Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Published in:
Rare Earth, Rare Earth Luminescence, Luminescent Rare Earth Compounds, and Photofunctional Rare Earth Hybrid Materials Read chapter Read first chapter

2017 | OriginalPaper | Chapter

6. Photofunctional Rare Earth Hybrid Materials Based on Polymer and Polymer/Silica Composite

Author : Bing Yan

Published in: Photofunctional Rare Earth Hybrid Materials

Publisher: Springer Singapore

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

This chapter mainly focuses on recent research progress in photofunctional rare earth hybrid materials based on polymer and polymer/silica composite. The emphasis is put on the rare earth hybrids with polymer as the main building units. It covers photofunctional rare earth hybrid material based on organic polymers, mainly the rare earth complexes with polymers; photofunctional rare earth hybrid materials based on organically modified silica and organic polymers, with both of the two units behaving as ligands coordinated to rare earth ions and no direct interaction between them; and photofunctional rare earth hybrid materials based on organically modified silica covalently bonded organic polymers. Herein, it focuses on the work of our group in the recent years.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
previous chapter Photofunctional Rare Earth Hybrid Materials Based on Functionalized Metal–Organic Frameworks
next chapter Photofunctional Rare Earth Hybrid Materials Based on Multicomponent Assembly
Literature
1.
Ueba Y, Banks E, Okmoto Y (1980) Investigation on the synthesis and characterization of rare earth metal-containing polymers. II. Fluorescence properties of Eu3+–polymer complexes containing β-diketone ligand. J Appl Polym Sci 25:2007–2017CrossRef
2.
Okmoto Y, Ueba Y, Zhanibekov NFD, Banks E (1981) Rare earth metal containing polymers. 3. Characterization of ion-containing polymer structures using rare earth metal fluorescence probes. Macromolecules 14:17–22CrossRef
3.
Bekiari V, Pistolis G, Lianos P (1999) Intensely luminescent materials obtained by combining lanthanide ions, 2,2′-bipyridine, and poly(ethylene glycol) in various fluid or solid environments. Chem Mater 11:3189–3195CrossRef
4.
Parra EF, Brito HF, Matos JDR, Dias LC (2002) Enhancement of the luminescent intensity of the novel system containing Eu3+ beta-diketonate complex doped in the epoxy resin. J Appl Polym Sci 83:2716–2726CrossRef
5.
Zucchi G, Murugesan V, Tondelier D, Aldakov D, Jeon T, Yang F, Thuery P, Ephritikhine M, Geffroy B (2011) Solution, solid state, and film properties of a structurally characterized highly luminescent molecular europium plastic material excitable with visible light. Inorg Chem 50:4851–4856CrossRef
6.
Lunstroot K, Driesen K, Nockemann P, Viau L, Mutin PH, Vioux A, Binnemans K (2010) Ionic liquid as plasticizer for europium(III)-doped luminescent poly(methyl methacrylate) films. Phys Chem Chem Phys 12:1879–1885
7.
Tanner PA, Yan B, Zhang HJ (2000) Preparation and luminescence properties of sol-gel hybrid materials incorporated with europium complexes. J Mater Sci 35:4325–4328CrossRef
8.
Yan B (2003) Sol-gel preparation and luminescence of silica/polymer hybrid material incorporated with terbium complex. Mater Lett 57:2535–2539CrossRef
9.
Yan B, Wang QM (2004) In-situ composition and luminescence of terbium coordination polymers/PEMA hybrid thick films. Opt Mater 27:533–537CrossRef
