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Published in: Journal of Nanoparticle Research 5/2008

01-05-2008 | Research Paper

Synthesis and characterization of bamboo-like CdS/TiO2 nanotubes composites with enhanced visible-light photocatalytic activity

Authors: Juhong Zhu, Dong Yang, Jiaqing Geng, Daimei Chen, Zhongyi Jiang

Published in: Journal of Nanoparticle Research | Issue 5/2008

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Abstract

In order to efficiently use the visible light in the photocatalytic reaction, a novel bamboo-like CdS/TiO2 nanotubes composite was prepared by a facile chemical reduction method, in which CdS nanoparticles located in the TiO2 nanotubes. The composition and structure of this nanocomposite were characterized by TEM, HRTEM, XRD, XPS, FTIR and UV-vis spectroscopy. This CdS/TiO2 nanotubes composite exhibited much higher visible-light photocatalytic activity for the degradation of methylene blue than pure TiO2 nanotubes and CdS nanoparticles, and the highest photodegradation efficiency after 6 h irradiation can reach 84.5%. It is inferred that the unique structure of CdS/TiO2 nanotubes composites acts an important role for the improvement of their photocatalytic activity.

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Literature
go back to reference Bessekhouad Y, Chaoui N, Trzpit M, Ghazzal N, Robert D, Weber JV (2006) UV–vis versus visible degradation of Acid Orange II in a coupled CdS/TiO2 semiconductors suspension. J Photochem Photobiol A: Chem 183:218–224CrossRef Bessekhouad Y, Chaoui N, Trzpit M, Ghazzal N, Robert D, Weber JV (2006) UV–vis versus visible degradation of Acid Orange II in a coupled CdS/TiO2 semiconductors suspension. J Photochem Photobiol A: Chem 183:218–224CrossRef
go back to reference Bessekhouad Y, Robert D, Weber JV (2004) Bi2S3/TiO2 and CdS/TiO2 heterojunctions as an available configuration for photocatalytic degradation of organic pollutant J Photochem Photobiol A: Chem 163:569–580CrossRef Bessekhouad Y, Robert D, Weber JV (2004) Bi2S3/TiO2 and CdS/TiO2 heterojunctions as an available configuration for photocatalytic degradation of organic pollutant J Photochem Photobiol A: Chem 163:569–580CrossRef
go back to reference Cao J, Sun JZ, Li HY, Hong J, Wang M (2004) A facile room-temperature chemical reduction method to TiO2@CdS core/sheath heterostructure nanowires. J Mater Chem 14:1203–1206CrossRef Cao J, Sun JZ, Li HY, Hong J, Wang M (2004) A facile room-temperature chemical reduction method to TiO2@CdS core/sheath heterostructure nanowires. J Mater Chem 14:1203–1206CrossRef
go back to reference Chen CC, Li XZ, Ma WH, Zhao JC, Hidaka H, Serpone N (2002) Effect of transition metal ions on the TiO2-assisted photodegradation of dyes under visible irradiation: a probe for the interfacial electron transfer process and reaction mechanism. J Phys Chem B 106:318–324CrossRef Chen CC, Li XZ, Ma WH, Zhao JC, Hidaka H, Serpone N (2002) Effect of transition metal ions on the TiO2-assisted photodegradation of dyes under visible irradiation: a probe for the interfacial electron transfer process and reaction mechanism. J Phys Chem B 106:318–324CrossRef
go back to reference Chen D, Yang D, Wang Q, Jiang Z (2006) Effects of boron doping on photocatalytic activity and microstructure of titanium dioxide nanoparticles. Ind Eng Chem Res 45:4110–4116 CrossRef Chen D, Yang D, Wang Q, Jiang Z (2006) Effects of boron doping on photocatalytic activity and microstructure of titanium dioxide nanoparticles. Ind Eng Chem Res 45:4110–4116 CrossRef
go back to reference Chen D, Jiang Z, Geng J, Wang Q, Yang D (2007) Carbon and nitrogen co-doped TiO2 with enhanced visible-light photocatalytic activity. Ind Eng Chem Res 46:2741–2746CrossRef Chen D, Jiang Z, Geng J, Wang Q, Yang D (2007) Carbon and nitrogen co-doped TiO2 with enhanced visible-light photocatalytic activity. Ind Eng Chem Res 46:2741–2746CrossRef
go back to reference Chen SG, Paulose M, Ruan C, Mor GK, Varghese OK, Kouzoudis D, Grimes CA (2006) Electrochemically synthesized CdS nanoparticle-modified TiO2 nanotube-array photoelectrodes: preparation, characterization, and application to photoelectrochemical cells. J Photochem Photobiol A: Chem 177:177–184CrossRef Chen SG, Paulose M, Ruan C, Mor GK, Varghese OK, Kouzoudis D, Grimes CA (2006) Electrochemically synthesized CdS nanoparticle-modified TiO2 nanotube-array photoelectrodes: preparation, characterization, and application to photoelectrochemical cells. J Photochem Photobiol A: Chem 177:177–184CrossRef
