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Journal of Materials Science

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02-04-2020 | Polymers & biopolymers

Polyrotaxane crosslinked modified EC/PVDF composite membrane displaying simultaneously enhanced pervaporation performance and solvent resistance for benzene/cyclohexane separation

Authors: Yuhui Zhang, Ligang Lin, Qi Wang, Rongrong Qiang, Yixin Gao, Sisi Ma, Qi Cheng, Yuzhong Zhang

Published in: Journal of Materials Science | Issue 19/2020

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Abstract

A new strategy was proposed that simultaneously improves the pervaporation (PV) performance and solvent resistance via the construction of a movable crosslinked structure in ethyl cellulose/polyvinylidene fluoride (EC/PVDF) composite membrane for the purpose of benzene/cyclohexane separation. Based on the molecular design of the macrocyclic compound cyclodextrin, polyrotaxane crosslinking agent (PR=) with a special sliding/rotating property and cavity structure was successfully synthesized. Furthermore, for convenient comparative study, cyclodextrin crosslinking agent (CD=) with cavity structure bereft of a sliding/rotating property and pentaerythritol triacrylate (PETA) without sliding/rotating property and cavity structure were prepared. The composite membranes were fabricated with crosslinking modified EC as active layer, together with PVDF support layer. The molecular structure and microstructure were confirmed. The pervaporation and swelling performance of the fabricated membranes for benzene/cyclohexane were investigated. PR= modified membranes showed good solvent resistance and exhibited a flux of 4332 g·m⁻²·h⁻¹ and separation factor of 6.26, which was higher than CD= and PETA modified membranes. The results were attributed to the facilitated transport behavior, which was markedly related with the sliding/rotating property and cavity structure of polyrotaxane (PR). The related research provides interesting suggestions for PV membrane design for the separation of organic mixtures.

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Baker RW (2012) Membrane technology and applications. Wiley, New York, p 592CrossRef

Moulik S, Vani B, Chandrasekhar S, Sridhar S (2018) Chitosan- polytetrafluoroethylene composite membranes for separation of methanol and toluene by pervaporatio. Carbohydr Polym 193:28–38CrossRef

Wang N, Wu T, Wang L, Li X, Zhao C, Li J, Ji S (2017) Hyperbranched polymer composite membrane using water as solvent for separating aromatic/aliphatic hydrocarbon mixtures. Sep Purif Technol 179:225–235CrossRef

Liu L, Wang N, Liu H, Shu L, Xie Y, Li J, An Q (2019) Nano-array assisted metal-organic polyhedra membranes for the pervaporation of aromatic/aliphatic mixtures. J Membr Sci 575:1–8CrossRef

Villaluenga JPG, Tabe-Mohammadi A (2000) A review on the separation of benzene/cyclohexane mixtures by pervaporation processes. J Membr Sci 169:159–174CrossRef

Aouinti L, Roizard D, Belbachir M (2015) PVC-activated carbon-based matrices: a promising combination for pervaporation membranes useful for aromatic-alkane separations. Sep Purif Technol 147:51–61CrossRef

Yu S, Jiang Z, Ding H, Pan F, Wang B, Yang J, Cao X (2015) Elevated pervaporation performance of polysiloxane membrane using channels and active sites of metal organic framework CuBTC. J Membr Sci 481:73–81CrossRef

Zheng P, Li X, Wu J, Wang N, Li J, An Q (2018) Enhanced butanol selectivity of pervaporation membrane with fluorinated monolayer on polydimethylsiloxane surface. J Membr Sci 548:215–222CrossRef

Smitha B, Suhanya D, Sridhar S, Ramakrishna M (2004) Separation of organic-organic mixtures by pervaporation—a review. J Membr Sci 241:1–21CrossRef

10.

Khazaei A, Mohebbi V, Behbahani RM, Ramazani SAA (2018) Energy consumption in pervaporation, conventional and hybrid processes to separate toluene and i-octane. Chem Eng Process 128:46–52CrossRef

11.

