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Journal of Materials Science
Published in: Journal of Materials Science 1/2019

20-08-2018 | Chemical routes to materials

Photothermal conversion performance of perylene diimide radical anion salts modified with tunable moieties

Authors: Qizhe Li, Wenlong Hou, Fei Peng, Hailong Wang, Shuo Zhang, Danyang Dong, Siyu Wu, Haiquan Zhang

Published in: Journal of Materials Science | Issue 1/2019

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Abstract

Among photothermal materials, perylene diimide radical anions were promising organic candidates with intense and characteristic near-infrared (NIR) absorption bands and non-fluorescence. Herein, two isolable and ambient stable bay-substituted perylene diimide radical anion salts, namely DBrPDI radical anion salt and TPPDI radical anion salt, were facilely prepared and confirmed by using a very thorough analysis based on the data from UV–Vis/NIR, FL, FTIR, EPR and NMR spectra. Subsequently, two radical anion salts were applied as photothermal conversion agents. DBrPDI radical anion salt exhibited high-performance photothermal conversion in DMF solutions, however a decline in aqueous solution. TPPDI radical anion salt with bulky moieties onto the PDI cores and amine position gave substantial evidence that the photothermal properties could be optimized and enhanced in aqueous solution by modulating the chemical structure of the photothermal conversion agent.
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Appendix
Available only for authorised users
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Metadata
Title
Photothermal conversion performance of perylene diimide radical anion salts modified with tunable moieties
Authors
Qizhe Li
Wenlong Hou
Fei Peng
Hailong Wang
Shuo Zhang
Danyang Dong
Siyu Wu
Haiquan Zhang
Publication date
20-08-2018
Publisher
Springer US
Published in
Journal of Materials Science / Issue 1/2019
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2822-2

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