Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Polymer Science, Series C
Published in: Polymer Science, Series C 1/2023

26-09-2023

Study of the Effect of Nonselective Organic Solvent Nature on the Self-Organization of Amphiphilic Block Copolymers of D,L-Lactide and Ethylene Oxide in Aqueous Solution

Authors: E. V. Kuznetsova, E. M. Shirokova, Yu. A. Puchkova, E. V. Yastremsky, S. N. Chvalun

Published in: Polymer Science, Series C | Issue 1/2023

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The self-organization of biocompatible amphiphilic block copolymers of D,L-lactide and ethylene oxide with various hydrophobic poly(D,L-lactide) block length in aqueous media has been investigated. It has been shown that the nature of nonselective organic solvent has a considerable effect on the size, size polydispersity, and morphology of micelles of a block copolymer with a long poly(D,L-lactide) block. To elucidate the dependence of properties of block copolymer micelles on the common organic solvent type (acetone, tetrahydrofuran, N,N-dimethylformamide, and acetonitrile) various parameters of the used solvents have been estimated, and correlation between the Flory–Huggins coefficient and the surface tension between the hydrophobic block and the nonselective organic solvent and the parameters of micellar structures has been found.
previous article Stimuli-Responsive Systems Based on Polymer-like Wormlike Micelles of Ionic Surfactants and Their Modern Applications

