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Journal of Polymer Research
Published in: Journal of Polymer Research 2/2020

01-02-2020 | ORIGINAL PAPER

Superabsorbent polymer based on guar gum-graft-acrylamide: synthesis and characterization

Authors: Arpit Sand, Aparna Vyas

Published in: Journal of Polymer Research | Issue 2/2020

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Abstract

Superabsorbent polymers of guar gum -graft-acrylamide were synthesized using KPS as a free radical initiator in the presence of Tetra (ethylene glycol) diacrylate as a cross linker using solution graft copolymerization technique. The structures of the grafted copolymers GG-g-PAAm were characterized by FT-IR spectroscopy thermo gravimetric and SEM analysis. The effect of reaction parameters such as concentration of guar gum, acrylamide, KPS, crosslinker (TEGDA), and NaOH (neutralizing agent) were optimized to achieve a superabsorbent polymers with high swelling capacity of 80 g/g (deionisied water) and 22 g/g (0.8 wt% sodium chloride solution). The swelling kinetics of the synthesized superabsorbent were analyzed by applying the Fickian diffusion model and the Schott’s pseudo second order kinetics model, illuminating that chain leisure behavior during absorption had a great effect on whole absorbency.
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Metadata
Title
Superabsorbent polymer based on guar gum-graft-acrylamide: synthesis and characterization
Authors
Arpit Sand
Aparna Vyas
Publication date
01-02-2020
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 2/2020
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-019-1951-x

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