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2012 | OriginalPaper | Chapter

25. Sulfur and Sulfuric Acid

Authors : Gerard E. d’Aquin, Robert C. Fell

Published in: Handbook of Industrial Chemistry and Biotechnology

Publisher: Springer US

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Abstract

Sulfur is one of the few elements that is found in its elemental form in nature. Typical sulfur deposits occur in sedimentary limestone/gypsum formations, in limestone/anhydrite formations associated with salt domes or in volcanic rock [1]. A yellow solid at normal temperature, sulfur becomes progressively lighter in color at lower temperatures and is almost white at the temperature of liquid air. It melts at 114–119°C (depending on crystalline form) to a yellow liquid which turns orange as the temperature is increased. The low viscosity of the liquid begins to rise sharply above 160°C, peaking at 93 Pas at 188°C, and then falling as the temperature continues to rise to its boiling point of 445°C. This and other anomalous properties of the liquid state are due to equilibria between the various molecular species of sulfur which includes small chains and rings.

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Literature
1.
go back to reference British Sulphur Corp: Ltd, Sulphur, No. 193,33–36 (Nov/Dec. 1987) British Sulphur Corp: Ltd, Sulphur, No. 193,33–36 (Nov/Dec. 1987)
2.
go back to reference d’Aquin GE North American Quarterly Sulfur Review, Con-Sul, Inc., Bigfork; Jan 15 d’Aquin GE North American Quarterly Sulfur Review, Con-Sul, Inc., Bigfork; Jan 15
3.
go back to reference (a) Sulfur Magazine, No. 259, p 41, Nov–Dec 1998, Gerrie du Plessis. (b) Hyne JB, “The Forming, Handling and 1230 Transportation of Elemental Sulphur, Presented at Sulphur 1990 Conference, British Sulphur Corporation, London (a) Sulfur Magazine, No. 259, p 41, Nov–Dec 1998, Gerrie du Plessis. (b) Hyne JB, “The Forming, Handling and 1230 Transportation of Elemental Sulphur, Presented at Sulphur 1990 Conference, British Sulphur Corporation, London
4.
go back to reference (a) Ibid, 45(b). (b) Kemp E, Hyne JB, Rennie W (1971) Reaction of Elemental Sulfur with Water Under U.V Radiation. Internal. J. Sulfur Chem Part Al(1) 69–70 (a) Ibid, 45(b). (b) Kemp E, Hyne JB, Rennie W (1971) Reaction of Elemental Sulfur with Water Under U.V Radiation. Internal. J. Sulfur Chem Part Al(1) 69–70
5.
go back to reference (a) Personal communication, Pennzoil Sulphur Co. Operations at Antwerp terminal. (b) Dowling, N.I., Clark PD, Hyne JB (1996) Understanding and Mitigating Corrosion During Handling and Transportation of Elemental Sulfur. Sulphur 1996 Conference, British Sulphur Corporation, London (a) Personal communication, Pennzoil Sulphur Co. Operations at Antwerp terminal. (b) Dowling, N.I., Clark PD, Hyne JB (1996) Understanding and Mitigating Corrosion During Handling and Transportation of Elemental Sulfur. Sulphur 1996 Conference, British Sulphur Corporation, London
6.
go back to reference Sandvik Process Systems, Inc., 21 Campus Rd., Totowa, NJ, USA Sandvik Process Systems, Inc., 21 Campus Rd., Totowa, NJ, USA
7.
go back to reference Berndorf Belt Systems USA, 920 Estes Avenue, Schaumburg, IL, USA Berndorf Belt Systems USA, 920 Estes Avenue, Schaumburg, IL, USA
8.
go back to reference Devco International, Inc., 6846 S. Canton Ave., Suite 400, Tulsa, OK, USA Devco International, Inc., 6846 S. Canton Ave., Suite 400, Tulsa, OK, USA
9.
go back to reference Martin Midstream Partners, P.O. Box 191, Kilgore, TX, 75663 Martin Midstream Partners, P.O. Box 191, Kilgore, TX, 75663
10.
go back to reference Enersul, Inc., 7210 Blackfoot Tr. SE, Calgary, Alberta, Canada Enersul, Inc., 7210 Blackfoot Tr. SE, Calgary, Alberta, Canada
11.
go back to reference Kaltenbach-Thuring SA, 9 Rue de l’Industrie, 6000 Beauvais, France. Kaltenbach-Thuring SA, 9 Rue de l’Industrie, 6000 Beauvais, France.
12.
go back to reference d’Aquin GE (2002) Transporting sulfur pellets, U.S. Patent 6368029, Apr. 9, 2002 d’Aquin GE (2002) Transporting sulfur pellets, U.S. Patent 6368029, Apr. 9, 2002
13.
