Top

Published in:

2020 | OriginalPaper | Chapter

13. Strategies Towards Improving the Stability of All-Inorganic Perovskite Quantum Dots

Authors : Kai Gu, Mu Yang, Hongshang Peng

Published in: Perovskite Quantum Dots

Publisher: Springer Singapore

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Perovskite quantum dots (PQDs) have attracted significant interests in the past few years because of their unique optical properties. Both all-inorganic and organic–inorganic perovskite quantum dots have shown great potential in optoelectronic devices such as light-emitting diodes (LEDs) for lighting and display technology. However, these commercial applications are severely impeded by their instability towards temperature, oxygen and moisture. Recently numerous strategies towards enhancing the stability of PQDs have been developed. This chapter reviews the strategies of improving the stability of all-inorganic perovskite quantum dots in detail, which are classified into two directions: (i) compositional adjustment and (ii) surface engineering.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

previous chapter Electrospun Nanofibers Embedded with Perovskite Quantum Dots

X. Lan, O. Voznyy, F.P. García de Arquer, M. Liu, J. Xu, A.H. Proppe, G. Walters, F. Fan, H. Tan, M. Liu, Z. Yang, S. Hoogland, E.H. Sargent, 10.6% Certified colloidal quantum dot solar cells via solvent-polarity-engineered halide passivation. Nano Lett. 16(7), 4630–4634 (2016). https://doi.org/10.1021/acs.nanolett.6b01957CrossRef

G.H. Carey, A.L. Abdelhady, Z. Ning, S.M. Thon, O.M. Bakr, E.H. Sargent, Colloidal quantum dot solar cells. Chem. Rev. 115(23), 12732–12763 (2015). https://doi.org/10.1021/acs.chemrev.5b00063CrossRef

N.J. Jeon, H. Na, E.H. Jung, T.-Y. Yang, Y.G. Lee, G. Kim, H.-W. Shin, S. Il Seok, J. Lee, J. Seo, A fluorene-terminated hole-transporting material for highly efficient and stable perovskite solar cells. Nat. Energy 3(8), 682–689 (2018). https://doi.org/10.1038/s41560-018-0200-6CrossRef

M.M. Adachi, F. Fan, D.P. Sellan, S. Hoogland, O. Voznyy, A.J. Houtepen, K.D. Parrish, P. Kanjanaboos, J.A. Malen, E.H. Sargent, Microsecond-sustained lasing from colloidal quantum dot solids. Nat. Commun. 6(1), 8694 (2015). https://doi.org/10.1038/ncomms9694CrossRef

Y. Wang, X. Li, X. Zhao, L. Xiao, H. Zeng, H. Sun, Nonlinear absorption and low-threshold multiphoton pumped stimulated emission from all-inorganic perovskite nanocrystals. Nano Lett. 16(1), 448–453 (2016). https://doi.org/10.1021/acs.nanolett.5b04110CrossRef

Y. Wang, X. Li, V. Nalla, H. Zeng, H. Sun, Solution-processed low threshold vertical cavity surface emitting lasers from all-inorganic perovskite nanocrystals. Adv. Func. Mater. 27(13), 1605088 (2017). https://doi.org/10.1002/adfm.201605088CrossRef

H. Cho, S.-H. Jeong, M.-H. Park, Y.-H. Kim, C. Wolf, C.-L. Lee, J.H. Heo, A. Sadhanala, N. Myoung, S. Yoo, Overcoming the electroluminescence efficiency limitations of perovskite light-emitting diodes. Science 350(6265), 1222–1225 (2015)CrossRef

Y.-H. Kim, C. Wolf, Y.-T. Kim, H. Cho, W. Kwon, S. Do, A. Sadhanala, C.G. Park, S.-W. Rhee, S.H. Im, R.H. Friend, T.-W. Lee, Highly efficient light-emitting diodes of colloidal metal-halide perovskite nanocrystals beyond quantum size. ACS Nano 11(7), 6586–6593 (2017). https://doi.org/10.1021/acsnano.6b07617CrossRef

L.N. Quan, F.P. García de Arquer, R.P. Sabatini, E.H. Sargent, Perovskites for light emission. Adv. Mater. 30(45), 1801996 (2018). https://doi.org/10.1002/adma.201801996CrossRef

10.

H. Wang, D.H. Kim, Perovskite-based photodetectors: materials and devices. Chem. Soc. Rev. 46(17), 5204–5236 (2017). https://doi.org/10.1039/C6CS00896HCrossRef

11.

