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Journal of Nanoparticle Research

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01-03-2012 | Research Paper

Synthesis and photophysical properties of polyamides containing in-chain porphyrin and [60]fullerene

Authors: Haiying Zhao, Chen Chen, Yizhou Zhu, Mingzhu Shi, Jianyu Zheng

Published in: Journal of Nanoparticle Research | Issue 3/2012

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Abstract

Conjugated polyamides containing porphyrin and [60]fullerene (C₆₀) in the main chain were prepared by a direct polycondensation of the 3′H,3″H-dicyclopropa[1, 9:16, 17] [5, 6]fullerene-C₆₀-I _h-3′,3″-dicarboxylic acid and 5,15-bis(4-aminophenyl)-10,20-bis(3,5-dialkoxyphenyl)porphyrin in the presence of triphenyl phosphite and pyridine. Gel permeation chromatography (GPC) analysis of the polyamides showed the weight-average molecular weight was about 23,626–23,736, and the temperature at 5% weight loss determined by thermogravimetric analysis (TGA) was above 216 °C. The transmission electron microscopy (TEM) images displayed the regular one-dimensional linear arrays of the polyamides with lengths exceeded 200 nm. The photoinduced electron transfer from porphyrin to C₆₀ in the polyamides was observed in nanosecond laser-flash photolysis experiments at ambient temperature, which produced a charge-separated state (porphyrin radical cation–C₆₀ radical anion pair) with a lifetime as long as 40 μs. The calculated ratio of k _CS/k _CR was found to be 2.1 × 10⁴. They could have potential applications for photoelectronic devices, organic solar cells and so on.

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Title: Synthesis and photophysical properties of polyamides containing in-chain porphyrin and [60]fullerene
Authors: Haiying Zhao
Chen Chen
Yizhou Zhu
Mingzhu Shi
Jianyu Zheng
Publication date: 01-03-2012
Publisher: Springer Netherlands
Published in: Journal of Nanoparticle Research / Issue 3/2012
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-012-0765-0

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