Skip to main content
Top

2018 | OriginalPaper | Chapter

4. Quantum Plasmon Resonances Controlled by Molecular Tunnel Junction

Author : Dr. Shu Fen Tan

Published in: Molecular Electronic Control Over Tunneling Charge Transfer Plasmons Modes

Publisher: Springer Singapore

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Quantum tunneling between two plasmonic resonators links non-linear quantum optics with terahertz nanoelectronics. Direct observation of and control over quantum plasmon resonances at length scales in the range 0.4–1.3 nm across molecular tunnel junctions made of two plasmonic resonators bridged by self-assembled monolayers (SAMs) were demonstrated. The tunnel barrier width and height are controlled by the properties of the molecules. Using electron energy-loss spectroscopy, a plasmon mode, the tunneling charge transfer plasmon, whose frequency (ranging from 140 to 245 THz) is dependent on the molecules bridging the gap was observed.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Tame MS, McEnery KR, Ozdemir SK, Lee J, Maier SA, Kim MS. Quantum plasmonics. Nat Phys. 2013;9(6):329–40.CrossRef Tame MS, McEnery KR, Ozdemir SK, Lee J, Maier SA, Kim MS. Quantum plasmonics. Nat Phys. 2013;9(6):329–40.CrossRef
3.
go back to reference Romero I, Aizpurua J, Bryant GW, García De Abajo FJ. Plasmons in nearly touching metallic nanoparticles: singular response in the limit of touching dimers. Opt Express. 2006;14(21):9988–99.CrossRefPubMed Romero I, Aizpurua J, Bryant GW, García De Abajo FJ. Plasmons in nearly touching metallic nanoparticles: singular response in the limit of touching dimers. Opt Express. 2006;14(21):9988–99.CrossRefPubMed
4.
go back to reference Zuloaga J, Prodan E, Nordlander P. Quantum description of the plasmon resonances of a nanoparticle dimer. Nano Lett. 2009;9(2):887–91.CrossRefPubMed Zuloaga J, Prodan E, Nordlander P. Quantum description of the plasmon resonances of a nanoparticle dimer. Nano Lett. 2009;9(2):887–91.CrossRefPubMed
5.
go back to reference Marinica DC, Kazansky AK, Nordlander P, Aizpurua J, Borisov AG. Quantum plasmonics: nonlinear effects in the field enhancement of a plasmonic nanoparticle dimer. Nano Lett. 2012;12(3):1333–9.CrossRefPubMed Marinica DC, Kazansky AK, Nordlander P, Aizpurua J, Borisov AG. Quantum plasmonics: nonlinear effects in the field enhancement of a plasmonic nanoparticle dimer. Nano Lett. 2012;12(3):1333–9.CrossRefPubMed
6.
go back to reference Savage KJ, Hawkeye MM, Esteban R, Borisov AG, Aizpurua J, Baumberg JJ. Revealing the quantum regime in tunnelling plasmonics. Nature. 2012;491(7425):574–7.CrossRefPubMed Savage KJ, Hawkeye MM, Esteban R, Borisov AG, Aizpurua J, Baumberg JJ. Revealing the quantum regime in tunnelling plasmonics. Nature. 2012;491(7425):574–7.CrossRefPubMed
7.
go back to reference Song P, Nordlander P, Gao S. Quantum mechanical study of the coupling of plasmon excitations to atomic-scale electron transport. J Chem Phys. 2011;134(7). Song P, Nordlander P, Gao S. Quantum mechanical study of the coupling of plasmon excitations to atomic-scale electron transport. J Chem Phys. 2011;134(7).
8.
go back to reference Kern J, Großmann S, Tarakina NV, Häckel T, Emmerling M, Kamp M, Huang J-S, Biagioni P, Prangsma JC, Hecht B. Atomic-scale confinement of resonant optical fields. Nano Lett. 2012;12(11):5504–9.CrossRefPubMed Kern J, Großmann S, Tarakina NV, Häckel T, Emmerling M, Kamp M, Huang J-S, Biagioni P, Prangsma JC, Hecht B. Atomic-scale confinement of resonant optical fields. Nano Lett. 2012;12(11):5504–9.CrossRefPubMed
9.
