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2013 | OriginalPaper | Chapter

Rubber/Thermoplastic Blends: Micro and Nano Structured

Authors : Cristina Cazan, Anca Duta

Published in: Advances in Elastomers I

Publisher: Springer Berlin Heidelberg

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Abstract

Research on recycling, scarcely visible only a few decades ago, is now a very active, fastgrowing discipline, particularly focusing on wastes re-use as second raw materials. This chapter presents an overview on the state-of- art in recycling, the most recent technologies, and recent developments. Rubber and PET are the most frequently recycled polymers, and are particularly addressed to within this chapter. Recent results are presented on rubber/thermoplastic-based micro/nano blends, along with their manufacturing and characterization methods. There are described methods to obtain the rubber-PET composites, based on ground discarded tires as a matrix composites, using as fillers plastic materials (PET, HDPE, and LDPE) and inorganic oxides (CaO, ZnO, and fly ash). Based on the structural and output properties and the chapter outlines the role of various components in the polymer composites. It is demonstrated that inorganic materials in the polymer composites allow obtaining performances unrecorded by pure polymer composites. However, the control of the inorganic material (type, quantity, particle size, and molecular structure) dispersed in polymeric matrix is essential in achieving the expected performance. Using different recipes, the composites can be tailored for various indoor and outdoor applications, as building materials as paving slabs, as thermal and electrical insulators, etc.

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Literature
1.
go back to reference Rosato, D., Plastics Processing Data Handbook, Springer, (1997) Rosato, D., Plastics Processing Data Handbook, Springer, (1997)
2.
go back to reference Callister, D., Materials science and enginnering an introduction, 7th ed., John Willy & Sons, Inc., 2007 Callister, D., Materials science and enginnering an introduction, 7th ed., John Willy & Sons, Inc., 2007
3.
go back to reference Challa, G.: Polymer chemistry: An introduction. By Ellis Horwood, London (1993) Challa, G.: Polymer chemistry: An introduction. By Ellis Horwood, London (1993)
4.
go back to reference Liu H.S., Richard C.P., Mead J.L., Stacer R.G., Development of novel applications for using recycled rubber in thermoplastics. Technical report 18, Chelsea Center for Recycling and Economic Development, Massachusetts, USA, 2000 Liu H.S., Richard C.P., Mead J.L., Stacer R.G., Development of novel applications for using recycled rubber in thermoplastics. Technical report 18, Chelsea Center for Recycling and Economic Development, Massachusetts, USA, 2000
5.
go back to reference Pramanik, P.K., Baker, W.E.: Toughening of ground rubber tire filled thermoplastic compounds using different compatibilizer systems. Plast. Rubber Compos. Process. Appl. 24(4), 229–237 (1995) Pramanik, P.K., Baker, W.E.: Toughening of ground rubber tire filled thermoplastic compounds using different compatibilizer systems. Plast. Rubber Compos. Process. Appl. 24(4), 229–237 (1995)
6.
go back to reference Scaffaro, R.: Effect of adding new phosphazene compounds to poly(butylene terephthalate)/polyamide blends I: preliminary study in a batch mixer. Polym. Degrad. Stab 90(2), 234–243 (2005)CrossRef Scaffaro, R.: Effect of adding new phosphazene compounds to poly(butylene terephthalate)/polyamide blends I: preliminary study in a batch mixer. Polym. Degrad. Stab 90(2), 234–243 (2005)CrossRef
7.
go back to reference De, S.K., Bhowmick, A.K.: Thermoplastic Elastomers from Rubber Plastic Blends. Horwood, London (1990) De, S.K., Bhowmick, A.K.: Thermoplastic Elastomers from Rubber Plastic Blends. Horwood, London (1990)
8.
go back to reference Walker, B.M., Rader, C.P.: Handbook of Thermoplastic Elastomers. Van Nostrand Reinhold, New York (1988)CrossRef Walker, B.M., Rader, C.P.: Handbook of Thermoplastic Elastomers. Van Nostrand Reinhold, New York (1988)CrossRef
10.
go back to reference ASTM D 5593 – 99: “Standard Classification for Thermoplastic Elastomers-Olefinic (TEO)” ASTM D 5593 – 99: “Standard Classification for Thermoplastic Elastomers-Olefinic (TEO)”
11.
go back to reference ASTM D 5046 – 98: “Standard specification for Fully Crosslinked Elastomeric Alloys” ASTM D 5046 – 98: “Standard specification for Fully Crosslinked Elastomeric Alloys”
12.
13.