Jiang L, Wang Y, Chung T, Qiao X, Lai J (2009) Polyimides membranes for pervaporation and biofuels separation. Prog Polym Sci 24:1135–1160CrossRef

12.

Dai S, Jiang Y, Wang T, Wu L, Yu X, Lin J, Shi S (2016) Enhanced performance of polyimide hybrid membranes for benzene separation by incorporating three-dimensional silver-graphene oxide. J Colloid Interface Sci 478:145–154CrossRef

13.

Wang M, Xing R, Wu H, Pan F, Zhang J, Ding H, Jiang Z (2017) Nanocomposite membranes based on alginate matrix and high loading of pegylated POSS for pervaporation dehydration. J Membr Sci 538:86–95CrossRef

14.

Murthy ZVP, Shah MK (2017) Separation of isopropyl alcohol-toluene mixtures by pervaporation using poly(vinyl alcohol) membrane. Arab J Chem 10:527–537CrossRef

15.

Fan S, Liu J, Tang X, Wang W, Xiao Z, Qiu B, Wang Y, Jian S, Qin Y, Wang Y (2018) Process operation performance of PDMS membrane pervaporation coupled with fermentation for efficient bioethanol production. Chin J Chem Eng. https://doi.org/10.1016/j.cjche.2018.12.005CrossRef

16.

Okeowo O, Nam S, Dorgan J (2008) Nonequilibrium nanoblend membranes for the pervaporation of benzene/cyclohexane mixtures. J Appl Polym Sci 108:2917–2922CrossRef

17.

Pulyalina AY, Polotskaya GA, Veremeychik КY, Goikhman MY, Podeshvo IV, Toikka AM (2015) Ethanol purification from methanol via pervaporation using polybenzoxazinoneimide membrane. Fuel Process Technol 139:178–185CrossRef

18.

Baheri B, Mohammadi T (2017) Sorption, diffusion and pervaporation study of thiophene/n-heptane mixture through self-support PU/PEG blend membrane. Sep Purif Technol 185:112–119CrossRef

19.

L. Liu, E. Sandra. Kentish. Pervaporation performance of crosslinked PVA membranes in the vicinity of the glass transition temperature. J Membr Sci 553 (2018) 63–69.

20.

Yi S, Wan Y (2017) Volatile organic compounds (VOCs) recovery from aqueous solutions via pervaporation with vinyltriethoxysilane-grafted-silicalite-1/polydimethylsiloxane mixed matrix membrane. Chem Eng J 313:1639–1646CrossRef

21.

Zhang W, Ying Y, Ma J, Guo X, Huang H, Liu D, Zhong C (2017) Mixed matrix membranes incorporated with polydopamine-coated metal-organic framework for dehydration of ethylene glycol by pervaporation. J Membr Sci 527:8–17CrossRef

22.

Khan A, Ali M, Ilyas A, Naik P, Vankelecom IFJ, Gilani MA, Bilad MR, Sajjad Z, Khan AL (2018) ZIF-67 filled PDMS mixed matrix membranes for recovery of ethanol via pervaporation. Sep Purif Technol 206:50–58CrossRef

23.

Huang Z, Ru X, Zhu Y, Guo Y, Teng L (2019) Poly(vinyl alcohol)/ZSM-5 zeolite mixed matrix membranes for pervaporation dehydration of isopropanol/water solution through response surface methodology. Chem Eng Res Des 144:19–34CrossRef

24.

Zhan X, Lu J, Xu H, Liu J, Liu X, Cao X, Li J (2019) Enhanced pervaporation performance of PDMS membranes based on nanosized Octa[(trimethoxysilyl)ethyl]-POSS as macro-crosslinker. Appl Surf Sci 473:785–798CrossRef

25.

A. Khazaei, V. Mohebbi, R. M. Behbahani, A. Ramazani S.A. Pervaporation of toluene and iso-octane through poly(vinyl alcohol)/graphene oxide nanoplate mixed matrix membranes: Comparison of crosslinked and noncrosslinked membranes. J Appl Polym Sci 135 (2017) 45853.

