Top

International Journal of Plastics Technology

Published in:

13-10-2018 | Research Article

Prediction of equilibrium swelling ratio on synthesized polyacrylamide hydrogel using central composite design modeling

Authors: S. Hamri, D. Lerari, M. Sehailia, B. Dali-Youcef, T. Bouchaour, K. Bachari

Published in: International Journal of Plastics Technology | Issue 2/2018

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Central composite design was successfully applied to predict the equilibrium swelling ratio (Y) of a crosslinked polyacrylamide (PAM) hydrogel. Samples were prepared by a facile, simple and efficient photochemical method, using Eosin Y/triethanolamine system as a photo-initiator and 1,6-hexanedioldiacrylate as a crosslinker. The mathematical relationship between the equilibrium swelling ratio and both experimental factors, i.e., temperature (X₁) and degree of crosslinking (X₂), was evaluated by a second-order quadratic model. The individual and interactive effects of these two parameters were described according to response surface modeling approach. This model allows to predefine the values of the equilibrium swelling ratio of the crosslinked PAM based on experimental conditions, i.e., temperature and degree of crosslinking within intervals [21–78 °C] and [0.75–9%], respectively. As a result, facilitating its application in areas such as drug delivery technology where controlling the swelling of a polymer allows further controlling of drug release. All predicted values were in full agreement with our experimental results [R² 99.85% and R² (adj) of 99.69% for response Y].

previous article Thermal, electrical and characterization effects of graphene on the properties of low-density polyethylene composites

next article Develop fuzzy logic inference system to predict carbon fiber-reinforced polypropylene hybrid composite’s shrinkage

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Ahmed EM (2015) Hydrogel: preparation, characterization, and applications: a review. J Adv Res 6:105–121. https://doi.org/10.1016/j.jare.2013.07.006 CrossRefPubMed

Shi Z, Gao Z, Ullah MW, Li S, Wang Q, Yang G (2016) Electroconductive natural polymer-based hydrogels. Biomaterials 111:40–54. https://doi.org/10.1016/j.biomaterials.2016.09.020 CrossRefPubMed

Primo GA, Igarzabal CIA, Pino GA, Ferrero JC, Rossa M (2016) Surface morphological modification of crosslinked hydrophilic co-polymers by nanosecond pulsed laser irradiation. Appl Surf Sci 369:422–429. https://doi.org/10.1016/j.apsusc.2016.02.047 CrossRef

Zheng Y, Wang A (2015) Superadsorbent with three-dimensional networks: from bulk hydrogel to granular hydrogel. Eur Polym J 72:661–686. https://doi.org/10.1016/j.eurpolymj.2015.02.031 CrossRef

Trimaille T, Pertici V, Gigmes D (2016) Recent advances in synthetic polymer based hydrogels for spinal cord repair. C R Chim 19:157–166. https://doi.org/10.1016/j.crci.2015.03.016 CrossRef

Sharma K, Kumar V, Chaudhary B, Kaith BS, Kalia S, Swart HC (2016) Application of biodegradable superabsorbent hydrogel composite based on Gum ghatti-co-poly(acrylic acid-aniline) for controlled drug delivery. Polym Degrad Stab 124:101–111. https://doi.org/10.1016/j.polymdegradstab.2015.12.021 CrossRef

Kakkar P, Madhan B (2016) Fabrication of keratin–silica hydrogel for biomedical applications. Mater Sci Eng C 66:178–184. https://doi.org/10.1016/j.msec.2016.04.067 CrossRef

Singh B, Sharma V (2017) Crosslinking of poly(vinylpyrrolidone)/acrylic acid with tragacanth gum for hydrogels formation for use in drug delivery applications. Carbohydr Polym 157:185–195. https://doi.org/10.1016/j.carbpol.2016.09.086 CrossRefPubMed

Gulsonbi M, Parthasarathy S, Bharat Raj K, Jaisankar V (2016) Green synthesis, characterization and drug delivery applications of a novel silver/carboxymethylcellulose–poly(acrylamide) hydrogel nanocomposite. Ecotoxicol Environ Saf 134:421–426. https://doi.org/10.1016/j.ecoenv.2015.10.031 CrossRefPubMed

10.

Silva D, Fernandes AC, Nunes TG, Colaço R, Serro AP (2015) The effect of albumin and cholesterol on the biotribological behavior of hydrogels for contact lenses. Acta Biomater 26:184–194. https://doi.org/10.1016/j.actbio.2015.08.011 CrossRefPubMed

11.

Lee YK, Lin YC, Tsai SH, Chen WL, Chen YM (2016) Therapeutic outcomes of combined topical autologous serum eye drops with silicone–hydrogel soft contact lenses in the treatment of corneal persistent epithelial defects: a preliminary study. Cont Lens Anterior Eye 39:425–430. https://doi.org/10.1016/j.clae.2016.06.003 CrossRefPubMed

12.

