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Published in: Journal of Materials Science 4/2019

26-10-2018 | Electronic materials

Realizing high-responsive superlattice organic photodiodes by C60 and zinc phthalocyanine

Authors: Rongzheng Ding, Ziqiang Xu, Tingcai Zheng, Fobao Huang, Yingquan Peng, Wenli Lv, Yuhuan Yang, Ying Wang, Sunan Xu, Lei Sun

Published in: Journal of Materials Science | Issue 4/2019

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Abstract

Organic superlattices, consisting of alternating thin films of different organic molecules, are expected to provide new molecule assembly and unique properties that are applicable to advanced optoelectronic devices. Adopting organic superlattice as the structure of active layer may be an appropriate trade-off between planar heterojunctions and bulk heterojunction. With this structure, exciton diffusion efficiency and carrier mobility can be appropriately improved at the same time, leading to the optimization of device performance. In this paper, superlattice organic photodiodes based on heterojunction composed of C60 and zinc phthalocyanine were fabricated and characterized. We demonstrate good optoelectronic properties of these devices with superlattice structure through experimental data. It is found that the performances of the devices are strongly dependent on the incident optical power and the number of heterojunction periods, n. We optimized n and obtained high-responsive devices. The SL-OPD with n = 3 exhibits the photoresponsivity up to 5.21 (± 0.26) A W−1 at the incident optical intensity of 0.068 (± 0.003) mW cm−2.

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Appendix
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Literature
1.
go back to reference Yao B, Zhou X, Ye X, Zhang J, Yang D, Ma D, Wan X (2015) 2,1,3-Benzothiadiazole-5,6-dicarboxylic imide based low-bandgap polymers for solution processed photodiode application. Org Electron 26:305–313CrossRef Yao B, Zhou X, Ye X, Zhang J, Yang D, Ma D, Wan X (2015) 2,1,3-Benzothiadiazole-5,6-dicarboxylic imide based low-bandgap polymers for solution processed photodiode application. Org Electron 26:305–313CrossRef
2.
go back to reference Kim IK, Li X, Ullah M, Shaw PE, Wawrzinek R, Namdas EB, Lo S-C (2015) High-performance, fullerene-free organic photodiodes based on a solution-processable indigo. Adv Mater 27:6390–6395CrossRef Kim IK, Li X, Ullah M, Shaw PE, Wawrzinek R, Namdas EB, Lo S-C (2015) High-performance, fullerene-free organic photodiodes based on a solution-processable indigo. Adv Mater 27:6390–6395CrossRef
3.
go back to reference Zhang L, Yang T, Shen L, Fang Y, Dang L, Zhou N, Guo X, Hong Z, Yang Y, Wu H, Huang J, Liang Y (2015) Toward highly sensitive polymer photodetectors by molecular engineering. Adv Mater 27:6496–6503CrossRef Zhang L, Yang T, Shen L, Fang Y, Dang L, Zhou N, Guo X, Hong Z, Yang Y, Wu H, Huang J, Liang Y (2015) Toward highly sensitive polymer photodetectors by molecular engineering. Adv Mater 27:6496–6503CrossRef
4.
go back to reference Lin Y, Wang J, Zhang Z-G, Bai H, Li Y, Zhu D, Zhan X (2015) An electron acceptor challenging fullerenes for efficient polymer solar cells. Adv Mater 27:1170–1174CrossRef Lin Y, Wang J, Zhang Z-G, Bai H, Li Y, Zhu D, Zhan X (2015) An electron acceptor challenging fullerenes for efficient polymer solar cells. Adv Mater 27:1170–1174CrossRef
5.
go back to reference Jianchang W, Ma Y, Na W, Lin Y, Lin J, Wang L, Ma C-Q (2015) 2,2-Dicyanovinyl-end-capped oligothiophenes as electron acceptor in solution processed bulk-heterojunction organic solar cells. Org Electron 23:28–38CrossRef Jianchang W, Ma Y, Na W, Lin Y, Lin J, Wang L, Ma C-Q (2015) 2,2-Dicyanovinyl-end-capped oligothiophenes as electron acceptor in solution processed bulk-heterojunction organic solar cells. Org Electron 23:28–38CrossRef
6.
go back to reference Falco A et al (2015) Spray deposition of Polyethylenimine thin films for the fabrication of fully-sprayed organic photodiodes. Org Electron 23:186–192CrossRef Falco A et al (2015) Spray deposition of Polyethylenimine thin films for the fabrication of fully-sprayed organic photodiodes. Org Electron 23:186–192CrossRef
7.