10.
Wang HF, Wang YG, Zhang L, Li HR (2013) Transparent and luminescent ionogels based on rare earth-containing ionic liquids and poly(methyl methacrylate) prepared through an environmentally friendly method. RSC Adv 3:8535–8540CrossRef
11.
Yan B, Qiao XF, Sheng K, Wang XL, Guo M, Shao YF (2012) Recent progress in the research of chemical assembled rare earth/inorganic/polymeric hybrid photofunctional materials. Sci China Chem (in Chinese) 42:1278–1288.
12.
Chen HY, Archer RD (1996) Synthesis and characterization of linear luminescent Schiff-base polyelectrolytes with europium(III) in the backbone. Macromolecules 29:1957–1964CrossRef
13.
Zhao LM, Yan B (2007) Novel polymer-inorganic hybrid materials fabricated with in situ composition and luminescent properties. J Non-Cryst Sol 353:4654–4659
14.
Bender JL, Corbin PS, Fraser CL, Metcalf DH, Richardson FS, Thomas EL, Urbas AM (2002) Site-isolated luminescent europium complexes with polyester macroligands: metal-mentered heteroarm stars and nanoscale assemblies with labile block junctions. J Am Chem Soc 124:8526–8527CrossRef
15.
Shunmugam R, Tew GN (2008) Polymers that contain ligated metals in their side chain: building a foundation for functional materials in opto-electronic applications with an emphasis on rare earth ions. Macromol Rapid Comm 29:1355–1362CrossRef
16.
Shunmugam R, Tew GN (2007) Dialing in color with rare earth metals: facile photoluminescent production of true white light. Polym Adv Technol 18: 940–945
17.
Wang LH, Wang W, Zhang WG, Kang ET, Huang W (2000) Synthesis and luminescence properties of novel Eu-containing copolymers consisting of Eu(III)-acrylate-β-diketonate complex monomers and methyl methacrylate. Chem Mater 12:2212–2218CrossRef
18.
Liu Y, Wang QM, Xiang YQ, Yan B (2006) Luminescent behavior of two novel thermo-sensitive poly(N-isopropylacrylamide) hydrogels incorporated with rare earth complexes. J Fluorescence 16:723–726CrossRef
19.
Wang QM, Yan B (2006) Assembly of luminescent hybrids from co-polymers bearing functional 4-vinyl pyridine and europium aromatic carboxylate. J Photochem Photobiol A Chem 177:1–5CrossRef
20.
Yan B, Wang QM (2007) Molecular fabrication and photoluminescence of novel terbium co-polymer using 4-vinyl pyridine as the efficient second ligand. Opt Mater 30:617–621CrossRef
21.
Yan B, Guo M, Li QP (2012) Two series of multi-component rare earth (Eu3+, Tb3+, Sm3+) polymeric hybrids: chemically bonded assembly and photophysical properties. Photochem Photobiol 88:242–249CrossRef
22.
Carlos LD, Messaddeq Y, Brito HF, Ferreira RAS, Bermudez VDZ, Ribeiro SJL (2000) Full-color phosphors from europium(III)-based organosilicates. Adv Mater 12:594–598CrossRef
23.
Carlos LD, Ferreira RAS, Rainho JP, Bermudez VDZ (2002) Fine tuning of the chromaticity of the emission color of organic-inorganic hybrids co-doped with EuIII, TbIII and TmIII. Adv Funct Mater 12:819–823CrossRef
24.
Dahmouche K, Carlos LD, Santilli CV, Bermudez VDZ, Craievich AF (2002) Small-angle x-ray scattering study of gelation and aging of Eu3+-doped sol-gel-derived siloxane-poly(oxyethylene) nanocomposites. J Phys Chem B 106:4377–4382CrossRef
25.
Goncalves MC, Bermudez VDZ, Ferreira RAS, Carlos LD, Ostrovskii D, Rocha J (2004) Optically functional di-urethanesil nanohybrids containing Eu3+ ions. Chem Mater 16:2530–2543CrossRef
