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Journal of Materials Science
Published in: Journal of Materials Science 4/2020

20-09-2019 | Metals & corrosion

Protective action of semi-fluorinated perfluorocyclobutyl polymer coatings against corrosion of mild steel

Authors: Eugene B. Caldona, Dennis W. Smith Jr., David O. Wipf

Published in: Journal of Materials Science | Issue 4/2020

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Abstract

This study examines perfluorocyclobutyl (PFCB) aromatic ether polymers and demonstrates, for the first time, their potential as corrosion-resistant coatings. PFCB polymers are a distinct class of semi-fluorinated polymers that are based on thermal cyclopolymerization of aromatic trifluorovinyl ethers. They combine the flexibility and thermal stability of aromatic ethers with strong fluorocarbon linkages. Electrochemical impedance spectroscopy and potentiodynamic scans reveal that PFCB coatings display protective barrier properties against corrosion attack nearly equal to that of polyvinylidene fluoride (PVDF) coatings. The PFCBs also show excellent adhesion to metal surfaces and nonstick properties comparable to that of PVDF. Combined with their high thermal resistance, PFCBs may lead to new corrosion-resistant coatings in marine, oil and gas, and other applications.
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Metadata
Title
Protective action of semi-fluorinated perfluorocyclobutyl polymer coatings against corrosion of mild steel
Authors
Eugene B. Caldona
Dennis W. Smith Jr.
David O. Wipf
Publication date
20-09-2019
Publisher
Springer US
Published in
Journal of Materials Science / Issue 4/2020
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-04025-2

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