go back to reference Esteban R, Borisov AG, Nordlander P, Aizpurua J. Bridging quantum and classical plasmonics with a quantum-corrected model. Nat Commun. 2012;3:825.CrossRefPubMed Esteban R, Borisov AG, Nordlander P, Aizpurua J. Bridging quantum and classical plasmonics with a quantum-corrected model. Nat Commun. 2012;3:825.CrossRefPubMed
10.
go back to reference Scholl JA, García-Etxarri A, Koh AL, Dionne JA. Observation of quantum tunneling between two plasmonic nanoparticles. Nano Lett. 2012;13(2):564–9.CrossRef Scholl JA, García-Etxarri A, Koh AL, Dionne JA. Observation of quantum tunneling between two plasmonic nanoparticles. Nano Lett. 2012;13(2):564–9.CrossRef
11.
go back to reference Duan H, Fernández-Domínguez AI, Bosman M, Maier SA, Yang JKW. Nanoplasmonics: classical down to the nanometer scale. Nano Lett. 2012;12(3):1683–9.CrossRefPubMed Duan H, Fernández-Domínguez AI, Bosman M, Maier SA, Yang JKW. Nanoplasmonics: classical down to the nanometer scale. Nano Lett. 2012;12(3):1683–9.CrossRefPubMed
12.
go back to reference Henzie J, Andrews SC, Ling XY, Li Z, Yang P. Oriented assembly of polyhedral plasmonic nanoparticle clusters. Proc Natl Acad Sci. 2013;110(17):6640–5.CrossRefPubMed Henzie J, Andrews SC, Ling XY, Li Z, Yang P. Oriented assembly of polyhedral plasmonic nanoparticle clusters. Proc Natl Acad Sci. 2013;110(17):6640–5.CrossRefPubMed
13.
go back to reference Tan SF, Wu L, Yang JKW, Bai P, Bosman M, Nijhuis CA. Quantum plasmon resonances controlled by molecular tunnel junctions. Science. 2014;343(6178):1496–9.CrossRefPubMed Tan SF, Wu L, Yang JKW, Bai P, Bosman M, Nijhuis CA. Quantum plasmon resonances controlled by molecular tunnel junctions. Science. 2014;343(6178):1496–9.CrossRefPubMed
14.
go back to reference Salomon A, Cahen D, Lindsay S, Tomfohr J, Engelkes VB, Frisbie CD. Comparison of electronic transport measurements on organic molecules. Adv Mater. 2003;15(22):1881–90.CrossRef Salomon A, Cahen D, Lindsay S, Tomfohr J, Engelkes VB, Frisbie CD. Comparison of electronic transport measurements on organic molecules. Adv Mater. 2003;15(22):1881–90.CrossRef
15.
go back to reference Reed MA, Zhou C, Muller CJ, Burgin TP, Tour JM. Conductance of a molecular junction. Science. 1997;278(5336):252–4.CrossRef Reed MA, Zhou C, Muller CJ, Burgin TP, Tour JM. Conductance of a molecular junction. Science. 1997;278(5336):252–4.CrossRef
16.
go back to reference Cui XD, Primak A, Zarate X, Tomfohr J, Sankey OF, Moore AL, Moore TA, Gust D, Nagahara LA, Lindsay SM. Changes in the electronic properties of a molecule when it is wired into a circuit. J Phys Chem B. 2002;106(34):8609–14.CrossRef Cui XD, Primak A, Zarate X, Tomfohr J, Sankey OF, Moore AL, Moore TA, Gust D, Nagahara LA, Lindsay SM. Changes in the electronic properties of a molecule when it is wired into a circuit. J Phys Chem B. 2002;106(34):8609–14.CrossRef
17.
go back to reference Nijhuis CA, Reus WF, Barber JR, Whitesides GM. Comparison of SAM-based junctions with Ga2O3/EGaIn top electrodes to other large-area tunneling junctions. J Phys Chem C. 2012;116(26):14139–50.CrossRef Nijhuis CA, Reus WF, Barber JR, Whitesides GM. Comparison of SAM-based junctions with Ga2O3/EGaIn top electrodes to other large-area tunneling junctions. J Phys Chem C. 2012;116(26):14139–50.CrossRef
18.
go back to reference Joachim C, Ratner MA. Molecular electronics: some views on transport junctions and beyond. Proc Natl Acad Sci USA. 2005;102(25):8801–8.CrossRefPubMed Joachim C, Ratner MA. Molecular electronics: some views on transport junctions and beyond. Proc Natl Acad Sci USA. 2005;102(25):8801–8.CrossRefPubMed
19.
go back to reference McCreery RL. Molecular electronic junctions. Chem Mater. 2004;16(23):4477–96.CrossRef McCreery RL. Molecular electronic junctions. Chem Mater. 2004;16(23):4477–96.CrossRef
20.