26.
Bermudez VDZ, Ostrovskii D, Goncüalves MC, Lavoryk S, Carlos LD, Ferreira RAS (2005) Eu3+ coordination in an organic/inorganic hybrid matrix with methyl end-capped short polyether chains. J Phys Chem B 109:7110–7119CrossRef
27.
Goncalves MC, Silva NJO, Bermudez VDZ, Ferreira RAS, Carlos LD, Dahmouche K, Santilli CV, Ostrovskii D, Correia Vilela IC, Craievich AF (2005) Local structure and near-infrared emission features of neodymium-based amine functionalized organic/inorganic hybrids. J Phys Chem B 109:20093–20104CrossRef
28.
Lima PP, Nobre SS, Freire RO, Junior SA, Ferreira RAS, Pischel U, Malta OL, Carlos LD (2007) Energy transfer mechanisms in organic-inorganic hybrids incorporating europium(III): a quantitative assessment by light emission spectroscopy. J Phys Chem C 111:17627–17634CrossRef
29.
Fu LS, Ferreira RAS, Nobre SS, Carlos LD, Rocha J (2007) In situ synthesis of rare earth complex in urea cross-linked organic/inorganic di-ureasil hybrids via carboxylic acid solvolysis. J Lumin 122–123:265–267
30.
Fernandes M, Bermudez VDZ, Ferreira RAS, Carlos LD, Martins NV (2008) Incorporation of the Eu(tta)3(H2O)2 complex into a co-condensed d-U(600)/d-U(900) matrix. J Lumin 128:205–212CrossRef
31.
Pecoraro E, Ferreira RAS, Molina C, Ribeiro SJL, Messsaddeq Y, Carlos LD (2008) Photoluminescence of bulks and thin films of Eu3+-doped organic/inorganic hybrids. J Alloys Compds 451:136–139CrossRef
32.
Fernandes M, Goncalves MC, Bermudeza VDZ, Ferreira RAS, Carlos LD, Charas A, Morgado J (2008) Optical material composed of a di-urethanesil host hybrid and a europium complex. J Alloys Compds 451:201–205CrossRef
33.
Molina C, Ferreira RAS, Poirier G, Fu LS, Ribeiro SJL, Messsaddeq Y, Carlo LD (2008) Er3+-based diureasil organic-inorganic hybrids. J Phys Chem C 112:19346–19352
34.
Mesquita ME, Nobre SS, Fernandes M, Ferreira RAS, Santos SCG, Rodrigues MO, Carlos LD, Bermudez VDZ (2009) Highly luminescent di-ureasil hybrid doped with a Eu(III) complex including dipicolinate ligands. J Photochem Photobiol A Chem 205:156–160
35.
Lima PP, Ferreira RAS, Júnior SA, Malta OL, Carlos LD (2009) Terbium(III)-containing organic–inorganic hybrids synthesized through hydrochloric acid catalysis. J Photochem Photobiol A Chem 201:214–221CrossRef
36.
Liu FY, Carlos LD, Ferreira RAS, Rocha J, Ferro MC, Tourrette A, Quignard F, Robitzer M (2010) Synthesis, texture, and photoluminescence of lanthanide-containing chitosan-silica hybrids. J Phys Chem B 114:77–83CrossRef
37.
Huang XG, Wang Q, Yan XH, Xu J, Liu WS, Wang Q, Tang Y (2011) Encapsulating a ternary europium complex in a silica/polymer hybrid matrix for high performance luminescence application. J Phys Chem C 115:2332–2340CrossRef
38.
Yan B, Wang QM (2007) Covalently bonded assembly and photoluminescent properties of rare earth/silica/poly(methyl methacrylate-co-maleic anhydride) hybrid materials. J Photochem Photobiol A Chem 197:213–219CrossRef
39.
Yan B, Zhao LM, Liu JL (2008) Molecular assembly and photophysical properties of covalently bonded rare earth polymeric hybrid materials phen-RE-MSMA (MS). J Photochem Photobiol A Chem 199:50–56CrossRef
40.
Yan B, Qiao XF (2007) Rare earth/inorganic/organic polymeric hybrid materials: molecular assembly, regular microstructure and photoluminescence. J Phys Chem B 111:12362–12374CrossRef
41.
