Top

Published in:

2015 | OriginalPaper | Chapter

Structure and Properties of Rubbers With Silica Nanoparticles as Petroleum-Free Fillers

Authors : Masayuki Yamaguchi, Vu Anh Doan, Shogo Nobukawa

Published in: Eco-friendly Polymer Nanocomposites

Publisher: Springer India

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Silica nanoparticles, as a petroleum-free eco-friendly material, are being used in the rubber industry instead of carbon blacks. Silica nanoparticles are found to show nucleating ability for the crystallization of butadiene rubber. Furthermore, they show migration behavior from styrene-butadiene rubber to butadiene rubber by Brownian motion, indicating that the interfacial tension with butadiene rubber is lower than that with styrene-butadiene rubber.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

previous chapter Gold Nanoparticle-Reinforced Eco-friendly Polymer Nanocomposites and Their Applications

Anai M, Aizawa S, Ito M (2007) Phase control of BR/SBR by silica particles. J Soft Mater 3:64–69CrossRef

Bar G, Ganter M, Brandsch R, Delineau L (2002) Examination of butadiene/styrene-co-butadiene rubber blends by tapping mode atomic force microscopy. Importance of the indentation depth and reduced tip-sample energy dissipation in tapping mode atomic force microscope study of elastomers. Langmuir 16:5702–5711CrossRef

Bejarano J, Benavente R, Perez E, Wilhelm M, Quijada R, Palza H (2004) Effect of nucleating agents on crystallization and melting behavior and mechanical properties of nucleated syndiotactic poly(propylene). Macromol Mater Eng 289:818–827CrossRef

Bian J, Han L, Wang X, Wen X, Dong L (2010) Nonisothermal crystallization behavior and mechanical properties of poly(butylene succinate)/silica nanocomposites. J Appl Polym Sci 116:902–912

Chen Y, Peng Z, Kong LX, Huang MF, Li PW (2011) Dynamics near the filler surface in natural rubber-silica. Polymer 48:1674–1677

Cheng TL, Su AC (1995) Spherulites of cis 1,4 polybutadine: molecular weight effect. Polymer 36:73–80CrossRef

Chu W, Chen D (2011) Silica-modified SBR/BR blends. J Appl Polym Sci 120:3695–3700CrossRef

Cole JH, St-Pierre (1978) The role of interfacial energy in the heterogeneous nucleation of polyether crystallization. J Polym Sci Polym Symp 63:205–235CrossRef

Datta S (1999) Elastomer Blends. Polymer Blends, vol 2. Wiley, New York, pp 477–515

10.

Doan VA, Nobukawa S, Yamaguchi M (2012) Localization of nanofibers on the polymer surface using interface transfer technique. Compos B 43:1218–1223CrossRef

11.

Doan VA, Nobukawa S, Ohtsubo S, Tada T, Yamaguchi M (2012) Selective migration of silica particles between rubbers. J Polym Res 20:145–150CrossRef

12.

Doan VA, Nobukawa S, Ohtsubo S, Tada T, Yamaguchi M (2013) Crystallization behavior of polybutadiene containing silica particles. J Appl Polym Sci 128:1848–1853

13.

Doan VA, Nobukawa S, Ohtsubo S, Tada T, Yamaguchi M (2013) Transfer of tackifier between poly(butadiene) and poly(styrene-co-butadiene). J Mater Sci 48:2046–2052CrossRef

14.

Fujimoto K, Yoshimiya N (1968) Blends of cis-1,4-polybutadiene with natural or styrene butadiene rubber. Rubber Chem Technol 41:669–677CrossRef

15.

Grebowicz J, Aycock W, Wunderlich B (1986) Heat capacity of 1,4-polybutadiene. Polymer 27:575–582CrossRef

16.

Kaewsakul W, Sahakaro K, Dierkes WK, Noordermeer JWM (2013) Optimization of rubber formulation for silica-reinforced natural rubber compounds. Rub Chem Technol 86:313–329CrossRef

17.

Lee J, Lee KJ, Jang J (2008) Effect of silica nanofillers on isothermal crystallization of poly(vinyl alcohol): In-site ATR-FTIR study. Polym Test 27:360–367CrossRef

18.