go back to reference Wu L, Duan H, Bai P, Bosman M, Yang JKW, Li E. Fowler-Nordheim tunneling induced charge transfer plasmons between nearly touching nanoparticles. ACS Nano. 2012;7(1):707–16.CrossRefPubMed Wu L, Duan H, Bai P, Bosman M, Yang JKW, Li E. Fowler-Nordheim tunneling induced charge transfer plasmons between nearly touching nanoparticles. ACS Nano. 2012;7(1):707–16.CrossRefPubMed
21.
go back to reference Nelayah J, Kociak M, Stephan O, Garcia de Abajo FJ, Tence M, Henrard L, Taverna D, Pastoriza-Santos I, Liz-Marzan LM, Colliex C. Mapping surface plasmons on a single metallic nanoparticle. Nat Phys. 2007;3(5):348–53.CrossRef Nelayah J, Kociak M, Stephan O, Garcia de Abajo FJ, Tence M, Henrard L, Taverna D, Pastoriza-Santos I, Liz-Marzan LM, Colliex C. Mapping surface plasmons on a single metallic nanoparticle. Nat Phys. 2007;3(5):348–53.CrossRef
22.
go back to reference Michel B, Vicki JK, Masashi W, Abbas IM, Michael BC. Mapping surface plasmons at the nanometre scale with an electron beam. Nanotechnology. 2007;18(16):165505.CrossRef Michel B, Vicki JK, Masashi W, Abbas IM, Michael BC. Mapping surface plasmons at the nanometre scale with an electron beam. Nanotechnology. 2007;18(16):165505.CrossRef
23.
go back to reference Bosman M, Ye E, Tan SF, Nijhuis CA, Yang JKW, Marty R, Mlayah A, Arbouet A, Girard C, Han M-Y. Surface plasmon damping quantified with an electron nanoprobe. Sci Rep. 2013;3. Bosman M, Ye E, Tan SF, Nijhuis CA, Yang JKW, Marty R, Mlayah A, Arbouet A, Girard C, Han M-Y. Surface plasmon damping quantified with an electron nanoprobe. Sci Rep. 2013;3.
24.
go back to reference Strange M, Rostgaard C, Häkkinen H, Thygesen KS. Self-consistent GW calculations of electronic transport in thiol- and amine-linked molecular junctions. Phys Rev B. 2011;83(11):115108.CrossRef Strange M, Rostgaard C, Häkkinen H, Thygesen KS. Self-consistent GW calculations of electronic transport in thiol- and amine-linked molecular junctions. Phys Rev B. 2011;83(11):115108.CrossRef
25.
go back to reference Reddy P, Jang S-Y, Segalman RA, Majumdar A. Thermoelectricity in molecular junctions. Science. 2007;315(5818):1568–71.CrossRefPubMed Reddy P, Jang S-Y, Segalman RA, Majumdar A. Thermoelectricity in molecular junctions. Science. 2007;315(5818):1568–71.CrossRefPubMed
26.
go back to reference Xiao X, Xu B, Tao NJ. Measurement of single molecule conductance:  benzenedithiol and benzenedimethanethiol. Nano Lett . 004;4(2):267–71. Xiao X, Xu B, Tao NJ. Measurement of single molecule conductance:  benzenedithiol and benzenedimethanethiol. Nano Lett . 004;4(2):267–71.
27.
go back to reference Scheer AM, Gallup GA, Burrow PD. Unoccupied orbital energies of 1,4-benzenedithiol and the HOMO–LUMO gap. Chem Phys Lett. 2008;466(4–6):131–5.CrossRef Scheer AM, Gallup GA, Burrow PD. Unoccupied orbital energies of 1,4-benzenedithiol and the HOMO–LUMO gap. Chem Phys Lett. 2008;466(4–6):131–5.CrossRef
28.
go back to reference Wold DJ, Frisbie CD. Formation of metal–molecule–metal tunnel junctions: microcontacts to alkanethiol monolayers with a conducting AFM tip. J Am Chem Soc. 2000;122(12):2970–1.CrossRef Wold DJ, Frisbie CD. Formation of metal–molecule–metal tunnel junctions: microcontacts to alkanethiol monolayers with a conducting AFM tip. J Am Chem Soc. 2000;122(12):2970–1.CrossRef
29.
go back to reference Wu S, Gonzalez MT, Huber R, Grunder S, Mayor M, Schonenberger C, Calame M. Molecular junctions based on aromatic coupling. Nat Nano. 2008;3(9):569–74.CrossRef Wu S, Gonzalez MT, Huber R, Grunder S, Mayor M, Schonenberger C, Calame M. Molecular junctions based on aromatic coupling. Nat Nano. 2008;3(9):569–74.CrossRef
30.
