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Fundamental Reaction Mechanisms in Radiation Chemistry and Recent Examples Read chapter Read first chapter

2014 | OriginalPaper | Chapter

6. Radiation Chemistry of Solid-State Carbohydrates Using EMR

Authors : Henk Vrielinck, Hendrik De Cooman, Freddy Callens, Einar Sagstuen

Published in: Applications of EPR in Radiation Research

Publisher: Springer International Publishing

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Abstract

We review our research of the past decade towards identification of radiation-induced radicals in solid state sugars and sugar phosphates. Detailed models of the radical structures are obtained by combining EPR and ENDOR experiments with DFT calculations of g and proton HF tensors, with agreement in their anisotropy serving as most important criterion. Symmetry-related and Schonland ambiguities, which may hamper such identification, are reviewed. Thermally induced transformations of initial radiation damage into more stable radicals can also be monitored in the EPR (and ENDOR) experiments and in principle provide information on stable radical formation mechanisms. Thermal annealing experiments reveal, however, that radical recombination and/or diamagnetic radiation damage is also quite important. Analysis strategies are illustrated with research on sucrose. Results on dipotassium glucose-1-phosphate and trehalose dihydrate, fructose and sorbose are also briefly discussed. Our study demonstrates that radiation damage is strongly regio-selective and that certain general principles govern the stable radical formation.

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previous chapter EPR and IR Spectroscopy of Free Radicals and Radical Ions Produced by Radiation in Solid Systems
next chapter EPR on Radiation-Induced Defects in SiO2
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Metadata
Title
Radiation Chemistry of Solid-State Carbohydrates Using EMR
Authors
Henk Vrielinck
Hendrik De Cooman
Freddy Callens
Einar Sagstuen
Copyright Year
2014
Book
Applications of EPR in Radiation Research

Print ISBN: 978-3-319-09215-7

Electronic ISBN: 978-3-319-09216-4

Copyright Year: 2014

DOI
https://doi.org/10.1007/978-3-319-09216-4_6

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