Qiao XF, Yan B (2009) Binary and ternary lanthanide centered hybrid polymeric materials: coordination bonding construction, characterization, microstructure and photoluminescence. Dalton Trans 38:8509–8518CrossRef
42.
Sheng K, Yan B, Lu HF, Guo L (2011) Ternary rare earth inorganic/organic hybrids with a mercapto-functionalized Si-O linkage and a polymer chain: coordination bonding assembly and luminescence. Eur J Inorg Chem:3498–3505
43.
Qiao XF, Yan B (2008) Assembly, characterization, and photoluminescence of hybrids containing europium (Ш) complexes covalently bonded to inorganic Si-O networks/organic polymers by modified beta-diketone. J Phys Chem B 112:14742–14750CrossRef
44.
Qiao XF, Yan B (2009) Hybrid materials of rare earth centers/functionalized 2-thenoyltrifluoroacetone/silicon-oxygen network/polymeric chain: coordination bonded assembly, physical characterization, and photoluminescence. Inorg Chem 48:4714–4723CrossRef
45.
Qiao XF, Yan B (2009) Luminescent polymeric hybrids functionalized by beta-diketone with silicon-oxygen networks and carbon chains: assembly and characterization. Eur Polym J 45:2002–2010CrossRef
46.
Sheng K, Yan B (2010) A new luminescent molecular based terbium hybrid material containing both organic polymeric chains and inorganic silica networks. J Mater Sci Mater Electr 21:65–71CrossRef
47.
Sheng K, Yan B (2009) Coordination bonding assembly and photophysical properties of europium organic/inorganic/polymeric hybrid materials. J Photochem Photobiol A Chem 206:140–147CrossRef
48.
Guo L, Yan B, Sheng K, Wang XL (2011) Coordination bonding construction, characterization and photoluminescence of ternary rare earth (Eu3+, Tb3+) hybrids with phenylphenacyl-sulfoxide modified bridge and polymer units. Dalton Trans 40:632–638
49.
Qiao XF, Zhang HY, Yan B (2010) Photoactive binary and ternary rare earth (Eu3+, Tb3+, Nd3+) hybrids with p-tert-butylcalix[4]arene derived Si-O linkages and polymers. Dalton Trans 39:8882–8892CrossRef
50.
Yan B, Sheng K, Yao RF (2009) Novel luminescent rare earth hybrids covalently trapped through phthalic anhydride linkage. J Non-Cryst Sol 355:1008–1011CrossRef
51.
Sheng K, Yan B, Qiao XF, Guo L (2010) Rare earth (Eu/Tb)/phthalic acid functionalized inorganic Si-O/organic polymeric hybrids: chemically bonded fabrication and photophysical property. J Photochem Photobiol A Chem 210:36–43CrossRef
52.
Wang XL, Yan B, Liu JL (2011) Photophysical properties of ternary rare earth (Sm3+, Eu3+) centered hybrid systems with N-heterocyclic modified Si-O bridge and terminal ligands. Photochem Photobiol Sci 10:580–586CrossRef
53.
Yan B, Wang XL, Liu JL (2011) Photophysical properties of ternary organometallic hybrid system of rare earth center linking organically modified silica and polymeric chain. Photochem Photobiol 87:602–610CrossRef
54.
Sheng K, Li HT, Jin Z, Li Y (2014) Near-white light luminescent material from Eu(III) complexes encapsulated in silica/PMMA matrices. J Mater Sci Mater Electron 25:4562–4567CrossRef
55.
Yan B, Yao RF, Wang QM (2006) Molecular assembly and photoluminescence of novel rare earth/inorganic/polymeric hybrid materials with functional covalent linkages. Mater Lett 60:3063–3067CrossRef
56.
Qiao XF, Yan B (2009) Covalently bonded assembly of rare earth/silicon-oxygen network/polyethylene glycol hybrid materials through functionalized 2-thenoyltrifluoroacetone linkage. J Phys Chem B 113:11865–11875CrossRef
