-Dipropylacrylamide

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Metadata
Title
Phase Transitions and Thermodynamic Interaction Parameters of Components in Poly(methyl methacrylate) and Poly(vinyl acetate)
Authors
S. A. Vshivkov
E. V. Rusinova
Publication date
09-02-2024
Publisher
Pleiades Publishing
Published in
Polymer Science, Series A / Issue 6/2023
Print ISSN: 0965-545X
Electronic ISSN: 1555-6107
DOI
https://doi.org/10.1134/S0965545X2360059X

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