Top

Topics in Catalysis

Published in:

06-10-2017 | Original Paper

Selective Hydrogenation of Acrolein to Propanal on a Pseudomorphic Pt/Ru(001) Bimetallic Surface

Authors: Dominic A. Esan, Michael Trenary

Published in: Topics in Catalysis | Issue 5-6/2018

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

The selective hydrogenation of acrolein has been studied on different pseudomorphic Pt/Ru(001) bimetallic surfaces with platinum coverages of 0.28, 1.1, and 3.7 ML, using temperature-programmed reaction spectroscopy (TPRS), reflection absorption infrared spectroscopy (RAIRS), and Auger electron spectroscopy (AES). The submonolayer (0.28 ML) Pt/Ru(001) surface was found to be inactive towards acrolein hydrogenation and behaves mostly like a clean Ru(001) surface with the platinum layers enhancing the decarbonylation and decomposition pathways. The multilayer (3.7 ML) Pt/Ru(001) surface behaved like a Pt(111) surface with the acrolein mostly decomposing to CO and surface carbon with no observable hydrogenation activity. However, the 1 ML Pt/Ru(001) pseudomorphic surface was found to display properties different from those of Ru(001) and Pt(111) surfaces with the desorption of propanal, the only hydrogenation product, around 330 K, and propylene around 370 K. A submonolayer (0.67 ML) PtRu/Ru(001) alloy system prepared to study the effect of surface mixing (with small amounts of subsurface platinum) gave results similar to those of surface platinum at submonolayer coverages. This suggests that, at submonolayer coverages, there is little difference in the properties of these surfaces with respect to the location of the platinum atoms in the Pt/Ru(001) system.

previous article Variation of SMSI with the Au:Pd Ratio of Bimetallic Nanoparticles on TiO2(110)

next article Dry Dehydrogenation of Ethanol on Pt–Cu Single Atom Alloys

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Available only for authorised users

Schlögl R (1998) Angew Chem Int Ed 37(17):2333–2336CrossRef

Okamoto Y (2004) Chem Phys Lett 395(4):279–284CrossRef

Rodriguez J (1996) Surf Sci Rep 24(7):223–287CrossRef

Sinfelt JH (2002) Surf Sci 500(1):923–946CrossRef

Tierney HL, Baber AE, Kitchin JR, Sykes ECH (2009) Phys Rev Lett 103(24):246102CrossRef

Kyriakou G, Boucher MB, Jewell AD, Lewis EA, Lawton TJ, Baber AE, Tierney HL, Flytzani-Stephanopoulos M, Sykes ECH (2012) Science 335(6073):1209–1212CrossRef

Kruppe CM, Krooswyk JD, Trenary M (2017) J Phys Chem C 121(17):9361–9369CrossRef

Lucci FR, Liu J, Marcinkowski MD, Yang M, Allard LF, Flytzani-Stephanopoulos M, Sykes ECH (2015) Nat Commun 6:8550CrossRef

Aich P, Wei H, Basan B, Kropf AJ, Schweitzer NM, Marshall CL, Miller JT, Meyer R (2015) J Phys Chem C 119(32):18140–18148CrossRef

10.

Wang Z-T, Darby MT, Therrien AJ, El-Soda M, Michaelides A, Stamatakis M, Sykes ECH (2016) J Phys Chem C 120(25):13574–13580CrossRef

11.

Greeley J, Mavrikakis M (2005) J Phys Chem B 109(8):3460–3471CrossRef

12.

Sinfelt JH (1983) Bimetallic catalysts: discoveries, concepts, and applications. Wiley, New York

13.

Fruëhberger B, Eng J, Chen JG (1997) Catal Lett 45(1):85–92CrossRef

14.

Murillo LE, Chen JG (2008) Surf Sci 602(4):919–931CrossRef

15.

Murillo LE, Chen JG (2008) Surf Sci 602(14):2412–2420CrossRef

16.

Murillo LE, Menning CA, Chen JG (2009) J Catal 268(2):335–342CrossRef

17.