26.

Liu H, Wang N, Cui C, Ji S, Li J (2018) Membrane materials in the pervaporation separation of aromatic/aliphatic hydrocarbon mixtures—a review. Chin J Chem Eng 26:1–16CrossRef

27.

Zheng H, Yoshikawa M (2015) Molecularly imprinted cellulose membranes for pervaporation separation of xylene isomers. J Membr Sci 478:148–154CrossRef

28.

Rynkowska E, Dzieszkowski K, Lancien A, Fatyeyeva K, Szymczyk A, Kujawski W (2017) Physicochemical properties and pervaporation performance of dense membranes based on cellulose acetate propionate (CAP) and containing polymerizable ionic liquid (PIL). J Membr Sci 544:243–251CrossRef

29.

Wang Y, Yang L, Luo G, Dai Y (2009) Preparation of cellulose acetate membrane filled with metal oxide particles for the pervaporation separation of methanol/methyl tert-butyl ether mixtures. Chem Eng J 146:6–10CrossRef

30.

Qu H, Kong Y, Lv H, Zhang Y, Yang J, Shi D (2010) Effect of crosslinking on sorption, diffusion and pervaporation of gasoline components in hydroxyethyl cellulose membranes. Chem Eng J 157:60–66CrossRef

31.

Uragami T, Tsukamoto K, Miyata T (2005) Permeation and separation characteristics of a mixture of benzene/cyclohexane through cellulose alkyl ester membranes during pervaporation. Macromol Chem Phys 206:642–648CrossRef

32.

Kato K, Ito K (2013) Polymer networks characterized by slidable crosslinks and the asynchronous dynamics of interlocked components. React Funct Polym 73:405–412CrossRef

33.

L. Lin, M. Dong, C. Liu, H. Sun. L. Zhang, C.Zhang, P. Deng, Y. Li. Building movable bridges in membrane matrix by polyrotaxane crosslinking for sulfur removal. Mater Lett 126 (2014) 59–62.

34.

Jang K, Iijima K, Koyama Y, Uchida S, Asai S, Takata T (2017) Synthesis and properties of rotaxane-cross-linked polymers using a double-stranded γ-CD-based inclusion complex as a supramolecular cross-linker. Polymer 128:379–385CrossRef

35.

Selin M, Peltonen L, Hirvonen J, Bimbo LM (2016) Dendrimers and their supramolecular nanostructures for biomedical applications. J Drug Deliv Sci Technol 34:10–20CrossRef

36.

Dong R, Zhou Y, Huang X, Zhu X, Lu Y, Shen J (2015) Functional supramolecular polymers for biomedical applications. Adv Mater 27:498–526CrossRef

37.

Li X, Wang Y, Wu R, Pan Y, Zheng Z, Ding X (2017) Slide-ring shape memory polymers with movable cross-links. React Funct Polym 119:26–36CrossRef

38.

Murakami H, Baba R, Fukushima M, Nonaka N (2015) Synthesis and characterization of polyurethanes crosslinked by polyrotaxanes consisting of half-methylated cyclodextrins and PEGs with different chain lengths. Polymer 56:368–374CrossRef

39.

Tardy BL, Dam HH, Kamphuis MMJ, Richardson JJ, Caruso F (2014) Self-assembled stimuli-responsive polyrotaxane co-shell particles. Biomacromol 15:53–59CrossRef

40.

Zhao T, Beckham HW (2003) Direct synthesis of cyclodextrin-rotaxanated poly(ethylene glycol)s and their self-diffusion behavior in dilute solution. Macromolecules 36(26):9859–9865CrossRef

41.

Ma S, Lin L, Wang Q, Zhang Y, Zhang H, Gao Y, Xu L, Pan F, Zhang Y (2019) Bioinspired EVAL membrane modified with cilia-like structures showing simultaneously enhanced permeability and antifouling properties. Colloids Surf B 181:134–142CrossRef

42.