Y. Dong, Y. Zou, J. Song, X. Song, H. Zeng, Recent progress of metal halide perovskite photodetectors. J. Mater. Chem. C 5(44), 11369–11394 (2017). https://doi.org/10.1039/C7TC03612DCrossRef

12.

H. Zhang, X. Wang, Q. Liao, Z. Xu, H. Li, L. Zheng, H. Fu, Embedding perovskite nanocrystals into a polymer matrix for tunable luminescence probes in cell imaging. Adv. Func. Mater. 27(7), 1604382 (2017). https://doi.org/10.1002/adfm.201604382CrossRef

13.

S. Lou, Z. Zhou, T. Xuan, H. Li, J. Jiao, H. Zhang, R. Gautier, J. Wang, Chemical transformation of lead halide perovskite into insoluble, less cytotoxic, and brightly luminescent cspbbr 3/cspb2br5 composite nanocrystals for cell imaging. ACS Appl. Mater. Interf. 11(27), 24241–24246 (2019). https://doi.org/10.1021/acsami.9b05484CrossRef

14.

F. Lang, O. Shargaieva, V.V. Brus, H.C. Neitzert, J. Rappich, N.H. Nickel, Influence of radiation on the properties and the stability of hybrid perovskites. Adv. Mater. 30(3), 1702905 (2018). https://doi.org/10.1002/adma.201702905CrossRef

15.

H. Cho, Y.-H. Kim, C. Wolf, H.-D. Lee, T.-W. Lee, Improving the stability of metal halide perovskite materials and light-emitting diodes. Adv. Mater. 30(42), 1704587 (2018). https://doi.org/10.1002/adma.201704587CrossRef

16.

L. Gomez, C. de Weerd, J.L. Hueso, T. Gregorkiewicz, Color-stable water-dispersed cesium lead halide perovskite nanocrystals. Nanoscale 9(2), 631–636 (2017)CrossRef

17.

X. Li, F. Cao, D. Yu, J. Chen, Z. Sun, Y. Shen, Y. Zhu, L. Wang, Y. Wei, Y. Wu, H. Zeng, All inorganic halide perovskites nanosystem: synthesis, structural features. Opt. Prop. Optoelectron. Appl. Small 13(9), 1603996 (2017). https://doi.org/10.1002/smll.201603996CrossRef

18.

V.K. Ravi, R.A. Scheidt, A. Nag, M. Kuno, P.V. Kamat, To exchange or not to exchange. Suppressing anion exchange in cesium lead halide perovskites with PbSO4–Oleate capping. ACS Energy Lett. 3(4), 1049–1055 (2018). https://doi.org/10.1021/acsenergylett.8b00380CrossRef

19.

Q.A. Akkerman, V. D’Innocenzo, S. Accornero, A. Scarpellini, A. Petrozza, M. Prato, L. Manna, Tuning the optical properties of cesium lead halide perovskite nanocrystals by anion exchange reactions. J. Am. Chem. Soc. 137(32), 10276–10281 (2015). https://doi.org/10.1021/jacs.5b05602CrossRef

20.

H.-C. Wang, S.-Y. Lin, A.-C. Tang, B.P. Singh, H.-C. Tong, C.-Y. Chen, Y.-C. Lee, T.-L. Tsai, R.-S. Liu, Mesoporous silica particles integrated with all-inorganic CsPbBr₃ perovskite quantum-dot nanocomposites (MP-PQDs) with high stability and wide color gamut used for backlight display. Angew. Chem. Int. Ed. 55(28), 7924–7929 (2016). https://doi.org/10.1002/anie.201603698CrossRef

21.

E.J. Juarez-Perez, Z. Hawash, S.R. Raga, L.K. Ono, Y. Qi, Thermal degradation of CH 3 NH 3 PbI 3 perovskite into NH 3 and CH 3 I gases observed by coupled thermogravimetry–mass spectrometry analysis. Energy Environ. Sci. 9(11), 3406–3410 (2016)CrossRef

22.

G.P. Nagabhushana, R. Shivaramaiah, A. Navrotsky, Direct calorimetric verification of thermodynamic instability of lead halide hybrid perovskites. Proc. Natl. Acad. Sci. 113(28), 7717–7721 (2016). https://doi.org/10.1073/pnas.1607850113CrossRef

23.

