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Topics in Catalysis
Published in: Topics in Catalysis 8/2017

28-04-2017 | Original Paper

Stereoselective Carboperfluoroalkylation of Internal Alkynes: Mechanistic Insights

Authors: Zhaodong Li, Estíbaliz Merino, Cristina Nevado

Published in: Topics in Catalysis | Issue 8/2017

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Abstract

A Pd-catalyzed difunctionalization of internal alkynes combining boronic acids and perfluoroalkyl iodides under mild conditions is described here. Tetrasubstituted olefins containing perfluoroalkyl groups are synthesized in high yields in a regio- and stereoselective manner. Mechanistic studies have been carried out to shed light on the nature of the likely intermediates involved in these transformations.
previous article Preface
next article A Nonlinear Ordinary Differential Equation for Generating Graphical Rate Equations from Concentration Versus Time Data

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Metadata
Title
Stereoselective Carboperfluoroalkylation of Internal Alkynes: Mechanistic Insights
Authors
Zhaodong Li
Estíbaliz Merino
Cristina Nevado
Publication date
28-04-2017
Publisher
Springer US
Published in
Topics in Catalysis / Issue 8/2017
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-017-0743-y

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Preface

Preface

Original Paper

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