14.
go back to reference Sadek, E.M., El-Nashar, D.E., Motawie, A.M.: Polymer-Plastics Technology and Engineering 42, 627–642 (2003)CrossRef Sadek, E.M., El-Nashar, D.E., Motawie, A.M.: Polymer-Plastics Technology and Engineering 42, 627–642 (2003)CrossRef
15.
go back to reference Legge, N.R., Holden, G., Schroeder, H.E.: Thermoplastic Elastomers: A comprehensiveReview. Hanser Publishers, Munich (1987) Legge, N.R., Holden, G., Schroeder, H.E.: Thermoplastic Elastomers: A comprehensiveReview. Hanser Publishers, Munich (1987)
16.
go back to reference De, S.K., Bhowmick, A.K. (eds.): Thermoplastic Elastomers from Rubber- Plastic Blends. Ellis Horwood Ltd, London (1990) De, S.K., Bhowmick, A.K. (eds.): Thermoplastic Elastomers from Rubber- Plastic Blends. Ellis Horwood Ltd, London (1990)
17.
go back to reference Abdou-Sabet, S., Fifty years of thermoplastic elastomer Innovations, presented at the Symposium on Thermoplastic Elastomers, ACS Rubber Division Meeting: Cincinnati. OH, USA (2000) Abdou-Sabet, S., Fifty years of thermoplastic elastomer Innovations, presented at the Symposium on Thermoplastic Elastomers, ACS Rubber Division Meeting: Cincinnati. OH, USA (2000)
18.
go back to reference Sadhan, K.De., Avraam, I.I., Klementina, K., Rubber recyling, New York: CRC Press, 2005 Sadhan, K.De., Avraam, I.I., Klementina, K., Rubber recyling, New York: CRC Press, 2005
19.
go back to reference Xanthos, M., Dagli, S.S.: Compatibilization of polymer blends by reactive processing. Polym. Eng. Sci 31, 929–935 (1991)CrossRef Xanthos, M., Dagli, S.S.: Compatibilization of polymer blends by reactive processing. Polym. Eng. Sci 31, 929–935 (1991)CrossRef
20.
go back to reference Deanin, R.D., Manion, M.A.: Handbook of Polyolefines, 2nd edn. Marcel Dekker Inc, New York, USA (2000) Deanin, R.D., Manion, M.A.: Handbook of Polyolefines, 2nd edn. Marcel Dekker Inc, New York, USA (2000)
21.
go back to reference Deanin, R.D., Manion, M.A.: Compatibilization of Polymer Blends. Marcel Dekker, Inc, New York (1999) Deanin, R.D., Manion, M.A.: Compatibilization of Polymer Blends. Marcel Dekker, Inc, New York (1999)
22.
go back to reference Alexandre, M., Dubois, P.: Polymer-layered Silicate Nanocomposites: Preparation, Properties and Uses of a New Class of Materials. Mat. Sci. Eng 12, 1–63 (2000)CrossRef Alexandre, M., Dubois, P.: Polymer-layered Silicate Nanocomposites: Preparation, Properties and Uses of a New Class of Materials. Mat. Sci. Eng 12, 1–63 (2000)CrossRef
23.
go back to reference Abdou-Sabet, S., Patel, R.P.: Morphology of elastomeric alloys. Rubber Chem. Technol 64, 729–769 (1991)CrossRef Abdou-Sabet, S., Patel, R.P.: Morphology of elastomeric alloys. Rubber Chem. Technol 64, 729–769 (1991)CrossRef
24.
go back to reference Feng, W., Isayev, A.I.: In-situ Ultrasonic Compatibilization of PP/EPDM Blends during Ultrasound Aided Extrusion. Polymer 45, 1207–1216 (2004)CrossRef Feng, W., Isayev, A.I.: In-situ Ultrasonic Compatibilization of PP/EPDM Blends during Ultrasound Aided Extrusion. Polymer 45, 1207–1216 (2004)CrossRef
25.
go back to reference Xiao, H.W., Huang, ShQ, Jiang, T.: Cheng ShY. Miscibility of blends of ethylene-propylenediene terpolymer and polypropylene, J Appl Polym Sci 83, 315–322 (2002)CrossRef Xiao, H.W., Huang, ShQ, Jiang, T.: Cheng ShY. Miscibility of blends of ethylene-propylenediene terpolymer and polypropylene, J Appl Polym Sci 83, 315–322 (2002)CrossRef
26.
go back to reference Nakason, C., Jarnthong, M., Kaesaman, A., Kiatkamjornwong, A.: Thermoplastic elastomers based on epoxidized natural rubber and high-density polyethylene blends: Effect of blend compatibilizers on the mechanical and morphological. J. Appl. Polym. Sci 109, 2694–2702 (2008)CrossRef Nakason, C., Jarnthong, M., Kaesaman, A., Kiatkamjornwong, A.: Thermoplastic elastomers based on epoxidized natural rubber and high-density polyethylene blends: Effect of blend compatibilizers on the mechanical and morphological. J. Appl. Polym. Sci 109, 2694–2702 (2008)CrossRef
27.
