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Topics in Catalysis
Published in: Topics in Catalysis 14-16/2014

01-09-2014 | Original Paper

Promoted NiO Catalysts for the Oxidative Dehydrogenation of Ethane

Authors: José M. López Nieto, Benjamín Solsona, Robert K. Grasselli, Patricia Concepción

Published in: Topics in Catalysis | Issue 14-16/2014

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Abstract

Metal oxide promoted NiO catalysts with a Ni/(Me + Ni) atomic ratio 0.92 have been investigated for the oxidative dehydrogenation of ethane. These materials have been characterized by several techniques (N2-adsorption, X-ray diffraction, X-ray photoelectron spectroscopy and Fourier transformed infrared spectroscopy of adsorbed CO and ethylene). The nature of surface sites is strongly influenced by the valence and the acid/base characteristics of the metal oxide promoters, which have a great impact on the selectivity to ethylene. Accordingly, a clear correlation between selectivity to ethylene and the valence of the promoter has been observed in the present work. Additionally, the acidity of the catalyst also enhances the selectivity to ethylene.
previous article Highly Selective Supported Alkali Chloride Catalysts for the Oxidative Dehydrogenation of Ethane
next article Formation Mechanism of Alkyl Nitrites, Valuable Intermediates in C1-Upgrading Chemistry and Oxidation Processes

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Appendix
Available only for authorised users
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Metadata
Title
Promoted NiO Catalysts for the Oxidative Dehydrogenation of Ethane
Authors
José M. López Nieto
Benjamín Solsona
Robert K. Grasselli
Patricia Concepción
Publication date
01-09-2014
Publisher
Springer US
Published in
Topics in Catalysis / Issue 14-16/2014
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-014-0288-2

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