go back to reference Pierre A, Deckman I, Lechene PB, Arias AC (2015) High detectivity all-printed organic photodiodes. Adv Mater 27:6411CrossRef Pierre A, Deckman I, Lechene PB, Arias AC (2015) High detectivity all-printed organic photodiodes. Adv Mater 27:6411CrossRef
8.
go back to reference Bellani S, Iacchetti A, Porro M, Beverina L, Antognazza MR, Natali D (2015) Charge transport characterization in a squaraine-based photodetector by means of admittance spectroscopy. Org Electron 22:56–61CrossRef Bellani S, Iacchetti A, Porro M, Beverina L, Antognazza MR, Natali D (2015) Charge transport characterization in a squaraine-based photodetector by means of admittance spectroscopy. Org Electron 22:56–61CrossRef
9.
go back to reference Büchele P, Morana M, Bagnis D, Tedde SF, Hartmann D, Fischer R, Schmidt O (2015) Space charge region effects in bidirectional illuminated P3HT:PCBM bulk heterojunction photodetectors. Org Electron 22:29–34CrossRef Büchele P, Morana M, Bagnis D, Tedde SF, Hartmann D, Fischer R, Schmidt O (2015) Space charge region effects in bidirectional illuminated P3HT:PCBM bulk heterojunction photodetectors. Org Electron 22:29–34CrossRef
11.
go back to reference Ai N, Zhou Y, Zheng Y, Chen H, Wang J, Pei J, Cao Y (2013) Achieving high sensitivity in single organic submicrometer ribbon based photodetector through surface engineering. Org Electron 14(4):1103–1108CrossRef Ai N, Zhou Y, Zheng Y, Chen H, Wang J, Pei J, Cao Y (2013) Achieving high sensitivity in single organic submicrometer ribbon based photodetector through surface engineering. Org Electron 14(4):1103–1108CrossRef
12.
go back to reference Rim YS, Yang YM, Bae SH, Chen H, Li C, Goorsky MS, Yang Y (2015) Ultrahigh and broad spectral photodetectivity of an organic-inorganic hybrid phototransistor for flexible electronics. Adv Mater 27(43):6885–6891CrossRef Rim YS, Yang YM, Bae SH, Chen H, Li C, Goorsky MS, Yang Y (2015) Ultrahigh and broad spectral photodetectivity of an organic-inorganic hybrid phototransistor for flexible electronics. Adv Mater 27(43):6885–6891CrossRef
13.
go back to reference Leem D-S, Lee K-H, Kwon Y-N, Yun D-J, Park K-B, Lim S-J, Kim K-S, Jin YW, Lee S (2015) Low dark current inverted organic photodetectors employing MoOx: Al cathode interlayer. Org Electron 24:176–181CrossRef Leem D-S, Lee K-H, Kwon Y-N, Yun D-J, Park K-B, Lim S-J, Kim K-S, Jin YW, Lee S (2015) Low dark current inverted organic photodetectors employing MoOx: Al cathode interlayer. Org Electron 24:176–181CrossRef
14.
go back to reference Luo X, Wen Z, Lili D, Lv W, Zhao F, Tang Y, Chen Z, Peng Y (2016) Notably improved red photoresponse of organic diode employing gold nanoparticles plasmonic absorption. J Nanosci Nanotechnol 16(6):707–5713 Luo X, Wen Z, Lili D, Lv W, Zhao F, Tang Y, Chen Z, Peng Y (2016) Notably improved red photoresponse of organic diode employing gold nanoparticles plasmonic absorption. J Nanosci Nanotechnol 16(6):707–5713
15.
go back to reference Luo X, Lv W, Lili D, Zhao F, Peng Y, Tang Y, Wang Y (2016) Insight into trap state dynamics for exploiting current multiplication in organic photodetectors. Phys Status Solidi RRL 10(6):485–492CrossRef Luo X, Lv W, Lili D, Zhao F, Peng Y, Tang Y, Wang Y (2016) Insight into trap state dynamics for exploiting current multiplication in organic photodetectors. Phys Status Solidi RRL 10(6):485–492CrossRef
16.
