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Published in: Environmental Earth Sciences 4/2017

01-02-2017 | Original Article

Quantitative analysis for the effect of microstructure on the mechanical strength of frozen silty clay with different contents of sodium sulfate

Authors: Zhemin You, Yuanming Lai, Mingyi Zhang, Enlong Liu

Published in: Environmental Earth Sciences | Issue 4/2017

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Abstract

Microstructural transformation is known substantially to be the reason for the differences in mechanical behavior and the failure mechanism of saline soil. The mechanical strength of frozen saline soil decreases by 19.0% initially and then increases by 49.3% with the increasing mass content of sodium sulfate, with the threshold value of 1.5%. To explain the mechanism of this phenomenon, mercury intrusion porosity and scanning electron microscope were adopted to obtain the pore size distributions and microstructural characteristics of silty clay with different mass contents of sodium sulfate at 0.0, 1.5, 2.5 and 5.0%, respectively. The microstructural parameters were calculated by the Image-Pro Plus software based on the threshold of 75 and magnification of 1000× and 2000×. The porosity increases firstly and reduces with the rising salt content, and the fractal dimension is affected slightly ranging from 1.18 to 1.23. As the salt content increases from 0.0 to 1.5%, salts dissolve completely and the thickness of liquid film increases, so does the pore volume, and the friction of soil particles and the mechanical strength decreases. When the salt content is beyond the threshold value, the solution in soil is supersaturated, and salts crystallize and fill the pores and deduce the pore volume. The increasing interlocking abilities between crystals and particles enhance the mechanical strength of frozen saline soil. The results can provide a theoretical guidance to predict the frost and salt heave of frozen saline soil engineering.

