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Journal of Polymer Research
Published in: Journal of Polymer Research 3/2020

01-03-2020 | ORIGINAL PAPER

Synthesis and characterization of a novel Schiff base polyamide ligand and its copper(II) complex for comparative removal of Pb(II) ions from aqueous solutions

Authors: Marjan Aghaei, Ali Hossein Kianfar, Mohammad Dinari

Published in: Journal of Polymer Research | Issue 3/2020

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Abstract

A dicarboxylic acid Schiff base ligand was synthesized via condensation of 2-hydroxybenzaldehyde with 5-aminoisophthalic acid. The derived monomer was reacted with 4,4′-diaminodiphenyl ether and triphenyl phosphite (TPP) in tetrabutylammonium bromide (TBAB) molten ionic liquid as a green solvent to form an aromatic polyamide with a moderate yield (71%) and inherent viscosity (0.2 dL g−1). The nanostructured copper(II)/polyamide complex was then prepared. The structure, optical properties, and morphology of the compositions were confirmed by FT-IR, −1H-NMR, elemental analysis, UV-Vis, powder X-ray diffraction (XRD), thermogravimetric analysis (TGA) and field emission scanning electron microscopy (FE-SEM). The polyamide ligand and its nanostructured complex were comparatively applied in the elimination of Pb(II) ions from aqueous solutions.
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Appendix
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Metadata
Title
Synthesis and characterization of a novel Schiff base polyamide ligand and its copper(II) complex for comparative removal of Pb(II) ions from aqueous solutions
Authors
Marjan Aghaei
Ali Hossein Kianfar
Mohammad Dinari
Publication date
01-03-2020
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 3/2020
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-020-2007-y

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