Top

Journal of Nanoparticle Research

Published in:

01-02-2017 | Research Paper

Silsesquioxane nanoparticles with reactive internal functional groups

Authors: Eric M . Brozek, Nancy M. Washton, Karl T. Mueller, Ilya Zharov

Published in: Journal of Nanoparticle Research | Issue 2/2017

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

A series of silsesquioxane nanoparticles containing reactive internal organic functionalities throughout the entire particle body have been synthesized using a surfactant-free method with organosilanes as the sole precursors and a base catalyst. The organic functional groups incorporated are vinyl, allyl, mercapto, cyanoethyl, and cyanopropyl groups. The sizes and morphologies of the particles were characterized using SEM and nitrogen adsorption, while the compositions were confirmed using TGA, FT-IR, solid state NMR, and elemental analysis. The accessibility and reactivity of the functional groups inside the particles were demonstrated by performing bromination and reduction reactions in the interior of the particles.

previous article A novel core–shell nanocomposite Ni–Ca@mSiO2 for benzophenone selective hydrogenation

next article Parametric analysis of the growth of colloidal ZnO nanoparticles synthesized in alcoholic medium

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Available only for authorised users

Albert K, Bayer EJ (1991) Characterization of bonded phases by solid-state NMR spectroscopy. J Chrom A 544:345–370

Arkhireeva A, Hay JNJ (2003) Synthesis of sub-200 nm silsesquioxane particles using a modified Stöber sol–gel route. Mater Chem 13:3122–3127

Arkhireeva A, Hay JN, Lane JM, Manzano M, Masters H, Oware W, Shaw SJJ (2004) Synthesis of organic-inorganic hybrid particles by sol-gel chemistry. Sol-Gel Sci Technol 31:31–36

Arkhireeva A, Hay JN, Oware WJ (2005) Non-Cryst Solids 351:1688–1695. J Non-Cryst Solids 351:1688–1695

Berthod AJ (1991) Silica: backbone material of liquid chromatographic column packings. J Chrom 549:1–28

Blaaderen A, Vrij A (1992) Synthesis and characterization of colloidal dispersions of fluorescent, monodisperse silica spheres. Langmuir 8:2921–2931

Brozek E, Zharov I (2009) Internal Functionalization and Surface Modification of Vinylsilsesquioxane Nanoparticles. Chem Mater 21:1451–1456

Buguslaw B, Welerowicz T (2004) Stationary phases with special structural properties for high-throughput separation techniques: preparation, characterization and applications. Comb Chem High T Scr 7:291–312

Burns A, Hooisweng O, Wiesner U (2006) Fluorescent core–shell silica nanoparticles: towards “Lab on a Particle” architectures for nanobiotechnology. Chem Soc Rev 35:1028–1042

Dash S, Mishra S, Patel S, Mishra BK (2008) Organically modified silica: synthesis and applications due to its surface interaction with organic molecules. Adv Colloid Interf Sci 140:77–94

Dobryanskaya GI, Zub YL, Barczak M, Dabrowski A (2006) Synthesis and structure-related adsorption characteristics of bifunctional polysiloxane xerogels with methyl and 3-mercaptopropyl groups. Coll J 68:548–557

Fontanals N, Marcé RM, Borrull F (2005) New hydrophilic materials for solid-phase extraction. Trends Anal Chem 24:394–406

Frenkel-Mullerad H, Avnir D (2000) The chemical reactivity of sol− gel materials: hydrobromination of ormosils. Chem Mater 12:3754–3759

Hoffmann F, Cornelius M, Morell J, Fröba M (2006) Silica-based mesoporous organic-inorganic hybrid materials.. Angew Chem Int Ed 45:3216–3251

Jin R-H, Yuan J-J (2005) Simple synthesis of hierarchically structured silicas by poly(ethyleneimine) aggregates preorganized by media modulation. Macromol Chem Phys 206:2160–2170

Jung CY, Kim JS, Kim HY, Ha JM, Kim YH, Koo SMJ (2012) One-pot synthesis and surface modifications of organically modified silica (ORMOSIL) particles having multiple functional groups. Colloid Interface Sci 367:67–73

Kumar R, Roy I, Ohulchanskky TY, Vathy LA, Bergey EJ, Sajjad M, Prasad PN (2010) In vivo biodistribution and clearance studies using multimodal organically modified silica nanoparticles. ACS Nano 4:699–708