go back to reference Supri, M., Ismail, H.: Effects of Dynamic Vulcanization and Glycidyl Methacrylate on Properties of rPVC/NBR blends. Polym. Testing 25, 318–326 (2006)CrossRef Supri, M., Ismail, H.: Effects of Dynamic Vulcanization and Glycidyl Methacrylate on Properties of rPVC/NBR blends. Polym. Testing 25, 318–326 (2006)CrossRef
28.
go back to reference Hope, P.S., Bonner, J.G., Milles, A.F.: Plastics. Rubber and Composites Processing and Applications 22, 147–158 (1994) Hope, P.S., Bonner, J.G., Milles, A.F.: Plastics. Rubber and Composites Processing and Applications 22, 147–158 (1994)
29.
go back to reference Papke, N., Karger-Kocsis, J.: Thermoplastic elastomers based on compatibilized poly(ethylene terephthalate) blends: effect of rubber type and dynamic curing. Polymer 42, 1109–1120 (2001)CrossRef Papke, N., Karger-Kocsis, J.: Thermoplastic elastomers based on compatibilized poly(ethylene terephthalate) blends: effect of rubber type and dynamic curing. Polymer 42, 1109–1120 (2001)CrossRef
30.
go back to reference Papadopoulou, C.P., Kalfoglou, N.K.: Comparison of compatibilizer effectiveness for PET/PP blends: their mechanical, thermal and morphology characterization. Polymer 41, 2543–2555 (2000)CrossRef Papadopoulou, C.P., Kalfoglou, N.K.: Comparison of compatibilizer effectiveness for PET/PP blends: their mechanical, thermal and morphology characterization. Polymer 41, 2543–2555 (2000)CrossRef
31.
go back to reference Aravind, P.A., Ranganathaiah, C., Kurian, J.V., Thomas, S.: Compatibilizing effect of EPM-g-MA in EPDM/poly(trimethylene terephthalate) incompatible blends. Polymer 45, 4925–4937 (2004)CrossRef Aravind, P.A., Ranganathaiah, C., Kurian, J.V., Thomas, S.: Compatibilizing effect of EPM-g-MA in EPDM/poly(trimethylene terephthalate) incompatible blends. Polymer 45, 4925–4937 (2004)CrossRef
33.
go back to reference Mohamad, Z., Ismail, H., Chantara, R.: Characterization of epoxidized natural rubber/ethylene vinyl acetate (ENR-50/EVA) blend: Effect of blend ratio. J. Appl. Polym. Sci. 99, 1504–1515 (2006)CrossRef Mohamad, Z., Ismail, H., Chantara, R.: Characterization of epoxidized natural rubber/ethylene vinyl acetate (ENR-50/EVA) blend: Effect of blend ratio. J. Appl. Polym. Sci. 99, 1504–1515 (2006)CrossRef
34.
go back to reference Klinklai, W., Kunyawut, C.: Preparation of thermoplastics elastomer between natural rubber and poly(lactic acid) in the presence of epoxidized natural rubber, pp. 23–29. International Conference on the Role of Universities in Hands-On Education Rajamangala University of Technology Lanna, Chiang-Mai, Thailand (2009) Klinklai, W., Kunyawut, C.: Preparation of thermoplastics elastomer between natural rubber and poly(lactic acid) in the presence of epoxidized natural rubber, pp. 23–29. International Conference on the Role of Universities in Hands-On Education Rajamangala University of Technology Lanna, Chiang-Mai, Thailand (2009)
35.
36.
go back to reference Soares, B.G., Almeida, M.S.M., Guimaraes, P.I.C.: The reactive compatibilization of NBR/EVA blends with oxazoline-modified nitrile rubber. Eur. Polymer J. 40, 2185–2194 (2004)CrossRef Soares, B.G., Almeida, M.S.M., Guimaraes, P.I.C.: The reactive compatibilization of NBR/EVA blends with oxazoline-modified nitrile rubber. Eur. Polymer J. 40, 2185–2194 (2004)CrossRef
37.
go back to reference Bonnin, E., Thibault, J.-F., Jansen, P., Soares, B.G.: Effect of compatibilizer and curing system on the thermal degradation of natural rubber/EVA copolymer blends. Polym. Degrad. Stab 52, 95–99 (1996)CrossRef Bonnin, E., Thibault, J.-F., Jansen, P., Soares, B.G.: Effect of compatibilizer and curing system on the thermal degradation of natural rubber/EVA copolymer blends. Polym. Degrad. Stab 52, 95–99 (1996)CrossRef
38.
