Skip to main content
Top
Published in: The International Journal of Advanced Manufacturing Technology 1-4/2019

12-09-2019 | ORIGINAL ARTICLE

Polishing single-crystal silicon carbide with porous structure diamond and graphene-TiO2 slurries

Authors: Ming Yi Tsai, Zuan Tang Hoo

Published in: The International Journal of Advanced Manufacturing Technology | Issue 1-4/2019

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

In this study, a self-modified diamond (SMD) slurry for mechanical polishing is presented as well as a novel TiO2-graphene slurry used with the aid of UV light for a chemical mechanical polishing (CMP) technique that improves the rate of polishing. The surface characteristics and removal rate of silicon carbide (SiC) samples polished with the slurry were compared with the results obtained by polishing with both a conventional diamond slurry and CMP slurry. The experimental results indicated that the material removal rate (MRR) of SiC from the wafer surface with the SMD slurry was higher, and surface finish and lapping efficiency was better than that achievable with other slurries. The experimental data also showed that a TiO2-graphene slurry had a higher removal rate compared to the TiO2 slurry using the same intensity of UV light. The TiO2-graphene slurry showed a 3-fold increase in removal rate over that of a traditional CMP slurry. An experiment was also carried out where nanodiamond (50 nm and 500 nm) abrasive was added to the graphene-TiO2. As expected, the removal rate increased but the average surface roughness was poor because the nanodiamond particles caused small scratches. The graphene-TiO2 with nanodiamond abrasives has 5 times the removal rate achieved with a traditional CMP slurry. This novel method can facilitate the extensive production of well-polished single-crystal SiC wafers.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Shi X, Pan G, Zhou Y, Zou C, Gong H (2013) Extended study of the atomic step-terrace structure on hexagonal SiC (0001) by chemical mechanical planarization. Appl Surf Sci 284:195–206CrossRef Shi X, Pan G, Zhou Y, Zou C, Gong H (2013) Extended study of the atomic step-terrace structure on hexagonal SiC (0001) by chemical mechanical planarization. Appl Surf Sci 284:195–206CrossRef
3.
go back to reference Huo FW, Guo DM, Kang RK, Feng G (2012) Nanogrinding of SiC wafers with high flatness and low subsurface damage Trans. Nonferrous Met Soc China 22:3027–3033CrossRef Huo FW, Guo DM, Kang RK, Feng G (2012) Nanogrinding of SiC wafers with high flatness and low subsurface damage Trans. Nonferrous Met Soc China 22:3027–3033CrossRef
5.
go back to reference Aida H, Doi T, Takeda H (2012) Ultraprecision CMP for sapphire, GaN, and SiC for advanced optoelectronics materials. Curr Appl Phys 12:41–46CrossRef Aida H, Doi T, Takeda H (2012) Ultraprecision CMP for sapphire, GaN, and SiC for advanced optoelectronics materials. Curr Appl Phys 12:41–46CrossRef
6.
go back to reference Kikuchi M, Takahashi Y, Suga T, Suzuki S, Bando Y (1992) Mechanochemical polishing of silicon carbide single crystal with chromium (III) oxide abrasive. J American Cer Soc 75:189–194CrossRef Kikuchi M, Takahashi Y, Suga T, Suzuki S, Bando Y (1992) Mechanochemical polishing of silicon carbide single crystal with chromium (III) oxide abrasive. J American Cer Soc 75:189–194CrossRef
7.
go back to reference Zhou L, Audurier V, Pirouz P, Powell JA (1997) Chemomechanical polishing of silicon carbide. J Electrochem Soc 144:L161–L163CrossRef Zhou L, Audurier V, Pirouz P, Powell JA (1997) Chemomechanical polishing of silicon carbide. J Electrochem Soc 144:L161–L163CrossRef
8.