Hou R, Yu W, Porosoff MD, Chen JG, Wang T (2014) J Catal 316:1–10CrossRef

18.

Jakob P, Schlapka A (2007) Surf Sci 601(17):3556–3568CrossRef

19.

Buatier de Mongeot F, Scherer M, Gleich B, Kopatzki E, Behm RJ (1998) Surf Sci 411(3):249–262CrossRef

20.

Diemant T, Bergbreiter A, Bansmann J, Hoster HE, Behm RJ (2010) ChemPhysChem 11(14):3123–3132CrossRef

21.

Hartmann H, Diemant T, Bansmann J, Behm RJ (2012) PCCP 14(31):10919–10934CrossRef

22.

Hartmann H, Diemant T, Behm RJ (2013) ChemPhysChem 14(16):3801–3805CrossRef

23.

Schlapka A, Käsberger U, Menzel D, Jakob P (2002) Surf Sci 502:129–135CrossRef

24.

Peden CHF, Goodman DW (1986) Ind Eng Chem Fundam 25(1):58–62CrossRef

25.

Claus P (1998) Top Catal 5(1):51–62CrossRef

26.

Gallezot P, Richard D (1998) Cat Rev 40(1–2):81–126CrossRef

27.

Egan RR, Earl GW, Ackerman J (1984) J Am Oil Chem Soc 61(2):324–329CrossRef

28.

Marinelli TBLW, Nabuurs S, Ponec V (1995) J Catal 151(2):431–438CrossRef

29.

Mohr C, Hofmeister H, Radnik J, Claus P (2003) J Am Chem Soc 125(7):1905–1911CrossRef

30.

Richard D, Ockelford J, Giroir-Fendler A, Gallezot P (1989) Catal Lett 3(1):53–58CrossRef

31.

Kluson P, Cerveny L (1995) Appl Catal A 128(1):13–31CrossRef

32.

Esan DA, Ren Y, Feng X, Trenary M (2017) J Phys Chem C 121(8):4384–4392CrossRef

33.

de Jesús JC, Zaera F (1999) Surf Sci 430(1–3):99–115CrossRef

34.

de Jesús JC, Zaera F (1999) J Mol Catal A 138(2–3):237–240CrossRef

35.

Loffreda D, Delbecq F, Vigné F, Sautet P (2005) Angew Chem Int Ed 44(33):5279–5282CrossRef

36.

Waluyo I, Ren Y, Trenary M (2013) J Phys Chem Lett 4(21):3779–3786CrossRef

37.

Esan DA, Trenary M (2017) PCCP 19(17):10870–10877CrossRef

38.

Horanyi G, Torkos K (1982) J Electroanal Chem Interfacial Electrochem 136(2):301–309CrossRef

39.

Davis JL, Barteau MA (1992) J Mol Catal 77(1):109–124CrossRef

40.

Sbrana G, Schettino V (1970) J Mol Spectrosc 33(1):100–108CrossRef

Title: Selective Hydrogenation of Acrolein to Propanal on a Pseudomorphic Pt/Ru(001) Bimetallic Surface
Authors: Dominic A. Esan
Michael Trenary
Publication date: 06-10-2017
Publisher: Springer US
Published in: Topics in Catalysis / Issue 5-6/2018
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-017-0857-2

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 5-6/2018

Shape Control in Gold Nanoparticles by N-Containing Ligands: Insights from Density Functional Theory and Wulff Constructions

Dissociative Chemisorption and Oxidation of H2 on the Stoichiometric IrO2(110) Surface

Facile and Cost Effective Synthesis of Oxide-Derived Silver Catalyst Electrodes via Chemical Solution Deposition for CO2 Electro-Reduction

Oxidative Carboxylation of 1-Decene to 1,2-Decylene Carbonate

Morphological Dependence of the Thermal and Photochemical Reactions of Acetaldehyde on Anatase TiO2 Nanocrystals

Dry Dehydrogenation of Ethanol on Pt–Cu Single Atom Alloys

Premium Partners