Imran AB, Seki T, Kataoka T, Kitowaki M, Ito K, Takeoka Y (2008) Fabrication of mechanically improved hydrogels using a movable cross-linker based on vinyl modified polyrotaxane. Chem Commun 41:5227–5229CrossRef

43.

Zeng K, Zheng S (2009) Synthesis and characterization of organic/inorganic polyrotaxanes from polyhedral oligomeric silsesquioxane and poly (ethylene oxide)/α-cyclodextrin polypseudorotaxanes via click Chemistry. Macromol Chem Phys 210:783–791CrossRef

44.

Wu J, He H, Gao C (2010) β-cyclodextrin-capped polyrotaxanes: one-pot facile synthesis via click. Macromolecules 43:2252–2260CrossRef

45.

Chen J, Huang X, Zhu Y, Jiang P (2017) Cellulose nanofiber supported 3D interconnected BN nanosheets for epoxy nanocomposites with ultrahigh thermal management capability. Adv Funct Mater 27:1604754CrossRef

46.

Jiang F, Cui S, Rungnim C, Song N, Shi L, Ding P (2019) Control of a dual-cross-linked boron nitride framework and the optimized design of the thermal conductive network for its thermoresponsive polymeric composites. Chem Mater 31:7685–7695

47.

Farahani MHDA, Chung TS (2019) A novel crosslinking technique towards the fabrication of high-flux polybenzimidazole (PBI) membranes for organic solvent nanofiltration (OSN). Sep Purif Technol 209:182–192CrossRef

48.

Cheng C, Li P, Zhang T, Wang X, Hsiao BS (2019) Enhanced pervaporation performance of polyamide membrane with synergistic effect of porous nanofibrous support and trace graphene oxide lamellae. Chem Eng Sci 196:265–276CrossRef

49.

S. Qiu, L. Wu, G. Shi., L. Zhang, H. Chen, C. Gao. Preparation and pervaporation property of chitosan membrane with functionalized multiwalled carbon nanotubes. Ind Eng Chem Res 49 (2010) 11667–11675.

50.

Yi S, Su Y, Wan Y (2010) Preparation and characterization of vinyltriethoxysilane (VTES) modified silicalite-1/PDMS hybrid pervaporation membrane and its application in ethanol separation from dilute aqueous solution. J Membr Sci 360:341–351CrossRef

51.

Zhang P, Qian J, Yang Y, Bai Y, An Q, Yan W (2007) Swelling behavior of palygorskite-polyacrylamide hybrid membrane in xylene mixtures and its pervaporation performance for separating the xylene isomers. J Membr Sci 288:280–289CrossRef

52.

Yang L, Kang Y, Wang Y, Xu L, Kita H, Okamoto K (2005) Synthesis of crown ether-containing copolyimides and their pervaporation properties to benzene/cyclohexane mixtures. J Membr Sci 249:33–39CrossRef

53.

J. Shen, Y. Chu, H. Ruan, L. Wu, C. Gao, Bart Van der Bruggen. Pervaporation of benzene/cyclohexane mixtures through mixed matrix membranes of chitosan and Ag+/carbon nanotubes. J Membr Sci 462 (2014) 160–169.

54.

Maji S, Banerjee S (2010) Preparation of new semifluorinated aromatic poly(ether amide)s and evaluation of pervaporation performance for benzene/cyclohexane 50/50 mixture. J Membr Sci 349:145–155CrossRef

Title: Polyrotaxane crosslinked modified EC/PVDF composite membrane displaying simultaneously enhanced pervaporation performance and solvent resistance for benzene/cyclohexane separation
Authors: Yuhui Zhang
Ligang Lin
Qi Wang
Rongrong Qiang
Yixin Gao
Sisi Ma
Qi Cheng
Yuzhong Zhang
Publication date: 02-04-2020
Publisher: Springer US
Published in: Journal of Materials Science / Issue 19/2020
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-020-04609-3

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