L. Protesescu, S. Yakunin, M.I. Bodnarchuk, F. Krieg, R. Caputo, C.H. Hendon, R.X. Yang, A. Walsh, M.V. Kovalenko, Nanocrystals of cesium lead halide perovskites (CsPbX₃, X = Cl, Br, and I): novel optoelectronic materials showing bright emission with wide color gamut. Nano Lett. 15(6), 3692–3696 (2015). https://doi.org/10.1021/nl5048779CrossRef

24.

H. Huang, M.I. Bodnarchuk, S.V. Kershaw, M.V. Kovalenko, A.L. Rogach, Lead halide perovskite nanocrystals in the research spotlight: stability and defect tolerance. ACS Energy Lett. 2(9), 2071–2083 (2017). https://doi.org/10.1021/acsenergylett.7b00547CrossRef

25.

Z. Li, M. Yang, J.-S. Park, S.-H. Wei, J.J. Berry, K. Zhu, Stabilizing perovskite structures by tuning tolerance factor: formation of formamidinium and cesium lead iodide solid-state alloys. Chem. Mater. 28(1), 284–292 (2016). https://doi.org/10.1021/acs.chemmater.5b04107CrossRef

26.

L. Protesescu, S. Yakunin, S. Kumar, J. Bär, F. Bertolotti, N. Masciocchi, A. Guagliardi, M. Grotevent, I. Shorubalko, M.I. Bodnarchuk, C.-J. Shih, M.V. Kovalenko, Dismantling the “Red Wall” of colloidal perovskites: highly luminescent formamidinium and formamidinium-cesium lead iodide nanocrystals. ACS Nano 11(3), 3119–3134 (2017). https://doi.org/10.1021/acsnano.7b00116CrossRef

27.

D. Amgar, T. Binyamin, V. Uvarov, L. Etgar, Near ultra-violet to mid-visible band gap tuning of mixed cation RbxCs1−xPbX3 (X = Cl or Br) perovskite nanoparticles. Nanoscale 10(13), 6060–6068 (2018). https://doi.org/10.1039/C7NR09607KCrossRef

28.

Z. Zhao, W. Xu, G. Pan, Y. Liu, M. Yang, S. Hua, X. Chen, H. Peng, H. Song, Enhancing the exciton emission of CsPbCl₃ perovskite quantum dots by incorporation of Rb⁺ ions. Mater. Res. Bull. 112, 142–146 (2019). https://doi.org/10.1016/j.materresbull.2018.12.004CrossRef

29.

D. Ghosh, P. Walsh Atkins, M.S. Islam, A.B. Walker, C. Eames, Good vibrations: locking of octahedral tilting in mixed-cation iodide perovskites for solar cells. ACS Energy Lett. 2(10), 2424–2429 (2017). https://doi.org/10.1021/acsenergylett.7b00729CrossRef

30.

S. Huang, B. Wang, Q. Zhang, Z. Li, A. Shan, L. Li, Postsynthesis potassium-modification method to improve stability of CsPbBr₃ perovskite nanocrystals. Adv. Opt. Mater. 6(6), 1701106 (2018). https://doi.org/10.1002/adom.201701106CrossRef

31.

Y. Liu, G. Pan, R. Wang, H. Shao, H. Wang, W. Xu, H. Cui, H. Song, Considerably enhanced exciton emission of CsPbCl₃ perovskite quantum dots by the introduction of potassium and lanthanide ions. Nanoscale 10(29), 14067–14072 (2018). https://doi.org/10.1039/C8NR03581DCrossRef

32.

B. Philippe, M. Saliba, J.-P. Correa-Baena, U.B. Cappel, S.-H. Turren-Cruz, M. Grätzel, A. Hagfeldt, H. Rensmo, Chemical distribution of multiple cation (Rb+, Cs+, MA+, and FA+) perovskite materials by photoelectron spectroscopy. Chem. Mater. 29(8), 3589–3596 (2017). https://doi.org/10.1021/acs.chemmater.7b00126CrossRef

33.

T.J. Jacobsson, S. Svanström, V. Andrei, J.P.H. Rivett, N. Kornienko, B. Philippe, U.B. Cappel, H. Rensmo, F. Deschler, G. Boschloo, Extending the compositional space of mixed lead halide perovskites by Cs, Rb, K, and Na doping. J. Phys. Chem. C 122(25), 13548–13557 (2018). https://doi.org/10.1021/acs.jpcc.7b12464CrossRef

34.