Pimenta AFR, Ascenso J, Fernandes JCS, Colaço R, Serro AP, Saramago B (2016) Controlled drug release from hydrogels for contact lenses: drug partitioning and diffusion. Int J Pharm 515:467–475. https://doi.org/10.1016/j.ijpharm.2016.10.047 CrossRefPubMed

13.

Vulpe R, Popa M, Picton L, Balan V, Dulong V, Butnaru M, Verestiuc L (2016) Crosslinked hydrogels based on biological macromolecules with potential use in skin tissue engineering. Int J Biol Macromol 84:174–181. https://doi.org/10.1016/j.ijbiomac.2015.12.019 CrossRefPubMed

14.

Baei P, Jalili-Firoozinezhad S, Rajabi-Zeleti S, Tafazzoli-Shadpour M, Baharvand H, Aghdami N (2016) Electrically conductive gold nanoparticle-chitosan thermosensitive hydrogels for cardiac tissue engineering. Mater Sci Eng C 63:131–141. https://doi.org/10.1016/j.msec.2016.02.056 CrossRef

15.

Defu L, Youxin Y, Derong L, Xinying L, Changdao M (2016) Biological properties of dialdehyde carboxymethyl cellulose crosslinked gelatin-PEG composite hydrogel fibers for wound dressings. Carbohydr Polym 137:508–514. https://doi.org/10.1016/j.carbpol.2015.11.024 CrossRef

16.

Yoon DS, Lee Y, Ryu HA, Jang Y, Lee KM, Choi Y, Choi WJ, Lee M, Park KM, Park KD, Lee JW (2016) Cell recruiting chemokine-loaded sprayable gelatin hydrogel dressings for diabetic wound healing. Acta Biomater 38:59–68. https://doi.org/10.1016/j.actbio.2016.04.030 CrossRefPubMed

17.

Sheng-Yuan K, Chung-Wei K, Hsin-Wei C, Chih-Wei H, Kuo-Chuan H (2016) An electrochromic device based on all-in-one polymer gel through in situ thermal polymerization. Sol Energy Mater Sol Cells 145:61–68. https://doi.org/10.1016/j.solmat.2015.04.012 CrossRef

18.

Ping Y, Suchun J, Jianghuai H, Xueping H, Ke Z, Gang Y (2016) Systematic study on highly efficient thermal synergistic polymerization effect between alicyclic imide moiety and phthalonitrile: scope, properties and mechanism. Polymer 102:266–280. https://doi.org/10.1016/j.polymer.2016.09.025 CrossRef

19.

Kasisomayajula S, Jadhav N, Gelling VJ (2016) Conductive polypyrrole and acrylate nanocomposite coatings: mechanistic study on simultaneous photopolymerization. Prog Org Coat 101:440–454. https://doi.org/10.1016/j.porgcoat.2016.07.023 CrossRef

20.

Hamri S, Bouchaour T (2016) pH-dependent swelling behaviour of interpenetrating polymer network hydrogels based on poly(hydroxybutyl methacrylate) and poly(2-hydroxyethyl methacrylate). Int J Plast Technol 20:279–293. https://doi.org/10.1007/s12588-016-9155-2 CrossRef

21.

Zhang H, Niu Q, Wang N, Nie J, Ma G (2015) Thermo-sensitive drug controlled release PLA core/PNIPAM shell fibers fabricated using a combination of electrospinning and UV photo-polymerization. Eur Polym J 71:440–450. https://doi.org/10.1016/j.eurpolymj.2015.08.023 CrossRef

22.

Xiao P, Zhang J, Dumur F, Tehfe MA, Morlet-Savary F, Graff B, Gigmes D, Fouassier JP, Lalevée J (2015) Visible light sensitive photoinitiating systems: recent progress in cationic and radical photopolymerization reactions under soft conditions. Prog Polym Sci 41:32–66. https://doi.org/10.1016/j.progpolymsci.2014.09.001 CrossRef

23.

Encinas MV, Rufs AM, Bertolotti SG, Previtali CM (2009) Xanthene dyes/amine as photoinitiators of radical polymerization: a comparative and photochemical study in aqueous medium. Polymer 50:2762–2767. https://doi.org/10.1016/j.polymer.2009.04.024 CrossRef

24.

Shaibani PM, Jiang K, Haghighat G, Hassanpourfard M, Etayash H, Naicker S, Thundat T (2016) The detection of Escherichia coli (E. coli) with the pH sensitive hydrogel nanofiber-light addressable potentiometric sensor (NF-LAPS). Sens Actuator B Chem 226:176–183. https://doi.org/10.1016/j.snb.2015.11.135 CrossRef

25.

Yang K, Wan S, Chen B, Gao W, Chen J, Liu M, He B, Wu H (2016) Dual pH and temperature responsive hydrogels based on β-cyclodextrin derivatives for atorvastatin delivery. Carbohydr Polym 136:300–306. https://doi.org/10.1016/j.carbpol.2015.08.096 CrossRefPubMed

26.