go back to reference Macaubas, P.H.P., Demarquette, N.R.: Morphologies and Interfacial tension of immiscible polypropylene/polystyrene blends modified with triblock copolymer. Polymer 42, 2543–2554 (2001)CrossRef Macaubas, P.H.P., Demarquette, N.R.: Morphologies and Interfacial tension of immiscible polypropylene/polystyrene blends modified with triblock copolymer. Polymer 42, 2543–2554 (2001)CrossRef
39.
go back to reference Chen, J.S., Liao, M.C., Shiah, M.S.: Asphalt modified by styrene-butadiene-styrene triblock copolymer: morphology and model. J. Mater. Civ. Eng. 143, 224–229 (2002)CrossRef Chen, J.S., Liao, M.C., Shiah, M.S.: Asphalt modified by styrene-butadiene-styrene triblock copolymer: morphology and model. J. Mater. Civ. Eng. 143, 224–229 (2002)CrossRef
40.
go back to reference Kim, D.H., Fasulo, P.D., Rodgers, W.R., Paul, D.R. Effect of the ratio of maleated polypropylene to organoclay on the structure and properties of TPO-based nanocomposites. Part I: Morphology and mechanical properties, Polymer 48 (2007) 5960e5978 Kim, D.H., Fasulo, P.D., Rodgers, W.R., Paul, D.R. Effect of the ratio of maleated polypropylene to organoclay on the structure and properties of TPO-based nanocomposites. Part I: Morphology and mechanical properties, Polymer 48 (2007) 5960e5978
41.
go back to reference Silva, S.M.L., López-Manchado, M.A., Arroyo, M.: Thermoplastic Olefin/Clay Nanocomposites. Effect of Matrix Composition, and Organoclay and Compatibilizer Structure on Morphology/Properties Relationships, Journal of Nanoscience and Nanotechnology 7, 4456–4464 (2007)CrossRef Silva, S.M.L., López-Manchado, M.A., Arroyo, M.: Thermoplastic Olefin/Clay Nanocomposites. Effect of Matrix Composition, and Organoclay and Compatibilizer Structure on Morphology/Properties Relationships, Journal of Nanoscience and Nanotechnology 7, 4456–4464 (2007)CrossRef
42.
go back to reference Mirzadeh, A., Lafleur, P.G., Kamal, M.R., Dubois, C., Co-continuity of thermoplastic elastomer rubber-based nanocomposites, Society of Plastics Engineers (SPE), 10.1002/spepro.002992, 2010 Mirzadeh, A., Lafleur, P.G., Kamal, M.R., Dubois, C., Co-continuity of thermoplastic elastomer rubber-based nanocomposites, Society of Plastics Engineers (SPE), 10.​1002/​spepro.​002992, 2010
43.
go back to reference Mahallati, P., Arefazar, A., Naderi, G.: Thermoplastic elastomer nanocomposites based on PA6/NBR. Int. Polym. Proc. 25, 132–138 (2010)CrossRef Mahallati, P., Arefazar, A., Naderi, G.: Thermoplastic elastomer nanocomposites based on PA6/NBR. Int. Polym. Proc. 25, 132–138 (2010)CrossRef
44.
go back to reference Ganguly, A., Bhowmick, A.K.: Quantification of surface forces of thermoplastic elastomeric nanocomposites based on poly(styrene-ethylene-co-butylene-styrene) and clay by atomic force microscopy. J. Appl. Polym. Sci. 111, 2104–2115 (2009)CrossRef Ganguly, A., Bhowmick, A.K.: Quantification of surface forces of thermoplastic elastomeric nanocomposites based on poly(styrene-ethylene-co-butylene-styrene) and clay by atomic force microscopy. J. Appl. Polym. Sci. 111, 2104–2115 (2009)CrossRef
45.
go back to reference Nishitani, Y., Naito, T., Sekiguchi, I., Kitano, T., Effect of addition of thermoplastic elastomers on tribological anti mechanical properties of vapor grown carbon filled polybutylene terephthalate composites, World Tribology Congress 2009 - Proceedings, 2009, 421 Nishitani, Y., Naito, T., Sekiguchi, I., Kitano, T., Effect of addition of thermoplastic elastomers on tribological anti mechanical properties of vapor grown carbon filled polybutylene terephthalate composites, World Tribology Congress 2009 - Proceedings, 2009, 421
46.
go back to reference Nakason, C., Nuansomsri, K., Kaesaman, A.: Dynamic vulcanization of natural rubber/high-density polyethylene blends: Effect of compatibilization, blend ratio and curing system. Polym. Testing 25, 782–796 (2006)CrossRef Nakason, C., Nuansomsri, K., Kaesaman, A.: Dynamic vulcanization of natural rubber/high-density polyethylene blends: Effect of compatibilization, blend ratio and curing system. Polym. Testing 25, 782–796 (2006)CrossRef
47.