M. Saliba, T. Matsui, K. Domanski, J.-Y. Seo, A. Ummadisingu, S.M. Zakeeruddin, J.-P. Correa-Baena, W.R. Tress, A. Abate, A. Hagfeldt, M. Grätzel, Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance. Science 354(6309), 206–209 (2016). https://doi.org/10.1126/science.aah5557CrossRef

35.

C. Eames, J.M. Frost, P.R.F. Barnes, B.C. O’Regan, A. Walsh, M.S. Islam, Ionic transport in hybrid lead iodide perovskite solar cells. Nat. Commun. 6(1), 7497 (2015). https://doi.org/10.1038/ncomms8497CrossRef

36.

J. Pal, S. Manna, A. Mondal, S. Das, K.V. Adarsh, A. Nag, Colloidal synthesis and photophysics of M3Sb2I9 (M=Cs and Rb) nanocrystals: lead-free perovskites. Angew. Chem. Int. Ed. 56(45), 14187–14191 (2017). https://doi.org/10.1002/anie.201709040CrossRef

37.

W.J. Mir, A. Warankar, A. Acharya, S. Das, P. Mandal, A. Nag, Colloidal thallium halide nanocrystals with reasonable luminescence, carrier mobility and diffusion length. Chem. Sci. 8(6), 4602–4611 (2017)CrossRef

38.

A. Swarnkar, V.K. Ravi, A. Nag, Beyond colloidal cesium lead halide perovskite nanocrystals: analogous metal halides and doping. ACS Energy Lett. 2(5), 1089–1098 (2017). https://doi.org/10.1021/acsenergylett.7b00191CrossRef

39.

A. Swarnkar, W.J. Mir, A. Nag, Can B-site doping or alloying improve thermal—and phase-stability of all-inorganic CsPbX₃ (X = Cl, Br, I) Perovskites? ACS Energy Lett. 3(2), 286–289 (2018). https://doi.org/10.1021/acsenergylett.7b01197CrossRef

40.

S. Zou, Y. Liu, J. Li, C. Liu, R. Feng, F. Jiang, Y. Li, J. Song, H. Zeng, M. Hong, X. Chen, Stabilizing cesium lead halide perovskite lattice through Mn(II) substitution for air-stable light-emitting diodes. J. Am. Chem. Soc. 139(33), 11443–11450 (2017). https://doi.org/10.1021/jacs.7b04000CrossRef

41.

W. Liu, Q. Lin, H. Li, K. Wu, I. Robel, J.M. Pietryga, V.I. Klimov, Mn2+-doped lead halide perovskite nanocrystals with dual-color emission controlled by halide content. J. Am. Chem. Soc. 138(45), 14954–14961 (2016). https://doi.org/10.1021/jacs.6b08085CrossRef

42.

H. Liu, Z. Wu, J. Shao, D. Yao, H. Gao, Y. Liu, W. Yu, H. Zhang, B. Yang, CsPbxMn1–xCl3 perovskite quantum dots with high mn substitution ratio. ACS Nano 11(2), 2239–2247 (2017). https://doi.org/10.1021/acsnano.6b08747CrossRef

43.

W.J. Mir, M. Jagadeeswararao, S. Das, A. Nag, Colloidal Mn-doped cesium lead halide perovskite nanoplatelets. ACS Energy Lett. 2(3), 537–543 (2017). https://doi.org/10.1021/acsenergylett.6b00741CrossRef

44.

Q.A. Akkerman, D. Meggiolaro, Z. Dang, F. De Angelis, L. Manna, Fluorescent alloy CsPbxMn1–xI3 perovskite nanocrystals with high structural and optical stability. ACS Energy Lett. 2(9), 2183–2186 (2017). https://doi.org/10.1021/acsenergylett.7b00707CrossRef

45.

T.C. Jellicoe, J.M. Richter, H.F.J. Glass, M. Tabachnyk, R. Brady, S.E. Dutton, A. Rao, R.H. Friend, D. Crdgington, N.C. Greenham, M.L. Böhm, Synthesis and optical properties of lead-free cesium tin halide perovskite nanocrystals. J. Am. Chem. Soc. 138(9), 2941–2944 (2016). https://doi.org/10.1021/jacs.5b13470CrossRef

46.

M. Li, X. Zhang, K. Matras-Postolek, H.-S. Chen, P. Yang, An anion-driven Sn2+ exchange reaction in CsPbBr 3 nanocrystals towards tunable and high photoluminescence. J. Mater. Chem. C 6(20), 5506–5513 (2018). https://doi.org/10.1039/C8TC00990BCrossRef

47.