go back to reference Lv W, Peng Y, Zhong J, Luo X, Li Y, Zheng T, Tang Y, Du L, Peng L et al (2015) Realizing near infrared sensitive organic photodiodes exploiting exciplex absorption in heterojunctions consisting of neodymium phthalocyanine and C60. IEEE Photonics Technol Lett 27(9):2043–2046CrossRef Lv W, Peng Y, Zhong J, Luo X, Li Y, Zheng T, Tang Y, Du L, Peng L et al (2015) Realizing near infrared sensitive organic photodiodes exploiting exciplex absorption in heterojunctions consisting of neodymium phthalocyanine and C60. IEEE Photonics Technol Lett 27(9):2043–2046CrossRef
17.
go back to reference Park S, Kim SJ, Nam JH, Pitner G, Lee TH, Ayzner AL, Wang H, Fong SW, Vosgueritchian M, Park YJ, Brongersma ML, Bao Z (2015) Significant enhancement of infrared photodetector sensitivity using a semiconducting single-walled carbon nanotube/C60 phototransistor. Adv Mater 27(4):759–765CrossRef Park S, Kim SJ, Nam JH, Pitner G, Lee TH, Ayzner AL, Wang H, Fong SW, Vosgueritchian M, Park YJ, Brongersma ML, Bao Z (2015) Significant enhancement of infrared photodetector sensitivity using a semiconducting single-walled carbon nanotube/C60 phototransistor. Adv Mater 27(4):759–765CrossRef
18.
go back to reference Luo X, Du L, Lv W, Sun L, Li Y, Peng Y, Zhao F, Zhang J, Tang Y, Wang Y (2015) Charge-transport interfacial modification enhanced ultraviolet (UV)/near-UV photodetector with high sensitivity and fast response speed. Synth Metal 210:230–235CrossRef Luo X, Du L, Lv W, Sun L, Li Y, Peng Y, Zhao F, Zhang J, Tang Y, Wang Y (2015) Charge-transport interfacial modification enhanced ultraviolet (UV)/near-UV photodetector with high sensitivity and fast response speed. Synth Metal 210:230–235CrossRef
19.
go back to reference Wang X, Zhou D, Huang J, Junsheng Y (2015) High performance organic ultraviolet photodetector with efficient electroluminescence realized by a thermally activated delayed fluorescence emitter. Appl Phys Lett 107:043303CrossRef Wang X, Zhou D, Huang J, Junsheng Y (2015) High performance organic ultraviolet photodetector with efficient electroluminescence realized by a thermally activated delayed fluorescence emitter. Appl Phys Lett 107:043303CrossRef
20.
go back to reference Hafez HA et al (2015) Nonlinear terahertz field-induced carrier dynamics in photoexcited epitaxial monolayer graphene. Phys Rev B 91(3):035422CrossRef Hafez HA et al (2015) Nonlinear terahertz field-induced carrier dynamics in photoexcited epitaxial monolayer graphene. Phys Rev B 91(3):035422CrossRef
21.
go back to reference Esaki L, Tsu R (1970) Superlattice and negative differential conductivity in semiconductors. IBM J Res Dev 14:61CrossRef Esaki L, Tsu R (1970) Superlattice and negative differential conductivity in semiconductors. IBM J Res Dev 14:61CrossRef
22.
go back to reference Steveler E, Verdun M, Portier B, Chevalier P, Dupuis C, Bardou N, Rodriguez J-B, Haïdar R, Pardo F, Pelouard J-L (2014) Optical index measurement of InAs/GaSb type-II superlattice for mid-infrared photodetection at cryogenic temperatures. Appl Phys Lett 105:141103CrossRef Steveler E, Verdun M, Portier B, Chevalier P, Dupuis C, Bardou N, Rodriguez J-B, Haïdar R, Pardo F, Pelouard J-L (2014) Optical index measurement of InAs/GaSb type-II superlattice for mid-infrared photodetection at cryogenic temperatures. Appl Phys Lett 105:141103CrossRef
23.
go back to reference Ali D, Richardson CJK (2014) Strain-balanced Si/SiGe type-II superlattices for near-infrared photodetection. Appl Phys Lett 105(3):031116CrossRef Ali D, Richardson CJK (2014) Strain-balanced Si/SiGe type-II superlattices for near-infrared photodetection. Appl Phys Lett 105(3):031116CrossRef
24.
go back to reference Haugan HJ, Brown GJ, Olson BV, Kadlec EA, Kim JK, Shaner EA (2015) Demonstration of long minority carrier lifetimes in very narrow bandgap ternary InAs/GaInSb superlattices. Appl Phys Lett 107(13):131102CrossRef Haugan HJ, Brown GJ, Olson BV, Kadlec EA, Kim JK, Shaner EA (2015) Demonstration of long minority carrier lifetimes in very narrow bandgap ternary InAs/GaInSb superlattices. Appl Phys Lett 107(13):131102CrossRef
25.
