Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Journal of Nanoparticle Research
Published in: Journal of Nanoparticle Research 8/2014

01-08-2014 | Research Paper

Surface, thermal, and mechanical properties of composites and nanocomposites of polyurethane/PTFE nanoparticles

Authors: P. S. Anbinder, P. J. Peruzzo, A. de Siervo, J. I. Amalvy

Published in: Journal of Nanoparticle Research | Issue 8/2014

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Films from blends of polyurethane and nano-polytetrafluoroethylene aqueous dispersions (PU/nanoPTFE) were prepared, and the effect of the addition of different amounts of PTFE nanoparticles (50 nm) was studied. The changes in the superficial properties of the films were studied by means of XPS, ATR/FTIR, and contact angle measurements. SEM and TEM results are also included. The contact angle values confirm the surface hydrophobicity of composite films. Even though nanoparticles are present in the bulk, higher concentrations of particles appear at the surface in samples with lower nanoPTFE content (up to 10 wt%), as revealed by XPS. Higher amounts of nanoPTFE particles cause aggregation. The mechanical and thermal properties of composites are also discussed.
previous article Magnetite nanoparticles functionalized with α-tocopheryl succinate (α-TOS) promote selective cervical cancer cell death
next article PEGylated graphene oxide as a nanocarrier for podophyllotoxin