go back to reference Bhowmick, A.K.: Stephens. H.L, Handbook of Elastomers, Second Edition (2001) Bhowmick, A.K.: Stephens. H.L, Handbook of Elastomers, Second Edition (2001)
48.
go back to reference Machado, A.V., Van Duin, M.: Dynamic vulcanization of EPDM/PE-based thermoplastic vulcanisates studied along the extruder axis, polymer 46, 6575–6586 (2005) Machado, A.V., Van Duin, M.: Dynamic vulcanization of EPDM/PE-based thermoplastic vulcanisates studied along the extruder axis, polymer 46, 6575–6586 (2005)
49.
go back to reference Bhowmick, A.K., Chiba, T., Inoue, T.: Reactive processing of rubber-plastic blend: Role of chemical compatibilizer. J. Appl. Sci. 50, 2055–2064 (1993)CrossRef Bhowmick, A.K., Chiba, T., Inoue, T.: Reactive processing of rubber-plastic blend: Role of chemical compatibilizer. J. Appl. Sci. 50, 2055–2064 (1993)CrossRef
50.
go back to reference Lachmann, M., Use of hot runner method in the injection molding of TPE, Thermoplastische Elastomere – Herausforderung an die Elastomerverarbeiter 127 (1997) 141–161 Lachmann, M., Use of hot runner method in the injection molding of TPE, Thermoplastische Elastomere – Herausforderung an die Elastomerverarbeiter 127 (1997) 141–161
51.
go back to reference Fried, J.R.: Polymer science and Technology. Prentice Hall, Second Edition (2003) Fried, J.R.: Polymer science and Technology. Prentice Hall, Second Edition (2003)
52.
go back to reference Rodriguez, F., Cohen, C., Ober, C.: Archer. Taylor & Francis, L.A., Principles of Polymer Systems (2003) Rodriguez, F., Cohen, C., Ober, C.: Archer. Taylor & Francis, L.A., Principles of Polymer Systems (2003)
53.
go back to reference Knieps, H., Extrusion of thermoplastic elastomers, Thermoplastische Elastomere – Herausforderung an die Elastomerverarbeiter 127 (1997) 103–115 Knieps, H., Extrusion of thermoplastic elastomers, Thermoplastische Elastomere – Herausforderung an die Elastomerverarbeiter 127 (1997) 103–115
54.
go back to reference Nagaoka, T.: Blow molding of thermoplastic elastomers (TPE). Porima Daijesuto 51, 42–54 (1999) Nagaoka, T.: Blow molding of thermoplastic elastomers (TPE). Porima Daijesuto 51, 42–54 (1999)
55.
go back to reference Hull, J.L., Concise Encyclopedia of Polymer Science and Engineering, John Wiley & Sons, 1990 Hull, J.L., Concise Encyclopedia of Polymer Science and Engineering, John Wiley & Sons, 1990
56.
go back to reference Popa, G.A., Rubber: Types, Properties and Uses, Chapter 8, ISBN: 978-1-61761-464-4, Nova Science Publishers, Inc., 2010 Popa, G.A., Rubber: Types, Properties and Uses, Chapter 8, ISBN: 978-1-61761-464-4, Nova Science Publishers, Inc., 2010
57.
go back to reference Pasch, H., Augenstein, M.: Chromatographic investigations of macromolecules in the critical range of liquid chromatography: 5- Characterization of block copolymers of decyl and methyl methacrylate. Makromol. Chem 194, 2533–2541 (1993)CrossRef Pasch, H., Augenstein, M.: Chromatographic investigations of macromolecules in the critical range of liquid chromatography: 5- Characterization of block copolymers of decyl and methyl methacrylate. Makromol. Chem 194, 2533–2541 (1993)CrossRef
58.
go back to reference Pash, H.: Liquid chromatography at the critical point of adsorption – A new technique for polymer characterization. Macromol. Symp. 110, 107–120 (1996)CrossRef Pash, H.: Liquid chromatography at the critical point of adsorption – A new technique for polymer characterization. Macromol. Symp. 110, 107–120 (1996)CrossRef
59.
go back to reference Wang, T.L., Huang, F.J.: Preparation and characterization of novel thermoplastic elastomers by step/chain transformation polymerization. Polymer 41, 5219–5228 (2000)CrossRef Wang, T.L., Huang, F.J.: Preparation and characterization of novel thermoplastic elastomers by step/chain transformation polymerization. Polymer 41, 5219–5228 (2000)CrossRef
60.
go back to reference Otsuka, N., Yang, Y.: Saito H and Inoue T Structure and properties of PP/Hydrogenated SBR. Ann Tech Conf Soc Plast Eng 54, 2331–2333 (1996) Otsuka, N., Yang, Y.: Saito H and Inoue T Structure and properties of PP/Hydrogenated SBR. Ann Tech Conf Soc Plast Eng 54, 2331–2333 (1996)
61.
