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Journal of Materials Science
Published in: Journal of Materials Science 44/2022

15-11-2022 | Electronic materials

Preparation and photocatalytic property of exfoliated poly(phenylenethiazolo[5,4‐d]thiazole) copolymers

Authors: Meiqi Ren, Xiaoli Dong, Yu Wang, Nan Zheng, Hongchao Ma, Xiufang Zhang

Published in: Journal of Materials Science | Issue 44/2022

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Abstract

Conjugated microporous polymers have attracted significant attention in recent years due to their high porosity, broad functionality and excellent chemical stability. In this work, the small-sized layered structure of poly(phenylenethiazolo[5,4-d]thiazole) (p-PhTT) copolymer was achieved by a facile solvothermal-assisted exfoliation process in a polar organic solvent. Owing to the shorter diffusion length, the layered structure could enhance carrier diffusion from the interior to the surface, as well as provide more active sites in photocatalytic reaction. The obtained exfoliated p-PhTT copolymers show good dispersion and stability in aqueous solution and exhibit efficiently photocatalytic activity for degrading rhodamine B dye under visible-light irradiation. This effective method offers a promising strategy for exfoliating other organic porous polymers.

Graphical Abstract

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Appendix
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Metadata
Title
Preparation and photocatalytic property of exfoliated poly(phenylenethiazolo[5,4‐d]thiazole) copolymers
Authors
Meiqi Ren
Xiaoli Dong
Yu Wang
Nan Zheng
Hongchao Ma
Xiufang Zhang
Publication date
15-11-2022
Publisher
Springer US
Published in
Journal of Materials Science / Issue 44/2022
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-022-07898-y

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