Li H, Gui X, Zhang L, Wang S, Ji C, Wei J, Wang K, Zhu H, Wu D, Cao A (2010) Carbon nanotube sponge filters for trapping nanoparticles and dye molecules from water. Chem Commun 46:7966–7968

Loy DA, Gaugher BM, Baugher CR, Schneider DA, Rahimian K (2000) Substituent effects on the sol−gel chemistry of organotrialkoxysilanes. Chem Mat 12:3624–3632

Maciel GE. NMR characterization of functionalized polysiloxanes. In: Solid State NMR of Polymers, Ando I, Asakura T, editors. Amsterdam: Elsevier; 1998. p 923-84.

Nakamura M, Ishimura K (2008) One-pot synthesis and characterization of three kinds of thiol−organosilica nanoparticles. Langmuir 24:5099–5108

Prasannakumaran B, Pavithran C (2010) Bifunctionalized hybrid silica spheres by hydrolytic cocondensation of 3-aminopropyltriethoxysilane and vinyltriethoxysilane. Langmuir 26:730–735

Radu DR, Lai C-Y, Huang J, Shu X, Lin VS-Y (2005) Fine-tuning the degree of organic functionalization of mesoporous silica nanosphere materials via an interfacially designed co-condensation method. Chem Commun:1264–1266

Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotii RA, Rouquérol J, Siemieniewska T (1985) Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure Appl Chem 57:603–619

Stöber W, Fink A, Bohn E (1968) Controlled growth of monodisperse silica spheres in the micron size range. Colloidal Interface Sci 26:62–69

Takahashi K, Tadanaga K, Hayashi A, Tatsumisago M (2007) Preparation and characterization of polyaminophenylsilsesquioxane particles by two-step acid–base-catalyzed sol–gel process. Chem Lett 36:324–325

Trewyn BG, Giri S, Slowing II, Lin V (2007a) Mesoporous silica nanoparticle based controlled release, drug delivery, and biosensor systems. Chem Commun 3236–3245

Trewyn BG, Slowing II, Giri S, Chen H-T, Lin VS-Y (2007b) Synthesis and functionalization of a mesoporous silica nanoparticle based on the sol–gel process and applications in controlled release. Acc Chem Res 40:846–853

Türker AR (2007) New sorbents for solid-phase extraction for metal enrichment. Clean 35:548–557

Vervoort RJM, Debets AJJ, Claessens HA, Cramers CA, de Jong GJJ (2000) Optimisation and characterisation of silica-based reversed-phase liquid chromatographic systems for the analysis of basic pharmaceuticals. J Chromatogr A 897:1–22

Wan Y, Zhang D, Hao N, Zhao D (2007) Organic groups functionalised mesoporous silicates. Int J Nanotechnol 4:66–99

Wang W, Gu B, Hamilton WJ (2003) Fabrication of two- and three-dimensional silica nanocolloidal particle arrays. J Phys Chem B 107:3400–3404

Yoshitake H (2010) Design of functionalization and structural analysis of organically-modified siliceous oxides with periodic structures for the development of sorbents for hazardous substances. J Mater Chem 20:4537–4550

Zukoski CF, Look J-L, Bogush GH (1994) Formation of uniform precipitates from alkoxides. In: The colloid chemistry of silica, Adv in Chemistry Series 234:451–465

Title: Silsesquioxane nanoparticles with reactive internal functional groups
Authors: Eric M . Brozek
Nancy M. Washton
Karl T. Mueller
Ilya Zharov
Publication date: 01-02-2017
Publisher: Springer Netherlands
Published in: Journal of Nanoparticle Research / Issue 2/2017
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-017-3771-4

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 2/2017

Differential pattern of deposition of nanoparticles in the airways of exposed workers

Lysozyme complexes with thermo- and pH-responsive PNIPAM-b-PAA block copolymer

Mycorrhizal fungi influence on silver uptake and membrane protein gene expression following silver nanoparticle exposure

Molecular beam epitaxial growth of oriented and uniform Ge2Sb2Te5 nanoparticles with compact dimensions

A novel core–shell nanocomposite Ni–Ca@mSiO2 for benzophenone selective hydrogenation

A simple fast microwave-assisted synthesis of thermoelectric bismuth telluride nanoparticles from homogeneous reaction-mixture

Premium Partners