go back to reference Inoue, T., Svoboda, P.: Structure-properties of PP-EPDP thermoplastic elastomer: Origin of strain recovery, 58th Ann Tech Conf Soc. Plast. Eng. 2, 1676–1679 (2000) Inoue, T., Svoboda, P.: Structure-properties of PP-EPDP thermoplastic elastomer: Origin of strain recovery, 58th Ann Tech Conf Soc. Plast. Eng. 2, 1676–1679 (2000)
62.
go back to reference Huang, F.J., Wang, T.L.: Synthesis and characterization of new segmented polyurethanes with side-chain, liquid-crystalline chain extenders. J Polym Sci Part A Polym Chem Ed 42, 290–302 (2003)CrossRef Huang, F.J., Wang, T.L.: Synthesis and characterization of new segmented polyurethanes with side-chain, liquid-crystalline chain extenders. J Polym Sci Part A Polym Chem Ed 42, 290–302 (2003)CrossRef
63.
go back to reference Li, H., White, J.L.: Preparation and characterization of biaxially oriented films from polybutylene terephthalate based thermoplastic elastomer block copolymers. Polym. Eng. Sci. 40, 2299–2310 (2000)CrossRef Li, H., White, J.L.: Preparation and characterization of biaxially oriented films from polybutylene terephthalate based thermoplastic elastomer block copolymers. Polym. Eng. Sci. 40, 2299–2310 (2000)CrossRef
64.
go back to reference Volegova, I.A., Godovsky, Y.K., Soliman, M.: Glass transition of undrawn and drawn copolyetherester thermoplastic elastomers. Int. J. Polym. Mater 52, 549–564 (2003)CrossRef Volegova, I.A., Godovsky, Y.K., Soliman, M.: Glass transition of undrawn and drawn copolyetherester thermoplastic elastomers. Int. J. Polym. Mater 52, 549–564 (2003)CrossRef
65.
go back to reference Thakkar, H., Goettler, L.A.: The effects of dynamic vulcanization on the morphology and rheology of TPV’s and their nanocomposites. Tech Papers ACS Rubber Div 163, 482–491 (2003) Thakkar, H., Goettler, L.A.: The effects of dynamic vulcanization on the morphology and rheology of TPV’s and their nanocomposites. Tech Papers ACS Rubber Div 163, 482–491 (2003)
66.
go back to reference Pham, L.P., Sung, C.: Effects of blending SIBS and SMA on morphology and mechanical properties. Mat Res Soc Symp Proceed 734, 391–395 (2002) Pham, L.P., Sung, C.: Effects of blending SIBS and SMA on morphology and mechanical properties. Mat Res Soc Symp Proceed 734, 391–395 (2002)
67.
go back to reference Sauer, B.B., McLean, R.S., Brill, D.J., Londono, J.D., Morphology and orientation during deformation of segmented elastomers studied by SAXS and atomic force microscopy, Abstr 222nd ACS Meet, Chicago III, USA, PMSE–163 (2001) Sauer, B.B., McLean, R.S., Brill, D.J., Londono, J.D., Morphology and orientation during deformation of segmented elastomers studied by SAXS and atomic force microscopy, Abstr 222nd ACS Meet, Chicago III, USA, PMSE–163 (2001)
68.
go back to reference Burford, R.P., Markotsis, M.G., Knott, R.B.: Small angle neutron scattering and transmission electron microscopy studies of interpenetrating polymers networks from thermoplastic elastomers. Nucl Instrum & Meth in Phys Res Sect B 208, 58–65 (2003)CrossRef Burford, R.P., Markotsis, M.G., Knott, R.B.: Small angle neutron scattering and transmission electron microscopy studies of interpenetrating polymers networks from thermoplastic elastomers. Nucl Instrum & Meth in Phys Res Sect B 208, 58–65 (2003)CrossRef
69.
go back to reference Schmalz, H., Abetz, V., Lange, R.: Thermoplastic elastomers based on semicrystalline block copolymers. Compos. Sci. Technol. 63, 1179–1186 (2003)CrossRef Schmalz, H., Abetz, V., Lange, R.: Thermoplastic elastomers based on semicrystalline block copolymers. Compos. Sci. Technol. 63, 1179–1186 (2003)CrossRef
70.
go back to reference Svodoba, P., Saito, H., Chiba, T., Inoue, T., Takemura, Y.: Morphology and elastomeric properties of isotactic polypropylene/hydrogenated polybutadiene blends. Polym. J. 32, 915–920 (2000)CrossRef Svodoba, P., Saito, H., Chiba, T., Inoue, T., Takemura, Y.: Morphology and elastomeric properties of isotactic polypropylene/hydrogenated polybutadiene blends. Polym. J. 32, 915–920 (2000)CrossRef
71.