Lorenzo MLD (2010) Crystallization kinetics of cis-1,4-polybutadiene. J Appl Polym Sci 116:1408–1413

19.

Marsh PA, Voet A, Price LD (1967) Electron microscopy of heterogeneous elastomer blends. Rubber Chem Technol 40:359–370CrossRef

20.

Meera AP, Said S, Grohens Y, Thomas S (2009) Nonlinear viscoelastic behavior of silica-filled natural rubber nanocomposites. J Phys Chem C 113:17997–18002CrossRef

21.

Mitchell JC (1963) The melting point of cis-1,4-polybutadiene. J Polym Sci Polym Lett 1:285–288CrossRef

22.

Mitchell JC (1967) Mechanical history effect in the crystallization of cis-1,4 polybutadiene. Polymer 8:369–379CrossRef

23.

Natta G, Corradini P (1956) Crystalline structure of 1,4-cis-polybutadiene and 1,4-cis-polyisoprene. Angew Chem 68:615–616CrossRef

24.

Natta G, Corradini P (1960) The crystal structure of cis 1,4 polybutadiene. Supplemento al Nouvo Cimento 15:111–121CrossRef

25.

Ougizawa T, Inoue T, Kammer HW (1985) UCST and LCST behavior in polymer blends. Macromolecules 18:2089–2092CrossRef

26.

Papageorgiou GZ, Papageorgiou DG, Chrissafis K, Bikiaris D, Will J, Hoppe A, Roether JA, Boccaccini AR (2014) Crystallization and melting behavior of poly(butylene succinate) nanocomposites containing silica-nanotubes and strontium hydroxyapatite nanorods. Ind Eng Chem Res 53:678–692CrossRef

27.

Papageorgiou DG, Vourlias G, Bikiaris D, Chrissafis K (2014) Synergistic effect of functionalized silica nanoparticles and nucleating agent for the improvement of the mechanical properties of propylene/ethylene random copolymer. Macromol Mater Eng 299:707–721CrossRef

28.

Pedrazzoli G, Pegoretti A, Kalaitzidou K (2014) Understanding the effect of silica nanoparticles and exfoliated graphite nanoparticles on the crystallization behavior of isotactic polypropylene. Polym Eng Sci 55:672-680

29.

Rafique FZ, Vasanthan N (2014) Crystallization, crystal structure, and isothermal melt crystallization kinetics of novel polyamide 6/SiO₂ nanocomposites prepared using the sol-gel technique. J Phys Chem B 118:9486–9495CrossRef

30.

Sun D, Li X, Zhang Y, Li Y (2011) Effect of modified nano-silica on the reinforcement of styrene butadiene rubber composites. J MAcromol Sci B Phys 50:1810-1821

31.

Turturro G, St-Pierre LE (1978) The heterogeneous nucleation of crystallization in isotactic polystyrene. J Colloid Inter Sci 67:349–354CrossRef

32.

Thakur VK, Grewell D, Thunga M, Kessler MR (2014) Novel composites from eco-friendly soy flour/sbs triblock copolymer. Macromol Mater Eng 299:953–958CrossRef

33.

Wunderlich B (1980) Macromolecular physics, vol. 3, Crystal melting, Academic press, New York

34.

Yoon H, Okamoto K, Umishita K, Yamaguchi M (2011) Development of conductive network of multi-walled carbon nanotubes in polycarbonate melt. Polym Comp 32:97–102CrossRef

35.

Yoon H, Okamoto K, Yamaguchi M (2009) Carbon nanotube imprinting on a polymer surface. Carbon 47:2840–2846CrossRef

36.

Zheng H, Wu J (2007) Preparation, crystallization, and spinnability of poly(ethylene terephthalate)/silica nanocomposites. J Appl Polym Sci 103:2564–2568CrossRef

Title: Structure and Properties of Rubbers With Silica Nanoparticles as Petroleum-Free Fillers
Authors: Masayuki Yamaguchi
Vu Anh Doan
Shogo Nobukawa
Publisher: Springer India
Book: Eco-friendly Polymer Nanocomposites
Print ISBN: 978-81-322-2472-3

Electronic ISBN: 978-81-322-2473-0

Copyright Year: 2015
DOI: https://doi.org/10.1007/978-81-322-2473-0_18

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Premium Partners