go back to reference Hyne JB. Some Impurities in Elemental Sulphur-Origins and Elimination. Sulphur 1991 Conference, The British Sulphur Corp, London Hyne JB. Some Impurities in Elemental Sulphur-Origins and Elimination. Sulphur 1991 Conference, The British Sulphur Corp, London
14.
go back to reference Thieler E (1936) Sulphur. Theodor Steinkopff, Leipzig Thieler E (1936) Sulphur. Theodor Steinkopff, Leipzig
15.
go back to reference Iraq and Poland were the only nations with operating Frasch mines in 2001. In 2012, Poland remains in production and Iraq is considering re-starting operations. Iraq and Poland were the only nations with operating Frasch mines in 2001. In 2012, Poland remains in production and Iraq is considering re-starting operations.
16.
go back to reference BC Insight (2010) Sulphur Magazine, Jan/Feb, 2011; US Geological Survey 2000 BC Insight (2010) Sulphur Magazine, Jan/Feb, 2011; US Geological Survey 2000
17.
go back to reference d’Aquin GE (Apr 2002, Apr 2011) North American Quarterly Sulphur Review, Con-Sul, Inc., Bigfork, MT d’Aquin GE (Apr 2002, Apr 2011) North American Quarterly Sulphur Review, Con-Sul, Inc., Bigfork, MT
19.
go back to reference British Sulphur Corp. London (Nov/Dec. 1987) Sulphur, No. 193, 26–30 British Sulphur Corp. London (Nov/Dec. 1987) Sulphur, No. 193, 26–30
20.
go back to reference British Sulphur Corp. London (Sept./Oct. 1987) Sulphur, No. 192, 30–39 British Sulphur Corp. London (Sept./Oct. 1987) Sulphur, No. 192, 30–39
21.
go back to reference Rameshi M. State of the art in gas Treating, Sulphur 2000 Conference, The British Sulphur Corporation, London Rameshi M. State of the art in gas Treating, Sulphur 2000 Conference, The British Sulphur Corporation, London
24.
go back to reference Ober J. Sulfur-2000 Annual report, Mineral industry surveys, U.S. Geological Survey, U.S. Dept of the Interior, Reston, VA Ober J. Sulfur-2000 Annual report, Mineral industry surveys, U.S. Geological Survey, U.S. Dept of the Interior, Reston, VA
25.
go back to reference Sander UHE, Fischer H, Rothe U, Kola R. (1984) Sulphur. Sulphur dioxide, and sulphuric acid. Verlag Chemie, Weinheim, Germany Sander UHE, Fischer H, Rothe U, Kola R. (1984) Sulphur. Sulphur dioxide, and sulphuric acid. Verlag Chemie, Weinheim, Germany
26.
go back to reference Heydorn B, Aguiar D, Ferguson A (1987) Sulfuric acid. In: Chemical economics handbook. SRI International, Menlo Park, CA Heydorn B, Aguiar D, Ferguson A (1987) Sulfuric acid. In: Chemical economics handbook. SRI International, Menlo Park, CA
27.
go back to reference Fairlie AM (1936) Sulfuric acid manufacture. Reinhold, New York Fairlie AM (1936) Sulfuric acid manufacture. Reinhold, New York
28.
go back to reference Duecker WW, West JR (eds) (1959) The manufacture of sulfuric acid. Van Nostrand Reinhold, New York Duecker WW, West JR (eds) (1959) The manufacture of sulfuric acid. Van Nostrand Reinhold, New York
29.
go back to reference Wyld W (1923) Sulphuric acid and sulphur dioxide raw materials. D. Van Nostrand, New York Wyld W (1923) Sulphuric acid and sulphur dioxide raw materials. D. Van Nostrand, New York
30.
go back to reference The British Sulphur Corp. Ltd (1989) World sulphur and sulphuric acid atlas, 5th edn. Purley Press Ltd, London The British Sulphur Corp. Ltd (1989) World sulphur and sulphuric acid atlas, 5th edn. Purley Press Ltd, London
32.
go back to reference Sohn HY, George DB, Zunkel AD (1983) Advances in sulfide smelting. The Metallurgical Society of AIME, Warrendale, PA Sohn HY, George DB, Zunkel AD (1983) Advances in sulfide smelting. The Metallurgical Society of AIME, Warrendale, PA
33.
go back to reference British Sulphur Corp. London (1987) Sulphur, No. 190, 33–40 British Sulphur Corp. London (1987) Sulphur, No. 190, 33–40
34.
go back to reference Bhambri N, Fell RC, Fries RM, Ritschel PM. Metallurgical Sulfuric Acid Plants for the New Millennium. In: Sulphur 1998 conference, British Sulphur Corporation, London Bhambri N, Fell RC, Fries RM, Ritschel PM. Metallurgical Sulfuric Acid Plants for the New Millennium. In: Sulphur 1998 conference, British Sulphur Corporation, London
36.