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Appendix
Available only for authorised users
Literature
1.
2a.
2b.
2c.
3.
H. Phan, R. I. Minut, P. McCrorie, C. Vasey, R. R. Larder, E. Krumins, M. Marlow, R. Rahman, C. Alexander, V. Taresco, and A. K. Pearce, J. Polym. Sci., Part A: Polym. Chem. 57, 1801 (2019).CrossRef
4.
E. V. Razuvaeva, A. I. Kulebyakina, D. R. Streltsov, A. V. Bakirov, R. A. Kamyshinsky, N. M. Kuznetsov, S. N. Chvalun, and E. V. Shtykova, Langmuir 34, 15470 (2018).CrossRefPubMed
5.
Y. A. Kadina, E. V. Razuvaeva, D. R. Streltsov, N. G. Sedush, E. V. Shtykova, A. I. Kulebyakina, A. A. Puchkov, D. S. Volkov, A. A. Nazarov, and S. N. Chvalun, Molecules 26, 602 (2021).CrossRefPubMedPubMedCentral
6.
A. M. Desyatskova, E. V. Kuznetsova, Y. A. Puchkova, E. V. Yastremsky, A. V. Bakirov, P. V. Dmitryakov, A. I. Buzin, and S. N. Chvalun, Mendeleev Commun. 33, 86 (2023).CrossRef
7.
N. G. Sedush, Y. A. Kadina, E. V. Razuvaeva, A. A. Puchkov, E. M. Shirokova, V. I. Gomzyak, K. T. Kalinin, A. I. Kulebyakina, and S. N. Chvalun, Nanobiotechnol. Rev. 16, 421 (2021).CrossRef
8.
I. Ali, F. Kareem, S. Rahim, S. Perveen, S. Ahmed, M. R. Shah, and M. I. Malik, React. Funct. Polym. 150, 104553 (2020).
9.
A. A. Efimova, A. V. Sybachin, S. N. Chvalun, A. I. Kulebyakina, E. V. Kozlova, and A. A. Yaroslavov, Polym. Sci., Ser. B 57 (2), 140 (2015).CrossRef
10.
A. A. Efimova, S. N. Chvalun, A. I. Kulebyakina, E. V. Kozlova, and A. A. Yaroslavov, Polym. Sci., Ser. A 58 (2), 172 (2016).CrossRef
11.
12.
Z. Lin, L. Xi, S. Chen, J. Tao, Y. Wang, X. Chen, P. Li, Z. Wang, and Y. Zheng, Acta Pharm. Sin. B 11, 1047 (2021).CrossRefPubMed
13.
14.
15.
P. Bhargava, J. X. Zheng, P. Li, R. P. Quirk, F. W. Harris, and S. Z. D. Cheng, Macromolecules 39, 4880 (2006).CrossRef
16.
T. Riley, S. Stolnik, C. R. Heald, C. D. Xiong, M. C. Garnett, L. Illum, S. S. Davis, S. C. Purkiss, R. J. Barlow, and P. R. Gellert, Langmuir 17, 3168 (2001).CrossRef
17.
I. A. B. Pijpers, F. Meng, J. C. M. van Hest, and L. K. E. A. Abdelmohsen, Polym. Chem. 11, 275 (2020).CrossRef
18.
R. Simonutti, D. Bertani, R. Marotta, S. Ferrario, D. Manzone, M. Mauri, M. Gregori, A. Orlando, and M. Masserini, Polymer 218, 123511 (2021).
19.
I. Astafieva, X. F. Zhong, and A. Eisenberg, Macromolecules 26, 7339 (1993).CrossRef
20.
21.
E. Tomaszewska, K. Soliwoda, K. Kadziola, B. Tkacz-Szczesna, G. Celichowski, M. Cichomski, W. Szmaja, and J. J. Grobelny, Nanomater. 2013, 1 (2013).CrossRef
22.
A. M. de Oliveira, E. Jӓger, A. Jӓger, P. Stepánek, and E. C. Giacomeli, Colloids Surf., A 436, 1092 (2013).CrossRef
23.
E. V. Kuznetsova, N. M. Kuznetsov, K. T. Kalinin, P. V. Lebedev-Stepanov, A. A. Novikov, and S. N. Chvalun, Colloid J. 84, 704 (2022).CrossRef
24.
A. D. Glova, S. G. Falkovich, D. I. Dmitrienko, A. V. Lyulin, S. V. Larin, V. M. Nazarychev, M. Karttunen, and S. V. Lyulin, Macromolecules 51, 552 (2018).CrossRef
25.
J. X. Zheng, H. Xiong, W. Y. Chen, K. Lee, R. M. Van Horn, R. P. Quirk, B. Lotz, E. L. Thomas, A.-C. Shi, and S. Z. D. Cheng, Macromolecules 39, 641 (2006).CrossRef
26.
27.
28.
29.
Properties of Solvents Used in Organic Chemistry http://​murov.​info/​orgsolvents.​htm (accessed on April 20, 2023).
30.
31.
G. Ovejero, P. Pérez, M. D. Romero, I. Guzmán, and E. Diéz, Eur. Polym. J. 43, 1444 (2007).CrossRef
32.
33.
34.
35.
Hansen Solubility Parameters. A User’s Handbook, 2nd ed. (CRC Press Taylor and Francis, Boca Raton, 2007).
36.
S. Venkatram, C. Kim, A. Chandrasekaran, and R. Ramprasad, J. Chem. Inf. Model. 59, 4188 (2019).CrossRefPubMed
Metadata
Title
Study of the Effect of Nonselective Organic Solvent Nature on the Self-Organization of Amphiphilic Block Copolymers of D,L-Lactide and Ethylene Oxide in Aqueous Solution
Authors
E. V. Kuznetsova
E. M. Shirokova
Yu. A. Puchkova
E. V. Yastremsky
S. N. Chvalun
Publication date
26-09-2023
Publisher
Pleiades Publishing
Published in
Polymer Science, Series C / Issue 1/2023
Print ISSN: 1811-2382
Electronic ISSN: 1555-614X
DOI
https://doi.org/10.1134/S1811238223700352

Other articles of this Issue 1/2023

Polymer Science, Series C 1/2023 Go to the issue

OriginalPaper

History and Perspectives of Atomistic Simulation of Polysaccharides

OriginalPaper

The Rheological Behavior of Polymer Solution Threads

OriginalPaper

Diblock Copolymer Melt in an Electric Field: Stability of the Homogeneous State in the Random Phase Approximation

OriginalPaper

Geometric Features of Structuring of Amphiphilic Macromolecules on the Surface of a Spherical Nanoparticle

OriginalPaper

Adsorption of Random Copolymer on a Chemically Heterogeneous Periodic Stripe-Patterned Surface

OriginalPaper

Stimuli-Responsive Systems Based on Polymer-like Wormlike Micelles of Ionic Surfactants and Their Modern Applications

Premium Partners

    Image Credits