go back to reference Neslen CL, Mitchel WC, Hengehold RL (2001) Effects of process parameter variations on the removal rate in chemical mechanical polishing of 4H-SiC. J Electron Mater 30:1271–1275CrossRef Neslen CL, Mitchel WC, Hengehold RL (2001) Effects of process parameter variations on the removal rate in chemical mechanical polishing of 4H-SiC. J Electron Mater 30:1271–1275CrossRef
9.
go back to reference Zhu Z, Muratov V, Fischer TE (1999) Tribochemical polishing of silicon carbide in oxidant solution. Wear 225-229:848–856CrossRef Zhu Z, Muratov V, Fischer TE (1999) Tribochemical polishing of silicon carbide in oxidant solution. Wear 225-229:848–856CrossRef
10.
go back to reference Kuo P, Currier I (2006) Augmented CMP techniques for silicon carbide. Mater Sci Forum 27–529:1099–1102CrossRef Kuo P, Currier I (2006) Augmented CMP techniques for silicon carbide. Mater Sci Forum 27–529:1099–1102CrossRef
11.
go back to reference Doi TK, Sano Y, Kurowaka S, Aida H, Ohnishi O, Uneda M, Ohyama K (2014) Novel chemical mechanical polishing/plasma-chemical vaporization machining (CMP/P-CVM) combined processing of hard-to-process crystals based on innovative concepts. Sensors Mater 26:403–415 Doi TK, Sano Y, Kurowaka S, Aida H, Ohnishi O, Uneda M, Ohyama K (2014) Novel chemical mechanical polishing/plasma-chemical vaporization machining (CMP/P-CVM) combined processing of hard-to-process crystals based on innovative concepts. Sensors Mater 26:403–415
12.
go back to reference Liu HK, Chen CC, Chen WC (2017) Diamond lapping of sapphire wafers with addition of graphene in slurry. Procedia Eng 184:156–162CrossRef Liu HK, Chen CC, Chen WC (2017) Diamond lapping of sapphire wafers with addition of graphene in slurry. Procedia Eng 184:156–162CrossRef
13.
go back to reference Kubota A, Yoshimura M, Fukuyama S, Iwamoto C, Touge M (2012) Planarization of C-face 4H-SiC substrate using Fe particles and hydrogen peroxide solution. Prec Eng 36:37–140CrossRef Kubota A, Yoshimura M, Fukuyama S, Iwamoto C, Touge M (2012) Planarization of C-face 4H-SiC substrate using Fe particles and hydrogen peroxide solution. Prec Eng 36:37–140CrossRef
14.
go back to reference Yagi K, Murata J, Kubota A, Sano Y, Hara H, Okamoto T (2008) Catalyst-referred etching of 4H–SiC substrate utilizing hydroxyl radicals generated from hydrogen peroxide molecules. Surf Interface Analysis 40:998–1001CrossRef Yagi K, Murata J, Kubota A, Sano Y, Hara H, Okamoto T (2008) Catalyst-referred etching of 4H–SiC substrate utilizing hydroxyl radicals generated from hydrogen peroxide molecules. Surf Interface Analysis 40:998–1001CrossRef
15.
go back to reference Zhou Y, Pan G, Shi X, Gong H, Luo G, Gu Z (2014) Chemical mechanical planarization (CMP) of on-axis Si-face SiC wafer using catalyst nanoparticles in a slurry. Surf Coa Technol 251:48–55CrossRef Zhou Y, Pan G, Shi X, Gong H, Luo G, Gu Z (2014) Chemical mechanical planarization (CMP) of on-axis Si-face SiC wafer using catalyst nanoparticles in a slurry. Surf Coa Technol 251:48–55CrossRef
16.
go back to reference Deng H, Hosoya K, Imanishi Y, Endo K, Yamamura K (2015) Electro-chemical mechanical polishing of single-crystal SiC using CeO2 slurry. Electrochem Commun 52:5–8CrossRef Deng H, Hosoya K, Imanishi Y, Endo K, Yamamura K (2015) Electro-chemical mechanical polishing of single-crystal SiC using CeO2 slurry. Electrochem Commun 52:5–8CrossRef
17.
go back to reference Kuo P, Currier I (2006) Augmented CMP techniques for silicon carbide. Mater Sci Forum 527–529:1099–1102CrossRef Kuo P, Currier I (2006) Augmented CMP techniques for silicon carbide. Mater Sci Forum 527–529:1099–1102CrossRef
18.