go back to reference Friedman L (1988) The Sulfuric Acid Plant Recent Advances-Reviews and Analysis. AIChE Meeting, Clearwater, FL. Friedman L (1988) The Sulfuric Acid Plant Recent Advances-Reviews and Analysis. AIChE Meeting, Clearwater, FL.
37.
go back to reference British Sulphur Corp. London. (1990) Sulphur, No. 203, 24–32 British Sulphur Corp. London. (1990) Sulphur, No. 203, 24–32
39.
go back to reference British Sulphur Corp. Ltd (1990) Sulphur 207:37–41 British Sulphur Corp. Ltd (1990) Sulphur 207:37–41
41.
go back to reference Davies M, Hodgson DS, Rodda I (1988) Applications of SARAMET in H2S04 plants. Sulphur 1988 Conference, British Sulphur Corporation, London Davies M, Hodgson DS, Rodda I (1988) Applications of SARAMET in H2S04 plants. Sulphur 1988 Conference, British Sulphur Corporation, London
42.
go back to reference Douren L (1987) Sandvik SX-The Future Material for Concentrated Sulfuric Acid. Sulphur 1987 Conference, British Sulphur Corporation, London. Douren L (1987) Sandvik SX-The Future Material for Concentrated Sulfuric Acid. Sulphur 1987 Conference, British Sulphur Corporation, London.
43.
go back to reference Holdschick H, Jurascheck MA (1988) Advances in the Development of Cast Materials for High Concentrated Sulphuric Acid at Temperatures up to 280°C. Paper read at Sulphur 1988 Conference, British Sulphur Corporation, London Holdschick H, Jurascheck MA (1988) Advances in the Development of Cast Materials for High Concentrated Sulphuric Acid at Temperatures up to 280°C. Paper read at Sulphur 1988 Conference, British Sulphur Corporation, London
44.
go back to reference Puricelli S, Fell RC, Randolph DR (2000) The State of Sulfuric Acid Technology. AlChE meeting, Clearwater, FL. Puricelli S, Fell RC, Randolph DR (2000) The State of Sulfuric Acid Technology. AlChE meeting, Clearwater, FL.
45.
go back to reference McAlister DR, Grendel RW, Schneider D, Shafer IR, Tucker IS (1990) A Sulfuric Acid Plant for the 1990s, Sulphur 1990 Conference, British Sulphur Corporation, London. McAlister DR, Grendel RW, Schneider D, Shafer IR, Tucker IS (1990) A Sulfuric Acid Plant for the 1990s, Sulphur 1990 Conference, British Sulphur Corporation, London.
46.
go back to reference Blicharz M (1988) Different Methods of Sulphur Removal from Gas from Non-ferrous Metal Works. Sulphur 1988 Conference, British Sulphur Corporation, London. Blicharz M (1988) Different Methods of Sulphur Removal from Gas from Non-ferrous Metal Works. Sulphur 1988 Conference, British Sulphur Corporation, London.
47.
go back to reference Matros YS, Bunimovich GA (1990) Reverse Process of S02 Oxidation in Sulfuric Acid Production. Sulphur 1990 Conference, British Sulphur Corporation, London. Matros YS, Bunimovich GA (1990) Reverse Process of S02 Oxidation in Sulfuric Acid Production. Sulphur 1990 Conference, British Sulphur Corporation, London.
48.
go back to reference Shafer, IR (1988) Namhae Heat Recovery System Update. Fertilizer Industry Round Table, Baltimore, MD. Shafer, IR (1988) Namhae Heat Recovery System Update. Fertilizer Industry Round Table, Baltimore, MD.
49.
go back to reference Smith RM, Sheputis I, Kim UB, Chin YB (1988) Sulfuric Acid Heat Recovery System (HRS) Operations at Namhae Chemical Corporation, Korea. Sulphur 1988, British Sulphur Corporation, London. Smith RM, Sheputis I, Kim UB, Chin YB (1988) Sulfuric Acid Heat Recovery System (HRS) Operations at Namhae Chemical Corporation, Korea. Sulphur 1988, British Sulphur Corporation, London.
51.
go back to reference Lebel G (1990) Pilot Plant Development of the Chemetics TiO2 Waste Acid Recovery Process. Sulphur 1990 Conference, British Sulphur Corporation, London Lebel G (1990) Pilot Plant Development of the Chemetics TiO2 Waste Acid Recovery Process. Sulphur 1990 Conference, British Sulphur Corporation, London
52.
go back to reference British Sulphur Corp. Ltd (1997) Sulphur 253:67–69 British Sulphur Corp. Ltd (1997) Sulphur 253:67–69
53.
go back to reference Polk P (2005) e-mail to Fell, R.C., Topsoe Houston, Tx. Polk P (2005) e-mail to Fell, R.C., Topsoe Houston, Tx.
Metadata
Title
Sulfur and Sulfuric Acid
Authors
Gerard E. d’Aquin
Robert C. Fell
Copyright Year
2012
Publisher
Springer US
DOI
https://doi.org/10.1007/978-1-4614-4259-2_25