X. Zhang, W. Cao, W. Wang, B. Xu, S. Liu, H. Dai, S. Chen, K. Wang, X.W. Sun, Efficient light-emitting diodes based on green perovskite nanocrystals with mixed-metal cations. Nano Energy 30, 511–516 (2016). https://doi.org/10.1016/j.nanoen.2016.10.039CrossRef

48.

W. van der Stam, J.J. Geuchies, T. Altantzis, K.H.W. van den Bos, J.D. Meeldijk, S. Van Aert, S. Bals, D. Vanmaekelbergh, D.C. de Mello, Highly emissive divalent-ion-doped colloidal CsPb1–xMxBr₃ perovskite nanocrystals through cation exchange. J. Am. Chem. Soc. 139(11), 4087–4097 (2017). https://doi.org/10.1021/jacs.6b13079CrossRef

49.

J. Deng, H. Wang, J. Xun, J. Wang, X. Yang, W. Shen, M. Li, R. He, Room-temperature synthesis of excellent-performance CsPb1-xSnxBr₃ perovskite quantum dots and application in light emitting diodes. Mater. Des. 185, 108246 (2020). https://doi.org/10.1016/j.matdes.2019.108246CrossRef

50.

B. Saparov, J.-P. Sun, W. Meng, Z. Xiao, H.-S. Duan, O. Gunawan, D. Shin, I.G. Hill, Y. Yan, D.B. Mitzi, Thin-film deposition and characterization of a Sn-deficient perovskite derivative Cs2SnI₆. Chem. Mater. 28(7), 2315–2322 (2016). https://doi.org/10.1021/acs.chemmater.6b00433CrossRef

51.

H.-C. Wang, W. Wang, A.-C. Tang, H.-Y. Tsai, Z. Bao, T. Ihara, N. Yarita, H. Tahara, Y. Kanemitsu, S. Chen, R.-S. Liu, High-performance CsPb1−xSnxBr₃ perovskite quantum dots for light-emitting diodes. Angew. Chem. Int. Ed. 56(44), 13650–13654 (2017). https://doi.org/10.1002/anie.201706860CrossRef

52.

Z.-J. Yong, S.-Q. Guo, J.-P. Ma, J.-Y. Zhang, Z.-Y. Li, Y.-M. Chen, B.-B. Zhang, Y. Zhou, J. Shu, J.-L. Gu, L.-R. Zheng, O.M. Bakr, H.-T. Sun, Doping-enhanced short-range order of perovskite nanocrystals for near-unity violet luminescence quantum yield. J. Am. Chem. Soc. 140(31), 9942–9951 (2018). https://doi.org/10.1021/jacs.8b04763CrossRef

53.

M. Liu, G. Zhong, Y. Yin, J. Miao, K. Li, C. Wang, X. Xu, C. Shen, H. Meng, Aluminum-doped cesium lead bromide perovskite nanocrystals with stable blue photoluminescence used for display backlight. Adv. Sci. 4(11), 1700335 (2017). https://doi.org/10.1002/advs.201700335CrossRef

54.

C. Bi, S. Wang, Q. Li, S.V. Kershaw, J. Tian, A.L. Rogach, Thermally stable copper (II)-doped cesium lead halide perovskite quantum dots with strong blue emission. J. Phys. Chem. Lett. 10(5), 943–952 (2019). https://doi.org/10.1021/acs.jpclett.9b00290CrossRef

55.

X. Shen, Y. Zhang, S.V. Kershaw, T. Li, C. Wang, X. Zhang, W. Wang, D. Li, Y. Wang, M. Lu, L. Zhang, C. Sun, D. Zhao, G. Qin, X. Bai, W.W. Yu, A.L. Rogach, Zn-alloyed CsPbI₃ nanocrystals for highly efficient perovskite light-emitting devices. Nano Lett. 19(3), 1552–1559 (2019). https://doi.org/10.1021/acs.nanolett.8b04339CrossRef

56.

M. Lu, X. Zhang, Y. Zhang, J. Guo, X. Shen, W.W. Yu, A.L. Rogach, Simultaneous strontium doping and chlorine surface passivation improve luminescence intensity and stability of CsPbI₃ nanocrystals enabling efficient light-emitting devices. Adv. Mater. 30(50), 1804691 (2018). https://doi.org/10.1002/adma.201804691CrossRef

57.