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Literature
go back to reference Agudo ER, Mees F, Jacobs P (2007) The role of saline solution properties on porous limestone salt weathering by magnesium and sodium sulfates. Environ Geol 52:269–281CrossRef Agudo ER, Mees F, Jacobs P (2007) The role of saline solution properties on porous limestone salt weathering by magnesium and sodium sulfates. Environ Geol 52:269–281CrossRef
go back to reference Cheng GD, Jiang H, Wang KL et al (2003) Thawing index and freezing index on the embankment surface in permafrost regions. J Glaciol Geocryol 25(6):603–607 Cheng GD, Jiang H, Wang KL et al (2003) Thawing index and freezing index on the embankment surface in permafrost regions. J Glaciol Geocryol 25(6):603–607
go back to reference Correns VCW, Steinborn W (1939) Experimente zur Messung und Erklärung der sogenannten Kristallisationskraft. Zeitschrift für Kristallographie-Crystalline Materials A 101:117–133 Correns VCW, Steinborn W (1939) Experimente zur Messung und Erklärung der sogenannten Kristallisationskraft. Zeitschrift für Kristallographie-Crystalline Materials A 101:117–133
go back to reference Derluyn H (2014) Deformation and damage due to drying-induced salt crystallization in porous limestone. J Mech Phys Solids 63:242–255CrossRef Derluyn H (2014) Deformation and damage due to drying-induced salt crystallization in porous limestone. J Mech Phys Solids 63:242–255CrossRef
go back to reference Diamond S (2000) Mercury porosimetry-an inappropriate method for the measurement of pore size distributions in cement-based materials. Cem Concr Res 30:1517–1525CrossRef Diamond S (2000) Mercury porosimetry-an inappropriate method for the measurement of pore size distributions in cement-based materials. Cem Concr Res 30:1517–1525CrossRef
go back to reference Flatt RJ (2002) Salt damage in porous materials how high supersaturations are generated. J Cryst Growth 242:435–454CrossRef Flatt RJ (2002) Salt damage in porous materials how high supersaturations are generated. J Cryst Growth 242:435–454CrossRef
go back to reference GB/T 50123-1999 (1999) Standard for soil test method. People’s Republic of China National Standard. China Planning Press, Beijing: 90, 99 GB/T 50123-1999 (1999) Standard for soil test method. People’s Republic of China National Standard. China Planning Press, Beijing: 90, 99
go back to reference Jha AK, Sivapullaiah PV (2016) Volume change behavior of lime treated gypseous soil-influence of mineralogy and microstructure. Appl Clay Sci 119:202–212CrossRef Jha AK, Sivapullaiah PV (2016) Volume change behavior of lime treated gypseous soil-influence of mineralogy and microstructure. Appl Clay Sci 119:202–212CrossRef
go back to reference Kaufmann J, Loser R, Leemann A (2009) Analysis of cement-bonded materials by multi-cycle mercury intrusion and nitrogen sorption. J Colloid Interface Sci 336:730–737CrossRef Kaufmann J, Loser R, Leemann A (2009) Analysis of cement-bonded materials by multi-cycle mercury intrusion and nitrogen sorption. J Colloid Interface Sci 336:730–737CrossRef
go back to reference Koniorczyk M (2012) Salt transport and crystallization in non-isothermal, partially saturated porous materials considering ions interaction model. Int J Heat Mass Transf 55:665–679CrossRef Koniorczyk M (2012) Salt transport and crystallization in non-isothermal, partially saturated porous materials considering ions interaction model. Int J Heat Mass Transf 55:665–679CrossRef
go back to reference Koniorczyk M (2015a) Coupled heat and water transport in deformable porous materials considering phase change kinetics. Int J Heat Mass Transf 81:260–271CrossRef Koniorczyk M (2015a) Coupled heat and water transport in deformable porous materials considering phase change kinetics. Int J Heat Mass Transf 81:260–271CrossRef
go back to reference Koniorczyk M (2015b) Modeling evolution of frost damage in fully saturated porous materials exposed to variable hygro-thermal conditions. Comput Methods Appl Mech Eng 297:38–61CrossRef Koniorczyk M (2015b) Modeling evolution of frost damage in fully saturated porous materials exposed to variable hygro-thermal conditions. Comput Methods Appl Mech Eng 297:38–61CrossRef
go back to reference Koniorczyk M, Gawin D (2012) Modelling of salt crystallization in building materials with microstructure-poromechanical approach. Constr Build Mater 36:860–873CrossRef Koniorczyk M, Gawin D (2012) Modelling of salt crystallization in building materials with microstructure-poromechanical approach. Constr Build Mater 36:860–873CrossRef
go back to reference Koniorczyk M, Konca P (2013) Experimental and numerical investigation of sodium sulphate crystallization in porous materials. Heat Mass Transf 49:437–449CrossRef Koniorczyk M, Konca P (2013) Experimental and numerical investigation of sodium sulphate crystallization in porous materials. Heat Mass Transf 49:437–449CrossRef
go back to reference Lai YM, Liao MK, Hu K (2016) A constitutive model of frozen saline sandy soil based on energy dissipation theory. Int J Plast 78:84–113CrossRef Lai YM, Liao MK, Hu K (2016) A constitutive model of frozen saline sandy soil based on energy dissipation theory. Int J Plast 78:84–113CrossRef