go back to reference Fujii H, Ohtaki M, Eguchi K, Arai H (1998) Preparation and photocatalytic activities of a semiconductor composite of CdS embedded in a TiO2 gel as a stable oxide semiconducting matrix. J Mol Catal A: Chem 129:61–68CrossRef Fujii H, Ohtaki M, Eguchi K, Arai H (1998) Preparation and photocatalytic activities of a semiconductor composite of CdS embedded in a TiO2 gel as a stable oxide semiconducting matrix. J Mol Catal A: Chem 129:61–68CrossRef
go back to reference Fujishima A, Rao TN, Tryk DA (2000) Titanium dioxide photocatalysis. J Photochem Photobiol C: Photochem Rev 1:1–21CrossRef Fujishima A, Rao TN, Tryk DA (2000) Titanium dioxide photocatalysis. J Photochem Photobiol C: Photochem Rev 1:1–21CrossRef
go back to reference Guo YG, Hu JS, Liang HP, Wan LJ, Bai CL (2005) TiO2-based composite nanotube arrays prepared via layer-by-layer assembly. Adv Funct Mater 15:196–202CrossRef Guo YG, Hu JS, Liang HP, Wan LJ, Bai CL (2005) TiO2-based composite nanotube arrays prepared via layer-by-layer assembly. Adv Funct Mater 15:196–202CrossRef
go back to reference Hirai T, Suzuki K, Komasawa I (2001) Preparation and photocatalytic properties of composite CdS nanoparticles–titanium dioxide particles. J Colloid Interface Sci 244:262–265CrossRef Hirai T, Suzuki K, Komasawa I (2001) Preparation and photocatalytic properties of composite CdS nanoparticles–titanium dioxide particles. J Colloid Interface Sci 244:262–265CrossRef
go back to reference Hodos M, Horváth E, Haspel H, Kukovecz Á, Kónya Z, Kiricsi I (2004) Photo sensitization of ion-exchangeable titanate nanotubes by CdS nanoparticles. Chem Phys Lett 399:512–515CrossRef Hodos M, Horváth E, Haspel H, Kukovecz Á, Kónya Z, Kiricsi I (2004) Photo sensitization of ion-exchangeable titanate nanotubes by CdS nanoparticles. Chem Phys Lett 399:512–515CrossRef
go back to reference Hsu MC, Leu IC, Sun YM, Hon MH (2005) Fabrication of CdS@TiO2 coaxial composite nanocables arrays by liquid-phase deposition. J Cryst Growth 285:642–648CrossRef Hsu MC, Leu IC, Sun YM, Hon MH (2005) Fabrication of CdS@TiO2 coaxial composite nanocables arrays by liquid-phase deposition. J Cryst Growth 285:642–648CrossRef
go back to reference Kasuga T, Hiramatsu M, Hoson A, Sekino T, Niihara K (1999) Titania nanotubes prepared by chemical processing. Adv Mater 11:1307–1311CrossRef Kasuga T, Hiramatsu M, Hoson A, Sekino T, Niihara K (1999) Titania nanotubes prepared by chemical processing. Adv Mater 11:1307–1311CrossRef
go back to reference Kim JC, Choi J, Lee YB, Hong JH, Lee JI, Yang JW, Lee WI, Hur NH (2006) Enhanced photocatalytic activity in composites of TiO2 nanotubes and CdS nanoparticles. Chem Commun 16:5024–5026CrossRef Kim JC, Choi J, Lee YB, Hong JH, Lee JI, Yang JW, Lee WI, Hur NH (2006) Enhanced photocatalytic activity in composites of TiO2 nanotubes and CdS nanoparticles. Chem Commun 16:5024–5026CrossRef
go back to reference Kukovecz Á, Hodos M, Kónya Z, Kiricsi I (2005) Complex-assisted one-step synthesis of ion-exchangeable titanate nanotubes decorated with CdS nanoparticles. Chem Phys Lett 411:445–449CrossRef Kukovecz Á, Hodos M, Kónya Z, Kiricsi I (2005) Complex-assisted one-step synthesis of ion-exchangeable titanate nanotubes decorated with CdS nanoparticles. Chem Phys Lett 411:445–449CrossRef
go back to reference Kumar A, Jain AK (2001) Photophysics and photochemistry of colloidal CdS–TiO2 coupled semiconductors—photocatalytic oxidation of indole. J Mol Catal A: Chem 165:265–273CrossRef Kumar A, Jain AK (2001) Photophysics and photochemistry of colloidal CdS–TiO2 coupled semiconductors—photocatalytic oxidation of indole. J Mol Catal A: Chem 165:265–273CrossRef
go back to reference Larramona G, Choné C, Jacob A, Sakakura D, Delatouche B, Péré D, Cieren X, Nagino M, Bayón R (2006) Nanostructured photovoltaic cell of the type titanium dioxide, cadmium sulfide thin coating, and copper thiocyanate showing high quantum efficiency. Chem Mater 18:1688–1696CrossRef Larramona G, Choné C, Jacob A, Sakakura D, Delatouche B, Péré D, Cieren X, Nagino M, Bayón R (2006) Nanostructured photovoltaic cell of the type titanium dioxide, cadmium sulfide thin coating, and copper thiocyanate showing high quantum efficiency. Chem Mater 18:1688–1696CrossRef