G. Pan, X. Bai, D. Yang, X. Chen, P. Jing, S. Qu, L. Zhang, D. Zhou, J. Zhu, W. Xu, B. Dong, H. Song, Doping lanthanide into perovskite nanocrystals: highly improved and expanded optical properties. Nano Lett. 17(12), 8005–8011 (2017). https://doi.org/10.1021/acs.nanolett.7b04575CrossRef

58.

G. Lefevre, A. Herfurth, H. Kohlmann, A. Sayede, T. Wylezich, S. Welinski, P. Duarte Vaz, S.F. Parker, J.F. Blach, P. Goldner, N. Kunkel, Electron-phonon coupling in luminescent europium-doped hydride perovskites studied by luminescence spectroscopy, inelastic neutron scattering, and first-principles calculations. J. Phys. Chem. C 122(19), 10501–10509 (2018). https://doi.org/10.1021/acs.jpcc.8b01011CrossRef

59.

A.K. Jena, A. Kulkarni, Y. Sanehira, M. Ikegami, T. Miyasaka, Stabilization of α-CsPbI₃ in ambient room temperature conditions by incorporating Eu into CsPbI₃. Chem. Mater. 30(19), 6668–6674 (2018). https://doi.org/10.1021/acs.chemmater.8b01808CrossRef

60.

W. Xiang, Z. Wang, D.J. Kubicki, W. Tress, J. Luo, D. Prochowicz, S. Akin, L. Emsley, J. Zhou, G. Dietler, M. Grätzel, A. Hagfeldt, Europium-doped CsPbI2Br for stable and highly efficient inorganic perovskite solar cells. Joule 3(1), 205–214 (2019). https://doi.org/10.1016/j.joule.2018.10.008CrossRef

61.

X. Zhang, Y. Zhang, X. Zhang, W. Yin, Y. Wang, H. Wang, M. Lu, Z. Li, Z. Gu, W.W. Yu, Yb3+ and Yb3+/Er3+ doping for near-infrared emission and improved stability of CsPbCl₃ nanocrystals. J. Mater. Chem. C 6(37), 10101–10105 (2018). https://doi.org/10.1039/C8TC03957GCrossRef

62.

J.-S. Yao, J. Ge, B.-N. Han, K.-H. Wang, H.-B. Yao, H.-L. Yu, J.-H. Li, B.-S. Zhu, J.-Z. Song, C. Chen, Q. Zhang, H.-B. Zeng, Y. Luo, S.-H. Yu, Ce3+-doping to modulate photoluminescence kinetics for efficient CsPbBr₃ nanocrystals based light-emitting diodes. J. Am. Chem. Soc. 140(10), 3626–3634 (2018). https://doi.org/10.1021/jacs.7b11955CrossRef

63.

C.M. Guvenc, Y. Yalcinkaya, S. Ozen, H. Sahin, M.M. Demir, Gd3+-doped α-CsPbI₃ nanocrystals with better phase stability and optical properties. J. Phys. Chem. C 123(40), 24865–24872 (2019). https://doi.org/10.1021/acs.jpcc.9b05969CrossRef

64.

J. Kang, L.-W. Wang, High defect tolerance in lead halide perovskite CsPbBr₃. J. Phys. Chem. Lett. 8(2), 489–493 (2017). https://doi.org/10.1021/acs.jpclett.6b02800CrossRef

65.

J. Pan, L.N. Quan, Y. Zhao, W. Peng, B. Murali, S.P. Sarmah, M. Yuan, L. Sinatra, N.M. Alyami, J. Liu, E. Yassitepe, Z. Yang, O. Voznyy, R. Comin, M.N. Hedhili, O.F. Mohammed, Z.H. Lu, D.H. Kim, E.H. Sargent, O.M. Bakr, Highly efficient perovskite-quantum-dot light-emitting diodes by surface engineering. Adv. Mater. 28(39), 8718–8725 (2016). https://doi.org/10.1002/adma.201600784CrossRef

66.

C. Wang, A.S.R. Chesman, J.J. Jasieniak, Stabilizing the cubic perovskite phase of CsPbI3 nanocrystals by using an alkyl phosphinic acid. Chem. Commun. 53(1), 232–235 (2017). https://doi.org/10.1039/C6CC08282CCrossRef

67.

J. De Roo, M. Ibáñez, P. Geiregat, G. Nedelcu, W. Walravens, J. Maes, J.C. Martins, I. Van Driessche, M.V. Kovalenko, Z. Hens, Highly dynamic ligand binding and light absorption coefficient of cesium lead bromide perovskite nanocrystals. ACS Nano 10(2), 2071–2081 (2016). https://doi.org/10.1021/acsnano.5b06295CrossRef

68.

