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Journal of Polymer Research
Published in: Journal of Polymer Research 3/2019

01-03-2019 | ORIGINAL PAPER

Photochemical properties of metalloporphyrin-silver nanoparticle stabilized by polymeric micelle

Authors: Zhihua Chai, Yanxia Wang, Si Chen, Hua Chen, Heng Yang, Xiaojie Guo, Fachao Wu

Published in: Journal of Polymer Research | Issue 3/2019

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Abstract

Inspired by the chlorophyll-protein complex in photosynthesis, a core–shell hybrid micelle was prepared from poly(ethylene glycol)-block-poly(4-vinylpyridine) (PEG-b-P4VP), zinc tetrakis(4-sulfonatophenyl) porphyrin (ZnTPPS), and silver nanoparticles (AgNPs). In the micellar core, AgNPs and ZnTPPS were dispersed through axial coordination. Structural and morphological characterizations of the complex micelle were carried out by transmission electron microscopy, laser light scatting, and ultraviolet–visible spectroscopy. In the micellar solutions, ZnTPPS showed increased photostability due to a decrease in the generation of singlet oxygen. Furthermore, electron transfer from ZnTPPS to AgNPs was observed by photoreduction of methylviologen hydrate. These results promote a greater understanding of the appealing properties of the natural chlorophyll-protein complex, which has important implications in artificial photosynthetic reactions and antibacterial therapy.
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Metadata
Title
Photochemical properties of metalloporphyrin-silver nanoparticle stabilized by polymeric micelle
Authors
Zhihua Chai
Yanxia Wang
Si Chen
Hua Chen
Heng Yang
Xiaojie Guo
Fachao Wu
Publication date
01-03-2019
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 3/2019
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-019-1735-3

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