go back to reference Linsebigler AL, Lu G, Yates JT Jr. (1995) Photocatalysis on TiO2 surfaces: principles, mechanisms, and selected results. Chem Rev 95:735–758CrossRef Linsebigler AL, Lu G, Yates JT Jr. (1995) Photocatalysis on TiO2 surfaces: principles, mechanisms, and selected results. Chem Rev 95:735–758CrossRef
go back to reference Peter LM, Riley DJ, Tull EJ, Wijayantha KGU (2002) Photosensitization of nanocrystalline TiO2 by self-assembled layers of CdS quantum dots. Chem Commun 12:1030–1031CrossRef Peter LM, Riley DJ, Tull EJ, Wijayantha KGU (2002) Photosensitization of nanocrystalline TiO2 by self-assembled layers of CdS quantum dots. Chem Commun 12:1030–1031CrossRef
go back to reference Sun X, Li Y (2003) Synthesis and characterization of ion-exchangeable titanate nanotubes. Chem Eur J 9:2229–2238CrossRef Sun X, Li Y (2003) Synthesis and characterization of ion-exchangeable titanate nanotubes. Chem Eur J 9:2229–2238CrossRef
go back to reference Takahashi M, Natori H, Tajima K, Kobayashi K (2005) Particulate assemblies of CdS and TiO2 prepared by Langmuir–Blodgett technique with octadecylamine/methylstearate mixed films. Thin Solid Films 489:205–214CrossRef Takahashi M, Natori H, Tajima K, Kobayashi K (2005) Particulate assemblies of CdS and TiO2 prepared by Langmuir–Blodgett technique with octadecylamine/methylstearate mixed films. Thin Solid Films 489:205–214CrossRef
go back to reference Thompson TL, Yates JT Jr. (2006) Surface science studies of the photoactivation of TiO2-new photochemical processes. Chem Rev 106:4428–4453CrossRef Thompson TL, Yates JT Jr. (2006) Surface science studies of the photoactivation of TiO2-new photochemical processes. Chem Rev 106:4428–4453CrossRef
go back to reference Wang WD, Serp P, Kalck P, Faria JL (2005) Photocatalytic degradation of phenol on MWNT and titania composite catalysts prepared by a modified sol–gel method. Appl Catal B: Environ 56:305–312CrossRef Wang WD, Serp P, Kalck P, Faria JL (2005) Photocatalytic degradation of phenol on MWNT and titania composite catalysts prepared by a modified sol–gel method. Appl Catal B: Environ 56:305–312CrossRef
go back to reference Yin H, Wada Y, Kitamura T, Sakata T, Mori H, Yanagida S (2001) Enhanced photocatalytic dechlorination of 1,2,3,4-tetrachlorobenzene using nanosized CdS/TiO2 hybrid photocatalyst under visible light irradiation. Chem Lett 30:334–335 CrossRef Yin H, Wada Y, Kitamura T, Sakata T, Mori H, Yanagida S (2001) Enhanced photocatalytic dechlorination of 1,2,3,4-tetrachlorobenzene using nanosized CdS/TiO2 hybrid photocatalyst under visible light irradiation. Chem Lett 30:334–335 CrossRef
go back to reference Yu JC, Yu JG, Tang HY, Zhang LZ (2002a) Effect of surface microstructure on the photoinduced hydrophilicity of porous TiO2 thin films. J Mater Chem 12:81–85CrossRef Yu JC, Yu JG, Tang HY, Zhang LZ (2002a) Effect of surface microstructure on the photoinduced hydrophilicity of porous TiO2 thin films. J Mater Chem 12:81–85CrossRef
go back to reference Yu JC, Zhang LZ, Yu JG (2002b) Direct sonochemical preparation and characterization of highly active mesoporous TiO2 with a bicrystalline framework. Chem Mater 14:4647–4653 CrossRef Yu JC, Zhang LZ, Yu JG (2002b) Direct sonochemical preparation and characterization of highly active mesoporous TiO2 with a bicrystalline framework. Chem Mater 14:4647–4653 CrossRef
go back to reference Yu JC, Wu L, Lin J, Li P, Li Q (2003) Microemulsion-mediated solvothermal synthesis of nanosized CdS-sensitized TiO2 crystalline photocatalyst. Chem Commun 13:1552–1553CrossRef Yu JC, Wu L, Lin J, Li P, Li Q (2003) Microemulsion-mediated solvothermal synthesis of nanosized CdS-sensitized TiO2 crystalline photocatalyst. Chem Commun 13:1552–1553CrossRef
Metadata
Title
Synthesis and characterization of bamboo-like CdS/TiO2 nanotubes composites with enhanced visible-light photocatalytic activity
Authors
Juhong Zhu
Dong Yang
Jiaqing Geng
Daimei Chen
Zhongyi Jiang
Publication date
01-05-2008
Publisher
Springer Netherlands
Published in
Journal of Nanoparticle Research / Issue 5/2008
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-007-9301-z

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