M. Green, The nature of quantum dot capping ligands. J. Mater. Chem. 20(28), 5797–5809 (2010). https://doi.org/10.1039/C0JM00007HCrossRef

69.

F. Liu, Y. Zhang, C. Ding, S. Kobayashi, T. Izuishi, N. Nakazawa, T. Toyoda, T. Ohta, S. Hayase, T. Minemoto, K. Yoshino, S. Dai, Q. Shen, Highly luminescent phase-stable cspbi3 perovskite quantum dots achieving near 100% absolute photoluminescence quantum yield. ACS Nano 11(10), 10373–10383 (2017). https://doi.org/10.1021/acsnano.7b05442CrossRef

70.

H. Wang, N. Sui, X. Bai, Y. Zhang, Q. Rice, F.J. Seo, Q. Zhang, V.L. Colvin, W.W. Yu, Emission recovery and stability enhancement of inorganic perovskite quantum dots. J. Phys. Chem. Lett. 9(15), 4166–4173 (2018). https://doi.org/10.1021/acs.jpclett.8b01752CrossRef

71.

B.A. Koscher, J.K. Swabeck, N.D. Bronstein, A.P. Alivisatos, Essentially trap-free CsPbBr₃ colloidal nanocrystals by postsynthetic thiocyanate surface treatment. J. Am. Chem. Soc. 139(19), 6566–6569 (2017). https://doi.org/10.1021/jacs.7b02817CrossRef

72.

L. Ruan, W. Shen, A. Wang, Q. Zhou, H. Zhang, Z. Deng, Stable and conductive lead halide perovskites facilitated by X-type ligands. Nanoscale 9(21), 7252–7259 (2017). https://doi.org/10.1039/C7NR02125ACrossRef

73.

F. Krieg, S.T. Ochsenbein, S. Yakunin, S. ten Brinck, P. Aellen, A. Süess, B. Clerc, D. Guggisberg, O. Nazarenko, Y. Shynkarenko, S. Kumar, C.-J. Shih, I. Infante, M.V. Kovalenko, Nanocrystals 2.0: zwitterionic capping ligands for improved durability and stability. ACS Energy Lett. 3(3), 641–646 (2018). https://doi.org/10.1021/acsenergylett.8b00035CrossRef

74.

J. Pan, Y. Shang, J. Yin, M. De Bastiani, W. Peng, I. Dursun, L. Sinatra, A.M. El-Zohry, M.N. Hedhili, A.-H. Emwas, O.F. Mohammed, Z. Ning, O.M. Bakr, Bidentate ligand-passivated CsPbI₃ perovskite nanocrystals for stable near-unity photoluminescence quantum yield and efficient red light-emitting diodes. J. Am. Chem. Soc. 140(2), 562–565 (2018). https://doi.org/10.1021/jacs.7b10647CrossRef

75.

F. Palazon, Q.A. Akkerman, M. Prato, L. Manna, X-ray lithography on perovskite nanocrystals films: from patterning with anion-exchange reactions to enhanced stability in air and water. ACS Nano 10(1), 1224–1230 (2016). https://doi.org/10.1021/acsnano.5b06536CrossRef

76.

C. Sun, Y. Zhang, C. Ruan, C. Yin, X. Wang, Y. Wang, W.W. Yu, Efficient and stable white leds with silica-coated inorganic perovskite quantum dots. Adv. Mater. 28(45), 10088–10094 (2016). https://doi.org/10.1002/adma.201603081CrossRef

77.

H. Hu, L. Wu, Y. Tan, Q. Zhong, M. Chen, Y. Qiu, D. Yang, B. Sun, Q. Zhang, Y. Yin, Interfacial synthesis of highly stable CsPbX₃/oxide janus nanoparticles. J. Am. Chem. Soc. 140(1), 406–412 (2018). https://doi.org/10.1021/jacs.7b11003CrossRef

78.

D.H. Park, J.S. Han, W. Kim, H.S. Jang, Facile synthesis of thermally stable CsPbBr₃ perovskite quantum dot-inorganic SiO₂ composites and their application to white light-emitting diodes with wide color gamut. Dyes Pigm. 149, 246–252 (2018). https://doi.org/10.1016/j.dyepig.2017.10.003CrossRef

79.

X. Li, Y. Wang, H. Sun, H. Zeng, Amino-mediated anchoring perovskite quantum dots for stable and low-threshold random lasing. Adv. Mater. 29(36), 1701185 (2017). https://doi.org/10.1002/adma.201701185CrossRef

80.