57.
Yan B, Zhao LM, Qiao XF, Wang XL, Zhao Y (2011) Sol-gel preparation, microstructure and luminescence of rare earth / silica / polyacrylamide hybrids through double functionalized covalent Si-O linkage. RSC Adv 1:1064–1071CrossRef
58.
Wang XL, Yan B, Liu JL (2010) Photoactive rare earth (Eu3+, Tb3+) hybrids with organically modified silica covalently bonded polymeric chain. Coll Polym Sci 288:1139–1150CrossRef
59.
Yan B, Qian K, Wang XL (2011) Photofunctional Eu3+/Tb3+ hybrids with inorganic silica covalently linking polymer chain through their double functionalization. Inorg Chim Acta 376:302–309CrossRef
60.
Qiao XF, Yan B (2008) Molecular construction and photophysics of luminescent covalently bonded hybrids by grafting the rare earth ions into the silicon-oxygen networks and carbon chains. J Photochem Photobiol A Chem 199:188–196CrossRef
61.
Qiao XF, Yan B (2009) Chemically bonded assembly and photophysical properties of luminescent hybrid polymeric materials embedded into silicon-oxygen network and carbon unit. J Organomet Chem 694:3232–3241CrossRef
62.
Qiao XF, Yan B (2011) Rare earth (Eu3+, Tb3+) centered polymeric hybrids: composite assembly of radical addition polymerization and condensation reaction, physical characterization and photoluminescence. New J Chem 35:568–575CrossRef
63.
Guo M, Yan B, Guo L, Qiao XF (2011) Cooperative sol-gel assembly, characterization and photoluminescence of rare earth hybrids with novel covalent linkages and 1,10-phenanthroline. Coll Surf A 380:53–59CrossRef
64.
Yan B, Guo M, Qiao XF (2011) Luminescent rare earth (Eu3+, Tb3+) hybrids with 4-vinylbenzeneboronic acid functionalized Si-O bridge and beta-diketones. Photochem Photobiol 87:786–794CrossRef
65.
Wang XL, Yan B (2012) Photofunctional binary and ternary Eu3+/Tb3+ hybrid materials with copolymer linkage methacrylic acid–vinyltrimethoxysilane and 1,10-phenanthroline. Coll Surf A 399:18–24CrossRef
66.
Li Y, Guo M, Yan B (2012) Photoluminescent Eu3+/Tb3+ hybrids from the copolymerization of organically-modified silane. Coll Polym Sci 290:1765–1775CrossRef
67.
Wang XL, Yan B (2011) Ternary luminescent rare earth-centered hybrids with organically modified titania and polymer units. Coll Polym Sci 289:423–431CrossRef
68.
Yan B, Guo M (2013) Photoluminescent hybrid aluminum and titanium gels linked with Eu3+/Tb3+ complexes and polymer units through coordination bond. Inorg Chim Acta 399:160–165CrossRef
69.
Li YJ, Ge XT, Pang XL, Yu XD, Zhen XL, Geng LJ, Wang YQ (2015) Molecular assembly and luminescent properties of europium polymeric hybrid material based on Si–O–Ti hosts. Mater Lett 152:170–172CrossRef
70.
Li QP, Yan B (2013) Novel luminescent hybrids by incorporating rare earth β-diketonates into polymers through ion pairing with an imidazolium counter ion. Photochem Photobiol Sci 12:1628–1635CrossRef
71.
Yan B, Guo M (2013) Photofunctional Eu3+/Tb3+ organic-inorganic polymeric hybrid microspheres with covalently bonded resin host. J Photochem Photobiol A Chem 257:34–43CrossRef
Metadata
Title
Photofunctional Rare Earth Hybrid Materials Based on Polymer and Polymer/Silica Composite
Author
Bing Yan
Copyright Year
2017
Publisher
Springer Singapore
Book
Photofunctional Rare Earth Hybrid Materials

Print ISBN: 978-981-10-2956-1

Electronic ISBN: 978-981-10-2957-8

Copyright Year: 2017

DOI
https://doi.org/10.1007/978-981-10-2957-8_6