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2019 | OriginalPaper | Chapter

Role of Compactness on Hardness and Reduced Modulus of Vaterite Determined with Nanoindentation

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Abstract

The influence of compaction degree of synthetic vaterite, the metastable polymorph of calcium carbonate, on determined mechanical properties was investigated using nanoindentation instrument. Specimens for measurements were prepared as pressed pellets with the application of three different forces—40, 60 and 80 kN. The highest values of reduced modulus and hardness were detected for vateritic pellet pressed at 60 kN. For this specimen, reduced modulus and hardness were found to be in ranges 74–10 and 5.2–0.3 GPa, respectively. Observation with scanning electron microscope showed increase compactness of pellet’s microstructure and an increase in density and length of microcracks within vateritic pellets when higher pressing force was applied.

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Literature
1.
go back to reference Tegethoff, F.W.: Calcium carbonate—from the cretaceous period into the 21st century, 1st edn. Birkhauser Verlag, Basel (2001) Tegethoff, F.W.: Calcium carbonate—from the cretaceous period into the 21st century, 1st edn. Birkhauser Verlag, Basel (2001)
2.
go back to reference Sigel, A., Sigel, H., Sigel, R.K.O.: Biomineralization: from nature to application, 1st edn. Wiley, Chichester (2008)CrossRef Sigel, A., Sigel, H., Sigel, R.K.O.: Biomineralization: from nature to application, 1st edn. Wiley, Chichester (2008)CrossRef
3.
go back to reference Van Driessche, A.E.S., Kellermeier, M., Benning, L.G., Gebauer, D.: New perspectives on mineral nucleation and growth: from solution precursors to solid materials. Springer, Cham (2017)CrossRef Van Driessche, A.E.S., Kellermeier, M., Benning, L.G., Gebauer, D.: New perspectives on mineral nucleation and growth: from solution precursors to solid materials. Springer, Cham (2017)CrossRef
4.
go back to reference Calvaresi, M., Falini, G., Pasquini, L., Reggi, M., Fermani, S., Gazzadi, G.C., Frabboni, S., Zerbetto, F.: Morphological and mechanical characterization of composite calcite/SWCNT–COOH single crystals. Nanoscale 5, 6944–6949 (2013)CrossRef Calvaresi, M., Falini, G., Pasquini, L., Reggi, M., Fermani, S., Gazzadi, G.C., Frabboni, S., Zerbetto, F.: Morphological and mechanical characterization of composite calcite/SWCNT–COOH single crystals. Nanoscale 5, 6944–6949 (2013)CrossRef
5.
go back to reference Ševčík, R., Šašek, P., Viani, A.: Physical and nanomechanical properties of the synthetic anhydrous crystalline CaCO3 polymorphs: vaterite, aragonite and calcite. J. Mater. Sci. 53, 4022–4033 (2018)CrossRef Ševčík, R., Šašek, P., Viani, A.: Physical and nanomechanical properties of the synthetic anhydrous crystalline CaCO3 polymorphs: vaterite, aragonite and calcite. J. Mater. Sci. 53, 4022–4033 (2018)CrossRef
6.
go back to reference Ševčík, R., Hrbek, V.: Influence of sample preparation on determined nanomechanical properties of metastable calcium carbonate polymorphs. In: Gdoutos, E.E. (ed.) ICTAEM 2018, pp. 3–7. Springer, Cham (2019) Ševčík, R., Hrbek, V.: Influence of sample preparation on determined nanomechanical properties of metastable calcium carbonate polymorphs. In: Gdoutos, E.E. (ed.) ICTAEM 2018, pp. 3–7. Springer, Cham (2019)
7.
go back to reference Tai, C.Y., Chen, F.-B.: Polymorphism of CaCO3 precipitated in a constant-composition environment. AIChE J. 44, 1790–1798 (1998)CrossRef Tai, C.Y., Chen, F.-B.: Polymorphism of CaCO3 precipitated in a constant-composition environment. AIChE J. 44, 1790–1798 (1998)CrossRef
8.
go back to reference Ren, D., Meyers, M.A., Zhou, B., Feng, Q.: Comparative study of carp otolith hardness: lapillus and asteriscus. Mater. Sci. Eng. C 33, 1876–1881 (2013)CrossRef Ren, D., Meyers, M.A., Zhou, B., Feng, Q.: Comparative study of carp otolith hardness: lapillus and asteriscus. Mater. Sci. Eng. C 33, 1876–1881 (2013)CrossRef
9.
go back to reference Portugal, S.J., Bowen, J., Riehl, C.: A rare mineral, vaterite, acts as a shock absorber in the eggshell of a communally nesting bird. Ibis 160, 173–178 (2018)CrossRef Portugal, S.J., Bowen, J., Riehl, C.: A rare mineral, vaterite, acts as a shock absorber in the eggshell of a communally nesting bird. Ibis 160, 173–178 (2018)CrossRef
10.
go back to reference Xiao, C., Li, M., Wang, B., Liu, M-F., Shao, C., Pan, H., Lu, Y., Xu, B-B., Li, S., Zhan, D., Jiang, Y., Tang, R., Liu, X.Y., Cölfen, H.: Total morphosynthesis of biomimetic prismatic-type CaCO3 thin films. Nat. Commun. 8, 1398–1406 (2017) Xiao, C., Li, M., Wang, B., Liu, M-F., Shao, C., Pan, H., Lu, Y., Xu, B-B., Li, S., Zhan, D., Jiang, Y., Tang, R., Liu, X.Y., Cölfen, H.: Total morphosynthesis of biomimetic prismatic-type CaCO3 thin films. Nat. Commun. 8, 1398–1406 (2017)
11.
go back to reference Ševčík, R., Pérez-Estébanez, M., Viani, A., Šašek, P., Mácová, P.: Characterization of vaterite synthesized at various temperatures and stirring velocities without use of additives. Powder Technol. 284, 265–271 (2015)CrossRef Ševčík, R., Pérez-Estébanez, M., Viani, A., Šašek, P., Mácová, P.: Characterization of vaterite synthesized at various temperatures and stirring velocities without use of additives. Powder Technol. 284, 265–271 (2015)CrossRef
12.
go back to reference Dhami, N.K., Mukherjee, A., Reddy, M.S.: Micrographical, minerological and nano-mechanical characterisation of microbial carbonates from urease and carbonic anhydrase producing bacteria. Ecol. Eng. 94, 443–454 (2016)CrossRef Dhami, N.K., Mukherjee, A., Reddy, M.S.: Micrographical, minerological and nano-mechanical characterisation of microbial carbonates from urease and carbonic anhydrase producing bacteria. Ecol. Eng. 94, 443–454 (2016)CrossRef
Metadata
Title
Role of Compactness on Hardness and Reduced Modulus of Vaterite Determined with Nanoindentation
Authors
Radek Ševčík
Vladimír Hrbek
Copyright Year
2019
DOI
https://doi.org/10.1007/978-3-030-21894-2_1

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