A. Loiudice, S. Saris, E. Oveisi, D.T.L. Alexander, R. Buonsanti, CsPbBr₃ QD/AlOx inorganic nanocomposites with exceptional stability in water, light, and heat. Angew. Chem. Int. Ed. 56(36), 10696–10701 (2017). https://doi.org/10.1002/anie.201703703CrossRef

81.

Y. Wei, H. Xiao, Z. Xie, S. Liang, S. Liang, X. Cai, S. Huang, A.A. Al Kheraif, H.S. Jang, Z. Cheng, J. Lin, Highly luminescent lead halide perovskite quantum dots in hierarchical CaF2 Matrices with enhanced stability as phosphors for white light-emitting diodes. Adv. Opt. Mater. 6(11), 1701343 (2018). https://doi.org/10.1002/adom.201701343CrossRef

82.

Z.-J. Li, E. Hofman, J. Li, A.H. Davis, C.-H. Tung, L.-Z. Wu, W. Zheng, Photoelectrochemically active and environmentally stable CsPbBr₃/TiO₂ core/shell nanocrystals. Adv. Func. Mater. 28(1), 1704288 (2018). https://doi.org/10.1002/adfm.201704288CrossRef

83.

S. Lou, T. Xuan, C. Yu, M. Cao, C. Xia, J. Wang, H. Li, Nanocomposites of CsPbBr₃ perovskite nanocrystals in an ammonium bromide framework with enhanced stability. J. Mater. Chem. C 5(30), 7431–7435 (2017). https://doi.org/10.1039/C7TC01174ACrossRef

84.

C.C. Lin, D.-H. Jiang, C.-C. Kuo, C.-J. Cho, Y.-H. Tsai, T. Satoh, C. Su, Water-resistant efficient stretchable perovskite-embedded fiber membranes for light-emitting diodes. ACS Appl. Mater. Interf. 10(3), 2210–2215 (2018). https://doi.org/10.1021/acsami.7b15989CrossRef

85.

K. Ma, X.-Y. Du, Y.-W. Zhang, S. Chen, In situ fabrication of halide perovskite nanocrystals embedded in polymer composites via microfluidic spinning microreactors. J. Mater. Chem. C 5(36), 9398–9404 (2017). https://doi.org/10.1039/C7TC02847DCrossRef

86.

M. Meyns, M. Perálvarez, A. Heuer-Jungemann, W. Hertog, M. Ibáñez, R. Nafria, A. Genç, J. Arbiol, M.V. Kovalenko, J. Carreras, A. Cabot, A.G. Kanaras, Polymer-enhanced stability of inorganic perovskite nanocrystals and their application in color conversion LEDs. ACS Appl. Mater. Interf. 8(30), 19579–19586 (2016). https://doi.org/10.1021/acsami.6b02529CrossRef

87.

S.N. Raja, Y. Bekenstein, M.A. Koc, S. Fischer, D. Zhang, L. Lin, R.O. Ritchie, P. Yang, A.P. Alivisatos, Encapsulation of perovskite nanocrystals into macroscale polymer matrices: enhanced stability and polarization. ACS Appl. Mater. Interf. 8(51), 35523–35533 (2016). https://doi.org/10.1021/acsami.6b09443CrossRef

88.

Y. Li, Y. Lv, Z. Guo, L. Dong, J. Zheng, C. Chai, N. Chen, Y. Lu, C. Chen, One-step preparation of long-term stable and flexible CsPbBr₃ perovskite quantum dots/ethylene vinyl acetate copolymer composite films for white light-emitting diodes. ACS Appl. Mater. Interf. 10(18), 15888–15894 (2018). https://doi.org/10.1021/acsami.8b02857CrossRef

89.

Q.A. Akkerman, G. Rainò, M.V. Kovalenko, L. Manna, Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals. Nat. Mater. 17(5), 394–405 (2018). https://doi.org/10.1038/s41563-018-0018-4CrossRef

Title: Strategies Towards Improving the Stability of All-Inorganic Perovskite Quantum Dots
Authors: Kai Gu
Mu Yang
Hongshang Peng
Publisher: Springer Singapore
Book: Perovskite Quantum Dots
Print ISBN: 978-981-15-6636-3

Electronic ISBN: 978-981-15-6637-0

Copyright Year: 2020
DOI: https://doi.org/10.1007/978-981-15-6637-0_13