Hanmin Z, Jianjun L, Hongtao C, Haijun L, Fenglin Y (2015) Forward osmosis using electric-responsive polymer hydrogels as draw agents: Influence of freezing–thawing cycles, voltage, feed solutions on process performance. Chem Eng J 259:814–819. https://doi.org/10.1016/j.cej.2014.08.065 CrossRef

27.

Wang Y, Dong A, Yuan Z, Chen D (2012) Fabrication and characterization of temperature-, pH- and magnetic-field-sensitive organic/inorganic hybrid poly (ethylene glycol)-based hydrogels. Colloids Surf A 415:68–76. https://doi.org/10.1016/j.colsurfa.2012.10.009 CrossRef

28.

Ghaedi M, Hajati S, Zare M, Zare M, Shajaripour Jaberi SY (2015) Experimental design for simultaneous analysis of malachite green and methylene blue; derivative spectrophotometry and principal component-artificial neural network. RSC Adv 5:38939–38947. https://doi.org/10.1039/C5RA02531A CrossRef

29.

Roosta M, Ghaedi M, Asfaram A (2015) Simultaneous ultrasonic-assisted removal of malachite green and safranin O by copper nanowires loaded on activated carbon: central composite design optimization. RSC Adv 5:57021–57029. https://doi.org/10.1039/c5ra03519h CrossRef

30.

Raheem A, Wan Azlina WAKG, Taufiq Yap YH, Danguah MK, Harun R (2015) Optimization of the microalgae Chlorella vulgaris for syngas production using central composite design. RSC Adv 5:71805–71815. https://doi.org/10.1039/C5RA10503J CrossRef

31.

Hongtao X, Paxton J, Lim J, Yan L, Zimei W (2014) Development of a gradient high performance liquid chromatography assay for simultaneous analysis of hydrophilic gemcitabine and lipophilic curcumin using a central composite design and its application in liposome development. J Pharm Biomed Anal 98:371–378. https://doi.org/10.1016/j.jpba.2014.06.022 CrossRef

32.

Sugashini S, Begum KMMS (2013) Optimization using central composite design (CCD) for the biosorption of Cr(VI) ions by cross linked chitosan carbonized rice husk (CCACR). Clean Technol Environ Policy 15:293–302. https://doi.org/10.1007/s10098-012-0512-3 CrossRef

33.

Ghaedi M, Mazaheri H, Khodadoust S, Hajati S, Purkait MK (2015) Application of central composite design for simultaneous removal of methylene blue and Pb²⁺ ions by walnut wood activated carbon. Spectrochim Acta A Mol Biomol Spectrosc 135:479–490. https://doi.org/10.1016/j.saa.2014.06.138 CrossRefPubMed

34.

Nazari A, Mirjalili M, Nasirizadeh N, Torabian S (2015) Optimization of nano TiO₂ pretreatment on free acid dyeing of wool using central composite design. J Ind Eng Chem 21:1068–1076. https://doi.org/10.1016/j.jiec.2014.05.017 CrossRef

35.

Ruitao L, Guosheng Y (2015) Bayes factor and posterior probability: complementary statistical evidence to p-value. Contemp Clin Trials 44:33–35. https://doi.org/10.1016/j.cct.2015.07.001 CrossRef

36.

Feng Y, Aman U (2013) A nonparametric R² test for the presence of relevant variables. J Stat Plan Inference 143:1527–1547. https://doi.org/10.1016/j.jspi.2013.03.026 CrossRef

37.

Ting L, Yuanlong L, Nigel G, Wenzheng Y, David R, Kening S (2017) Application of polyacrylamide flocculation with and without alum coagulation for mitigating ultrafiltration membrane fouling: role of floc structure and bacterial activity. Chem Eng J 307:41–48. https://doi.org/10.1016/j.cej.2016.08.063 CrossRef

Title: Prediction of equilibrium swelling ratio on synthesized polyacrylamide hydrogel using central composite design modeling
Authors: S. Hamri
D. Lerari
M. Sehailia
B. Dali-Youcef
T. Bouchaour
K. Bachari
Publication date: 13-10-2018
Publisher: Springer India
Published in: International Journal of Plastics Technology / Issue 2/2018
Print ISSN: 0972-656X
Electronic ISSN: 0975-072X
DOI: https://doi.org/10.1007/s12588-018-9224-9

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 2/2018

Critical review on agrowaste cellulose applications for biopolymers

Thermoplastic composites between polybutylene succinate and recycled PET adding hollow glass microspheres

The effects of natural polyphenols and calcium-based thermal stabilizer on the rheological and thermal resistance behaviors of PVC

Thermal, electrical and characterization effects of graphene on the properties of low-density polyethylene composites

Freestanding flexible composite films of CdS-impregnated cellulose nanocrystals/PVDF: synthesis and characterization

Retraction Note to: Investigation on the improvement of physico-mechanical, viscoelastic and morphological properties of isotactic polypropylene (iPP)/ethylene-propylene diene rubber (EPDM)/nitrile rubber (NBR) elastomeric blends

Premium Partners