go back to reference Duncan J. Shaw, Introduction to Colloid and Surface Chemistry, Elsevier Science Ltd., 1992 Duncan J. Shaw, Introduction to Colloid and Surface Chemistry, Elsevier Science Ltd., 1992
72.
go back to reference Bhattacharya, De Sati N., Kamal, M.R., Gupta, R.K., Polymeric nanocomposites: theory and practice, Hanser Verlag, Munich, 2008 Bhattacharya, De Sati N., Kamal, M.R., Gupta, R.K., Polymeric nanocomposites: theory and practice, Hanser Verlag, Munich, 2008
73.
go back to reference Vladuta, C., Andronic, L., Visa, M., Duta, A.: Ceramic interface properties evaluation based on contact angle measurement. Surf. Coat. Technol. 202, 2448–2452 (2008)CrossRef Vladuta, C., Andronic, L., Visa, M., Duta, A.: Ceramic interface properties evaluation based on contact angle measurement. Surf. Coat. Technol. 202, 2448–2452 (2008)CrossRef
74.
go back to reference Voinea, M., Vladuta, C., Bogatu, C., Duta, A.: Surface properties of copper based cermet materials. Mater. Sci. Eng., B 152, 76–80 (2008)CrossRef Voinea, M., Vladuta, C., Bogatu, C., Duta, A.: Surface properties of copper based cermet materials. Mater. Sci. Eng., B 152, 76–80 (2008)CrossRef
75.
go back to reference Rubber: Types, Properties and Uses, Nova Science Publishers, Inc., Cazan, C., Duta, A. co-authors Capitol 8: Recycled Rubber – Composite Matrix, 2010, ISBN: 978-1-61761-464-4 Rubber: Types, Properties and Uses, Nova Science Publishers, Inc., Cazan, C., Duta, A. co-authors Capitol 8: Recycled Rubber – Composite Matrix, 2010, ISBN: 978-1-61761-464-4
76.
go back to reference Vladuta, C., Voinea, M., Purghel, E., Duta, A.: Correlations between the structure and the morphology of PET- rubber nanocomposites with different additives. Mater. Sci. Eng., B 165–3, 221–226 (2009)CrossRef Vladuta, C., Voinea, M., Purghel, E., Duta, A.: Correlations between the structure and the morphology of PET- rubber nanocomposites with different additives. Mater. Sci. Eng., B 165–3, 221–226 (2009)CrossRef
77.
go back to reference Vladuta, C., Andronic, L., Duta, A.: Effect of TiO2 nanoparticles on the interfaces PET-rubber composites. J. Nanosci. Nanotechnol. 10, 2518–2526 (2010)CrossRef Vladuta, C., Andronic, L., Duta, A.: Effect of TiO2 nanoparticles on the interfaces PET-rubber composites. J. Nanosci. Nanotechnol. 10, 2518–2526 (2010)CrossRef
78.
go back to reference Popovic, I.G., Katsikas, L.: The characterization of polymer composites by thermogravimetry. Materialy composite 40(1), 7–12 (2006) Popovic, I.G., Katsikas, L.: The characterization of polymer composites by thermogravimetry. Materialy composite 40(1), 7–12 (2006)
79.
go back to reference Allen, N.S., Edge, M., Mohammadian, M.: Polym. Degrad. Stab. 43, 229–237 (1994)CrossRef Allen, N.S., Edge, M., Mohammadian, M.: Polym. Degrad. Stab. 43, 229–237 (1994)CrossRef
80.
go back to reference Nakayama, Y., Takahashi, K., Sasamoto, T.: Surf Interf Anal 24, 711–717 (1996)CrossRef Nakayama, Y., Takahashi, K., Sasamoto, T.: Surf Interf Anal 24, 711–717 (1996)CrossRef
81.
go back to reference Bikiaris, D.M., Karayannidis, G.P.: Polym. Degrad. Stab. 63, 213–218 (1999)CrossRef Bikiaris, D.M., Karayannidis, G.P.: Polym. Degrad. Stab. 63, 213–218 (1999)CrossRef
82.
go back to reference Fechine, G.J.M., Rabellob, M.S.: Souto Maiora, R.M., Catalani, L.H., Surface characterization of photodegraded poly(ethylene terephthalate). The effect of ultraviolet absorbers. Polymer 45, 2303–2308 (2004)CrossRef Fechine, G.J.M., Rabellob, M.S.: Souto Maiora, R.M., Catalani, L.H., Surface characterization of photodegraded poly(ethylene terephthalate). The effect of ultraviolet absorbers. Polymer 45, 2303–2308 (2004)CrossRef
83.