go back to reference Lee HS, Kim DI, An JH, Lee HJ, Kim KH, Jeong H (2010) Hybrid polishing mechanism of single crystal SiC using mixed abrasive slurry. CIRP Ann Manuf Technol 59:333–336CrossRef Lee HS, Kim DI, An JH, Lee HJ, Kim KH, Jeong H (2010) Hybrid polishing mechanism of single crystal SiC using mixed abrasive slurry. CIRP Ann Manuf Technol 59:333–336CrossRef
19.
go back to reference Yamamura K, Takiguchi T, Ueda M, Deng H, Hattori AN, Zettsu N (2011) Plasma assisted polishing of single crystal SiC for obtaining atomically flat strain-free surface. CIRP Ann Manuf Technol 60:571–574CrossRef Yamamura K, Takiguchi T, Ueda M, Deng H, Hattori AN, Zettsu N (2011) Plasma assisted polishing of single crystal SiC for obtaining atomically flat strain-free surface. CIRP Ann Manuf Technol 60:571–574CrossRef
21.
go back to reference Deng H, Yamamura K (2013) Atomic-scale flattening mechanism of 4H-SiC (0001) in plasma assisted polishing. CIRP Ann Manuf Technol 62:575–578CrossRef Deng H, Yamamura K (2013) Atomic-scale flattening mechanism of 4H-SiC (0001) in plasma assisted polishing. CIRP Ann Manuf Technol 62:575–578CrossRef
23.
go back to reference Wang FJ, Wang ZD, Yang ZQ (2010) Study on technique of magnetorheological finishing single crystal silicon carbide. Sci Technol Innov Herald 32:112–113 Wang FJ, Wang ZD, Yang ZQ (2010) Study on technique of magnetorheological finishing single crystal silicon carbide. Sci Technol Innov Herald 32:112–113
25.
go back to reference Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339–1339CrossRef Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339–1339CrossRef
26.
go back to reference Pei S, Cheng HM (2012) The reduction of graphene oxide. Carbon 50:3210–3228CrossRef Pei S, Cheng HM (2012) The reduction of graphene oxide. Carbon 50:3210–3228CrossRef
27.
go back to reference Doi TK, Seshimo K, Yamakzi T, Ohtsubo M (2015) Building of super high-efficiency processing technology based on innovative concept (Establishment of effective polishing process of SiC substrate using Dilatancy pad tool with bowl feed method). JSME (in Japanese) 81:824 Doi TK, Seshimo K, Yamakzi T, Ohtsubo M (2015) Building of super high-efficiency processing technology based on innovative concept (Establishment of effective polishing process of SiC substrate using Dilatancy pad tool with bowl feed method). JSME (in Japanese) 81:824
28.
go back to reference Guo CS, Wang K, Hou S, Wan L, Liv JP, Zhang Y, Qu XD, Chen SY, Xu J (2017) H2O2 and/or TiO2 photocatalysis under UV irradiation for the removal of antibiotic. J Hazard Mater 323:710–718CrossRef Guo CS, Wang K, Hou S, Wan L, Liv JP, Zhang Y, Qu XD, Chen SY, Xu J (2017) H2O2 and/or TiO2 photocatalysis under UV irradiation for the removal of antibiotic. J Hazard Mater 323:710–718CrossRef
30.
go back to reference Jeng YR, Huang PY (2005) A material removal rate model considering interfacial micro-contact wear behavior for chemical mechanical polishing. J Tribol 127:190–197CrossRef Jeng YR, Huang PY (2005) A material removal rate model considering interfacial micro-contact wear behavior for chemical mechanical polishing. J Tribol 127:190–197CrossRef
Metadata
Title
Polishing single-crystal silicon carbide with porous structure diamond and graphene-TiO2 slurries
Authors
Ming Yi Tsai
Zuan Tang Hoo
Publication date
12-09-2019
Publisher
Springer London
Published in
The International Journal of Advanced Manufacturing Technology / Issue 1-4/2019
Print ISSN: 0268-3768
Electronic ISSN: 1433-3015
DOI
https://doi.org/10.1007/s00170-019-04223-x

Other articles of this Issue 1-4/2019

The International Journal of Advanced Manufacturing Technology 1-4/2019 Go to the issue

Premium Partners