go back to reference Niu FJ, Cheng GD, Li JJ et al (2006) Experimental study on the thermal boundary conditions and temperature fields of duct-ventilated embankment in permafrost regions. J Glaciol Geocryol 28(3):380–389 Niu FJ, Cheng GD, Li JJ et al (2006) Experimental study on the thermal boundary conditions and temperature fields of duct-ventilated embankment in permafrost regions. J Glaciol Geocryol 28(3):380–389
go back to reference Okorafor OC (1999) Solubility and density isotherms for sodium sulfate-water-methanol system. J Chem Eng Data 44:488–490CrossRef Okorafor OC (1999) Solubility and density isotherms for sodium sulfate-water-methanol system. J Chem Eng Data 44:488–490CrossRef
go back to reference Romero E, Simms PH (2008) Microstructure investigation in unsaturated soils: a review with special attention to contribution of mercury intrusion porosimetry and environmental scanning electron microscopy. Geotech Geol Eng 26:705–727CrossRef Romero E, Simms PH (2008) Microstructure investigation in unsaturated soils: a review with special attention to contribution of mercury intrusion porosimetry and environmental scanning electron microscopy. Geotech Geol Eng 26:705–727CrossRef
go back to reference Sasanian S, Newson TA (2013) Use of mercury intrusion porosimetry for microstructural investigation of reconstituted clays at high water contents. Eng Geol 158:15–22CrossRef Sasanian S, Newson TA (2013) Use of mercury intrusion porosimetry for microstructural investigation of reconstituted clays at high water contents. Eng Geol 158:15–22CrossRef
go back to reference Scherer GW (2004) Stress from crystallization of salt. Cem Concr Res 34:1613–1624CrossRef Scherer GW (2004) Stress from crystallization of salt. Cem Concr Res 34:1613–1624CrossRef
go back to reference Tang CS, Shi B, Liu C et al (2008a) Influencing factors of geometrical structure of surface shrinkage cracks in clayey soils. Eng Geol 101:204–217CrossRef Tang CS, Shi B, Liu C et al (2008a) Influencing factors of geometrical structure of surface shrinkage cracks in clayey soils. Eng Geol 101:204–217CrossRef
go back to reference Tang CS, Shi B, Wang BJ (2008b) Factors affecting analysis of soil microstructure using SEM. Chin J Geotech Eng 30(4):560–565 Tang CS, Shi B, Wang BJ (2008b) Factors affecting analysis of soil microstructure using SEM. Chin J Geotech Eng 30(4):560–565
go back to reference Thaulow N, Sahu S (2004) Mechanism of concrete deterioration due to salt crystallization. Mater Charact 53:123–127CrossRef Thaulow N, Sahu S (2004) Mechanism of concrete deterioration due to salt crystallization. Mater Charact 53:123–127CrossRef
go back to reference Tovey NK, Smart P, Hounslow MW et al (1992) Automatic orientation mapping of some types of soil fabric. Geoderma 53:179–200CrossRef Tovey NK, Smart P, Hounslow MW et al (1992) Automatic orientation mapping of some types of soil fabric. Geoderma 53:179–200CrossRef
go back to reference Tsui N, Flatt RJ, Scherer GW (2003) Crystallization damage by sodium sulfate. J Cult Herit 4:109–115CrossRef Tsui N, Flatt RJ, Scherer GW (2003) Crystallization damage by sodium sulfate. J Cult Herit 4:109–115CrossRef
go back to reference Vallejo LE (1996) Fractal analysis of the fabric changes in a consolidating clay. Eng Geol 43:281–290CrossRef Vallejo LE (1996) Fractal analysis of the fabric changes in a consolidating clay. Eng Geol 43:281–290CrossRef
go back to reference Wan XS, Lai YM, Wang C (2015) Experimental study on the freezing temperatures of saline silty soils. Permafr Periglac Process 26:175–187CrossRef Wan XS, Lai YM, Wang C (2015) Experimental study on the freezing temperatures of saline silty soils. Permafr Periglac Process 26:175–187CrossRef
go back to reference Washburn EW (1921) Note on a method of determining the distribution of pore sizes in a porous material. Proc Natl Acad Sci USA 7:115–116CrossRef Washburn EW (1921) Note on a method of determining the distribution of pore sizes in a porous material. Proc Natl Acad Sci USA 7:115–116CrossRef
go back to reference Zhou J, Ye G, Breugel KV (2010) Characterization of pore structure in cement-based materials using pressurization-depressurization cycling mercury intrusion porosimetry (PDC-MIP). Cem Concr Res 40:1120–1128CrossRef Zhou J, Ye G, Breugel KV (2010) Characterization of pore structure in cement-based materials using pressurization-depressurization cycling mercury intrusion porosimetry (PDC-MIP). Cem Concr Res 40:1120–1128CrossRef
Metadata
Title
Quantitative analysis for the effect of microstructure on the mechanical strength of frozen silty clay with different contents of sodium sulfate
Authors
Zhemin You
Yuanming Lai
Mingyi Zhang
Enlong Liu
Publication date
01-02-2017
Publisher
Springer Berlin Heidelberg
Published in
Environmental Earth Sciences / Issue 4/2017
Print ISSN: 1866-6280
Electronic ISSN: 1866-6299
DOI
https://doi.org/10.1007/s12665-017-6454-7

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