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
Abdulkadir A, Baki H, Yusuf M, Sefix S (2006) Synthesis, characterization and surface properties of amphiphilic polystyrene-b-polypropylene glycol block copolymers. Eur Polym J 42:740–750CrossRef
Balkenende AR, van de Boogaard HJAP, Schloten M, Willard NP (1998) Evaluation of different approaches to assess the surface tension of low-energy solids by means of contact angle measurements. Langmuir 14:5907–5912CrossRef
Beamson G, Briggs D (1992) High resolution XPS of organic polymers—the scienta ESCA300 database. John Wiley & Sons, New York
Chattopadhyay DK, Mishra AK, Sreedhar B, Raju KVSN (2006) Thermal and viscoelastic properties of polyurethane-imide/clay hybrid coatings. Polym Degrad Stab 91:1837–1849CrossRef
Durrieu V, Gandini A, Belgacem MN, Blayo A, Eisele G, Putaux J-L (2004) Preparation of aqueous anionic poly-(urethane-urea) dispersions: influence of the nature and proportion of the urethane groups on the dispersion and polymer properties. J Appl Polym Sci 94:700–710CrossRef
Eckesley ST, Helmer BJ (1997) Mechanistic considerations of particle size effects on film properties of hard/soft latex blends. J Coat Technol 69:97–107CrossRef
Giani E, Sparnacci K, Laus M, Palamone G, Kapeliouchko V, Arcella V (2003) TFE − polystyrene core − shell nanospheres and nanocomposites. Macromolecules 36:4360–4367CrossRef
Hosokawa M, Nogi K, Naito M, Yokoyama T (2007) Nanoparticle technology handbook. Elsevier, Amsterdam 18
Huang T, Lu R, Wang H, Ma Y, Tian J, Li T (2011) Investigation on the tribological properties of POM modified by nano-PTFE. J Macromol Sci B Phys 50:1235–1248CrossRef
Jeong HY, Lee MH, Kim BK (2006) Surface modification of waterborne polyurethane. Colloids and surfaces A: physicochem. Eng Asp 290:178–185CrossRef
Kapeliouchko V, Palamone G, Poggio T, Zuccheri G, Passeri R, Sparnacci K, Antonioli D, Deregibus S, Laus M (2009) PMMA-based core-shell nanoparticles with various PTFE cores. J Polym Sci A 47:2928–2937CrossRef
Król P (2007) Synthesis methods, chemical structures and phase structures of linear polyurethanes. Prog Mat Sci 52:915–1015CrossRef
Lai YK, Lin CJ, Wang H, Huang HY, Zhuang HF (2008) Superhydrophilic-superhydrophobic micropattern on TiO2 nanotube films by photocatalytic lithography. Electrochem Commun 10:387–391CrossRef
Lakshmi RV, Basu BJ (2009) Fabrication of superhydrophobic sol–gel composite films using hydrophobically modified colloidal zinc hydroxide. J Colloid Interface Sci 339:454–460CrossRef
Lee MH, Jang MK, Kim BK (2007) Surface modification of high heat resistant UV-cured polyurethane dispersions. Eur Polym J 43:4271–4278CrossRef
Li M, Zhai J, Liu H, Song YL, Jiang L, Zhu DB (2003) Electrochemical deposition of conductive superhydrophobic zinc oxide thin films. J Phys Chem B 107:9954–9957
Liu H, Shang Q, Xiao G, Lv J (2011) Fabrication of stable superhydrophobic coatings with bicomponent polyurethane/polytetrafluoroethylene composites. Asian J Chem 23:2866–2870
Marchese E, Kapeliouchko V, Colaiana P (2001) TFE polymerization process. US Patent 6,297,334
Meng HF, Wang ST, Xi JM, Tang ZY, Jiang L (2008) Facile means of preparing super amphiphobic surfaces on common engineering metals. J Phys Chem C 112:11454–11458CrossRef
Owens DK, Wendt RC (1969) Estimation of the surface free energy of polymers. J Appl Polym Sci 13:1741–1747CrossRef
Pan LN, Dong HR, Bi PY (2009) Chemical preparation of aluminum superhydrophobic surface with nano-micro mixed structure by SDBS/HCl etching method. J Chin Univ-Chin 30:1371–1374
Pardini OR, Amalvy JI (2008) FTIR, 1H-NMR spectra, and thermal characterization of water-based polyurethane/acrylic hybrids. J Appl Polym Sci 107:1207–1214CrossRef
Peruzzo PJ, Anbinder PS, Pardini OR, Costa CA, Leite CA, Galembeck F, Amalvy JI (2010) Polyurethane/acrylate hybrids: effects of the acrylic content and thermal treatment on the polymer properties. J Appl Polym Sci 116:2694–2705
Pompe G, Häußler L, Adam G, Eichhorn K-J, Janke A, Hupfer B, Lehmann D (2005) Reactive polytetrafluoroethylene/polyamide 6 compounds. II. Study of the reactivity with respect to the functionality of the polytetrafluoroethylene component and analysis of the notched impact strength of the polytetrafluoroethylene/polyamide 6 compounds. J Appl Polym Sci 98:1317–1324CrossRef
Righetti MC, Boggioni A, Laus M, Antonioli D, Sparnacci K, Boarino L (2013a) Thermal and mechanical properties of PES/PTFE composites and nano composites. J Appl Polym Sci 55:3624–3633CrossRef
Righetti MC, Boggioni A, Laus M, Antonioli D, Sparnacci K, Enrico E, Boarino L (2013b) ageing reduction in PES through the incorporation of rigid non-interacting PTFE nano particles. Thermochim Acta 571:53–59CrossRef
Sparnacci K, Antonioli D, Deregibus S, Laus M, Poggio T, Kapeliouchko V, Palamone G (2009) PTFE-based core-soft shell nanospheres and soft matrix nanocomposites. Macromolecules 42:3518–3524CrossRef
Yamauchi G, Riko Y, Yasuno Y, Shimizu T, Funakoshi N (2005) Water-repellent coating for mobile phone microphones. Surf Coat Int B 88:281–283CrossRef
Yiang CY, Krimm S (1956) Infrared spectra of high polymers. III. Polytetrafluoroethylene and polychlorotrifluoroethylene. J Chem Phys 25:563–571
Zheng ZR, Gu ZY, Huo RT, Ye YH (2009) Superhydrophobicity of polyvinylidene fluoride membrane fabricated by chemical vapor deposition from solution. Appl Surf Sci 255:7263–7267
Zhu MF, Zuo WW, Yu H, Yang W, Chen YM (2006) Superhydrophobic surface directly created by electrospinning based on hydrophilic material. J Mater Sci 41:3793–3797CrossRef
Metadata
Title
Surface, thermal, and mechanical properties of composites and nanocomposites of polyurethane/PTFE nanoparticles
Authors
P. S. Anbinder
P. J. Peruzzo
A. de Siervo
J. I. Amalvy
Publication date
01-08-2014
Publisher
Springer Netherlands
Published in
Journal of Nanoparticle Research / Issue 8/2014
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-014-2529-5

Other articles of this Issue 8/2014

Journal of Nanoparticle Research 8/2014 Go to the issue

Research Paper

Biofunctionalization of silica-coated magnetic particles mediated by a peptide

Research Paper

Synthesis of silver-titanium dioxide nanocomposites for antimicrobial applications

Research Paper

The preparation of nickel nanoparticles through a novel solid-state intramolecular reaction of polynuclear nickel(II) complex

Review

Overview of nano-drugs characteristics for clinical application: the journey from the entry to the exit point

Research Paper

Magnetic nanoparticles supported imidazolium-based ionic liquids as nanocatalyst in microwave-mediated solvent-free Biginelli reaction

Research Paper

Organometallic deposition of ultrasmooth nanoscale Ni film

Premium Partners

    Image Credits