go back to reference Ho Choi S, Kim B, Frisbie CD. Electrical resistance of long conjugated molecular wires. Science. 2008;320(5882):1482–6.CrossRefPubMed Ho Choi S, Kim B, Frisbie CD. Electrical resistance of long conjugated molecular wires. Science. 2008;320(5882):1482–6.CrossRefPubMed
31.
go back to reference Pontes RB, Rocha AR, Sanvito S, Fazzio A, da Silva AJR. Ab initio calculations of structural evolution and conductance of benzene-1,4-dithiol on gold leads. ACS Nano. 2011;5(2):795–804.CrossRefPubMed Pontes RB, Rocha AR, Sanvito S, Fazzio A, da Silva AJR. Ab initio calculations of structural evolution and conductance of benzene-1,4-dithiol on gold leads. ACS Nano. 2011;5(2):795–804.CrossRefPubMed
32.
go back to reference Palik ED. Handbook of optical constants of solids. San Diego, California: Academic; 1991. Palik ED. Handbook of optical constants of solids. San Diego, California: Academic; 1991.
33.
go back to reference Haynes WM. CRC handbook of chemistry and physics. 94th ed. Taylor and Francis; 2013. Haynes WM. CRC handbook of chemistry and physics. 94th ed. Taylor and Francis; 2013.
34.
go back to reference Bosman M, Zhang L, Duan H, Tan SF, Nijhuis CA, Qiu CW, Yang JKW. Encapsulated annealing: enhancing the plasmon quality factor in lithographically–defined nanostructures. Sci Rep. 2014; 4. Bosman M, Zhang L, Duan H, Tan SF, Nijhuis CA, Qiu CW, Yang JKW. Encapsulated annealing: enhancing the plasmon quality factor in lithographically–defined nanostructures. Sci Rep. 2014; 4.
35.
go back to reference Sellers H, Ulman A, Shnidman Y, Eilers JE. Structure and binding of alkanethiolates on gold and silver surfaces: implications for self-assembled monolayers. J Am Chem Soc. 1993;115(21):9389–401.CrossRef Sellers H, Ulman A, Shnidman Y, Eilers JE. Structure and binding of alkanethiolates on gold and silver surfaces: implications for self-assembled monolayers. J Am Chem Soc. 1993;115(21):9389–401.CrossRef
36.
go back to reference Cox EG, Cruickshank DWJ, Smith JAS. The crystal structure of benzene at −3 °C. Proc Royal Soc Lon Ser A Math Phys Sci. 1958;247(1248):1–21. Cox EG, Cruickshank DWJ, Smith JAS. The crystal structure of benzene at −3 °C. Proc Royal Soc Lon Ser A Math Phys Sci. 1958;247(1248):1–21.
37.
go back to reference Kiguchi MSN, Murakoshi K. In-situ preparation of a single molecular junction with mechanically controllable break junctions in vacuum. J Phys Conf Ser. 2008;100:052–059. Kiguchi MSN, Murakoshi K. In-situ preparation of a single molecular junction with mechanically controllable break junctions in vacuum. J Phys Conf Ser. 2008;100:052–059.
38.
go back to reference Kim Y, Pietsch T, Erbe A, Belzig W, Scheer E. Benzenedithiol: a broad-range single-channel molecular conductor. Nano Lett. 2011;11(9):3734–8.CrossRefPubMed Kim Y, Pietsch T, Erbe A, Belzig W, Scheer E. Benzenedithiol: a broad-range single-channel molecular conductor. Nano Lett. 2011;11(9):3734–8.CrossRefPubMed
39.
go back to reference García de Abajo FJ. Optical excitations in electron microscopy. Rev Mod Phys. 2010;82(1):209–275. García de Abajo FJ. Optical excitations in electron microscopy. Rev Mod Phys. 2010;82(1):209–275.
40.
go back to reference Bigelow NW, Vaschillo A, Iberi V, Camden JP, Masiello DJ. Characterization of the electron- and photon-driven plasmonic excitations of metal nanorods. ACS Nano. 2012;6(8):7497–504.CrossRefPubMed Bigelow NW, Vaschillo A, Iberi V, Camden JP, Masiello DJ. Characterization of the electron- and photon-driven plasmonic excitations of metal nanorods. ACS Nano. 2012;6(8):7497–504.CrossRefPubMed
Metadata
Title
Quantum Plasmon Resonances Controlled by Molecular Tunnel Junction
Author
Dr. Shu Fen Tan
Copyright Year
2018
Publisher
Springer Singapore
DOI
https://doi.org/10.1007/978-981-10-8803-2_4

Premium Partners