go back to reference Imanishi Y, Hattori S, Kakuta A, Numata S (1993) Direct observation of an organic superlattice structure. Phys Rev Lett 71(13):2098CrossRef Imanishi Y, Hattori S, Kakuta A, Numata S (1993) Direct observation of an organic superlattice structure. Phys Rev Lett 71(13):2098CrossRef
26.
go back to reference So FF, Forrest SR (1991) Evidence for exciton confinement in crystalline organic multiple quantum wells. Phys Rev Lett 66(20):2649CrossRef So FF, Forrest SR (1991) Evidence for exciton confinement in crystalline organic multiple quantum wells. Phys Rev Lett 66(20):2649CrossRef
27.
go back to reference Gordan OD, Hermann S, Friedrich M, Zahn DRT (2005) Optical properties of 3,4,9,10-perylenetertracarboxylic dianhydride/copper phthalocyanine superlattices. J Appl Phys 97:063518CrossRef Gordan OD, Hermann S, Friedrich M, Zahn DRT (2005) Optical properties of 3,4,9,10-perylenetertracarboxylic dianhydride/copper phthalocyanine superlattices. J Appl Phys 97:063518CrossRef
28.
go back to reference Park TJ, Lee YK, Kwon SK, Kwon JH, Jang J (2006) Resonant tunneling diode made of organic semiconductor superlattice. Appl Phys Lett 89:151114CrossRef Park TJ, Lee YK, Kwon SK, Kwon JH, Jang J (2006) Resonant tunneling diode made of organic semiconductor superlattice. Appl Phys Lett 89:151114CrossRef
29.
go back to reference Yanase T, Nagahama T, Shimada T (2013) Fabrication and characterization of photo-responsive organic p-type/n-type/piezoelectric tricolor superlattices. Appl Phys Lett 103(13):133305CrossRef Yanase T, Nagahama T, Shimada T (2013) Fabrication and characterization of photo-responsive organic p-type/n-type/piezoelectric tricolor superlattices. Appl Phys Lett 103(13):133305CrossRef
30.
go back to reference Park SH, Roy A, Beaupré S, Cho S, Coates N, Moon JS, Moses D, Leclerc M, Lee K, Heeger AJ (2009) Bulk heterojunction solar cells with internal quantum efficiency approaching 100%. Nat Photonics 3:297–302CrossRef Park SH, Roy A, Beaupré S, Cho S, Coates N, Moon JS, Moses D, Leclerc M, Lee K, Heeger AJ (2009) Bulk heterojunction solar cells with internal quantum efficiency approaching 100%. Nat Photonics 3:297–302CrossRef
31.
go back to reference Hoppe H, Sariciftici NS (2004) Organic solar cells: an overview. J Mater Res 19:7–15CrossRef Hoppe H, Sariciftici NS (2004) Organic solar cells: an overview. J Mater Res 19:7–15CrossRef
32.
go back to reference Yang F, Shtein M, Forrest SR (2005) Controlled growth of a molecular bulk heterojunction photovoltaic cell. Nat Mater 4:37–41CrossRef Yang F, Shtein M, Forrest SR (2005) Controlled growth of a molecular bulk heterojunction photovoltaic cell. Nat Mater 4:37–41CrossRef
33.
go back to reference Peumans P, Bulović V, Forrest SR (2000) Efficient photon harvesting at high optical intensities in ultrathin organic double-heterostructure photovoltaic diodes. Appl Phys Lett 76(19):2650–2652CrossRef Peumans P, Bulović V, Forrest SR (2000) Efficient photon harvesting at high optical intensities in ultrathin organic double-heterostructure photovoltaic diodes. Appl Phys Lett 76(19):2650–2652CrossRef
34.
go back to reference Hong ZR, Huang ZH, Zeng XT (2006) Investigation into effects of electron transporting materials on organic solar cells with copper phthalocyanine/C60 heterojunctions. Chem Phys Lett 425(1–3):62–65CrossRef Hong ZR, Huang ZH, Zeng XT (2006) Investigation into effects of electron transporting materials on organic solar cells with copper phthalocyanine/C60 heterojunctions. Chem Phys Lett 425(1–3):62–65CrossRef
35.