go back to reference Horrocks, A.R., Mwila, J., Miraftab, M., Liu, M., Chohan, S.S.: Polym. Degrad. Stab. 65, 25–36 (1999)CrossRef Horrocks, A.R., Mwila, J., Miraftab, M., Liu, M., Chohan, S.S.: Polym. Degrad. Stab. 65, 25–36 (1999)CrossRef
84.
go back to reference Allen, N.S., Edge, M., Corrales, T., Catalina, F.: Polym. Degrad. Stab. 61, 139–149 (1998)CrossRef Allen, N.S., Edge, M., Corrales, T., Catalina, F.: Polym. Degrad. Stab. 61, 139–149 (1998)CrossRef
85.
go back to reference Garbassi, F., Mora, M., Occhiello, E.: Polymer Surfaces: From Physics to Technology. John Wiley & Sons, Chichester (1998) Garbassi, F., Mora, M., Occhiello, E.: Polymer Surfaces: From Physics to Technology. John Wiley & Sons, Chichester (1998)
86.
go back to reference Use of different surface analysis techniques for the study of the photo-degradation of a polymeric matrix composite A. Larena*, S. Jimenez de Ochoa, Applied Surface Science 238 (2004) 530–537 Use of different surface analysis techniques for the study of the photo-degradation of a polymeric matrix composite A. Larena*, S. Jimenez de Ochoa, Applied Surface Science 238 (2004) 530–537
87.
go back to reference Dick, J.S., Rubber Technology, Hanser Publishers, 2001 Dick, J.S., Rubber Technology, Hanser Publishers, 2001
88.
go back to reference Wang, H.Y., Hu, G.L., Zhou, Y., Pan, X.D., Effects of UV-raddiation on structure and properties of poly(ethylene terephthalate), Cailiao Kexue yu Gongyi/Materials Science and Technology, 16-4 (2008) 582-584 + 588 Wang, H.Y., Hu, G.L., Zhou, Y., Pan, X.D., Effects of UV-raddiation on structure and properties of poly(ethylene terephthalate), Cailiao Kexue yu Gongyi/Materials Science and Technology, 16-4 (2008) 582-584 + 588
89.
go back to reference Lupa, L., Negrea, P., Sallai, M., Ciopec, M., Ghiga, M., Valorificarea cenuşii de zinc sub formă de oxid de zinc de înaltă puritate, Buletinul AGIR n r. 1-2/2008 Lupa, L., Negrea, P., Sallai, M., Ciopec, M., Ghiga, M., Valorificarea cenuşii de zinc sub formă de oxid de zinc de înaltă puritate, Buletinul AGIR n r. 1-2/2008
90.
go back to reference Mijin, Dušan: D., Savic, M., Snežana, P., Smiljanić, A., Glavaški, O., Jovanović, M., Petrović, S., A study of the photocatalytic degradation of metamitron în ZnO water suspensions. Desalination 249, 286–292 (2009)CrossRef Mijin, Dušan: D., Savic, M., Snežana, P., Smiljanić, A., Glavaški, O., Jovanović, M., Petrović, S., A study of the photocatalytic degradation of metamitron în ZnO water suspensions. Desalination 249, 286–292 (2009)CrossRef
91.
go back to reference Wang, X., Chen, S., Cheng, X., Tu, D.: The UV aging of nano-ZnO/polyethylene composite. Diangong Jishu Xuebao/Transactions of China Electrotechnical Society 23, 6–10 (2008) Wang, X., Chen, S., Cheng, X., Tu, D.: The UV aging of nano-ZnO/polyethylene composite. Diangong Jishu Xuebao/Transactions of China Electrotechnical Society 23, 6–10 (2008)
92.
go back to reference Qamar, M., Muneer, M.: A comparative photocatalytic activity of titanium dioxide and zinc oxide by investigating the degradation of vanillin. Desalination 249, 535–540 (2009)CrossRef Qamar, M., Muneer, M.: A comparative photocatalytic activity of titanium dioxide and zinc oxide by investigating the degradation of vanillin. Desalination 249, 535–540 (2009)CrossRef
93.
go back to reference Mathews, R.W., McEvoy, S.R.: Photocatalytic degradation of phenol în the presence of near UV illuminated titanium dioxide. J. Photochem. Photobiol. A: Chem. 64, 231–246 (1992)CrossRef Mathews, R.W., McEvoy, S.R.: Photocatalytic degradation of phenol în the presence of near UV illuminated titanium dioxide. J. Photochem. Photobiol. A: Chem. 64, 231–246 (1992)CrossRef
Metadata
Title
Rubber/Thermoplastic Blends: Micro and Nano Structured
Authors
Cristina Cazan
Anca Duta
Copyright Year
2013
Publisher
Springer Berlin Heidelberg
DOI
https://doi.org/10.1007/978-3-642-20925-3_7

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