go back to reference Li Y, Lv W, Luo X, Sun L, Zhao F, Zhang J, Zhong J, Huang F, Peng Y (2015) Enhanced performance of PbPc photosensitive organic field effect transistors by inserting different-thickness pentacene inducing layers. Org Electron 26:186–190CrossRef Li Y, Lv W, Luo X, Sun L, Zhao F, Zhang J, Zhong J, Huang F, Peng Y (2015) Enhanced performance of PbPc photosensitive organic field effect transistors by inserting different-thickness pentacene inducing layers. Org Electron 26:186–190CrossRef
36.
go back to reference Li Y, Zhang J, Lv W, Luo X, Sun L, Zhong J, Zhao F, Huang F, Peng Y (2015) Substrate temperature dependent performance of near infrared photoresponsive organic field effect transistors based on lead phthalocyanine. Synth Met 205:190–194CrossRef Li Y, Zhang J, Lv W, Luo X, Sun L, Zhong J, Zhao F, Huang F, Peng Y (2015) Substrate temperature dependent performance of near infrared photoresponsive organic field effect transistors based on lead phthalocyanine. Synth Met 205:190–194CrossRef
37.
go back to reference Döring S, Otto T, Cehovski M, Charfi O, Caspary R, Kowalsky W, Rabe T (2016) Highly sensitive wide range organic photodiode based on zinc phthalocyanine:C60. Phys Status Solidi A 213(9):2387–2391CrossRef Döring S, Otto T, Cehovski M, Charfi O, Caspary R, Kowalsky W, Rabe T (2016) Highly sensitive wide range organic photodiode based on zinc phthalocyanine:C60. Phys Status Solidi A 213(9):2387–2391CrossRef
38.
go back to reference Lee J, Jadhav P, Baldo MA (2009) High efficiency organic multilayer photodetectors based on singlet exciton fission. Appl Phys Lett 95:033301CrossRef Lee J, Jadhav P, Baldo MA (2009) High efficiency organic multilayer photodetectors based on singlet exciton fission. Appl Phys Lett 95:033301CrossRef
39.
go back to reference Baeg K-J, Binda M, Natali D, Caironi M, Noh Y-Y (2013) Organic light detectors: photodiodes and phototransistors. Adv Mater 25:4267–4295CrossRef Baeg K-J, Binda M, Natali D, Caironi M, Noh Y-Y (2013) Organic light detectors: photodiodes and phototransistors. Adv Mater 25:4267–4295CrossRef
40.
go back to reference Gong X, Tong M, Xia Y, Cai W, Moon JS, Cao Y et al (2009) High-detectivity polymer photodetectors with spectral response from 300 nm to 1450 nm. Science 325(5948):1665–1667CrossRef Gong X, Tong M, Xia Y, Cai W, Moon JS, Cao Y et al (2009) High-detectivity polymer photodetectors with spectral response from 300 nm to 1450 nm. Science 325(5948):1665–1667CrossRef
41.
go back to reference Li Z, Gao F, Greenham NC, Mcneill CR (2011) Comparison of the operation of polymer/fullerene, polymer/polymer, and polymer/nanocrystal solar cells: a transient photocurrent and photovoltage study. Adv Funct Mater 21:1419–1431CrossRef Li Z, Gao F, Greenham NC, Mcneill CR (2011) Comparison of the operation of polymer/fullerene, polymer/polymer, and polymer/nanocrystal solar cells: a transient photocurrent and photovoltage study. Adv Funct Mater 21:1419–1431CrossRef
42.
go back to reference Mihailetchi VD, Wildeman J, Blom PW (2005) Space-charge limited photocurrent. Phys Rev Lett 94:126602–126800CrossRef Mihailetchi VD, Wildeman J, Blom PW (2005) Space-charge limited photocurrent. Phys Rev Lett 94:126602–126800CrossRef
43.
go back to reference Koster LJA, Mihailetchi VD, Ramaker R, Blom PWM (2005) Light intensity dependence of open-circuit voltage of polymer:fullerene solar cells. Appl Phys Lett 86:123509CrossRef Koster LJA, Mihailetchi VD, Ramaker R, Blom PWM (2005) Light intensity dependence of open-circuit voltage of polymer:fullerene solar cells. Appl Phys Lett 86:123509CrossRef
Metadata
Title
Realizing high-responsive superlattice organic photodiodes by C60 and zinc phthalocyanine
Authors
Rongzheng Ding
Ziqiang Xu
Tingcai Zheng
Fobao Huang
Yingquan Peng
Wenli Lv
Yuhuan Yang
Ying Wang
Sunan Xu
Lei Sun
Publication date
26-10-2018
Publisher
Springer US
Published in
Journal of Materials Science / Issue 4/2019
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-3052-3

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