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Journal of Polymer Research

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01-01-2024 | Original Paper

Synthesis, characterization and hydrolytic degradation studies of aromatic polyphosphazenes derivatives

Authors: Tanzeela G. Shahzady, Hajira Rehman, Ahmad Shuaib, Zulfiqar Ali, Shazia Khurshid, Amir Mushtaq

Published in: Journal of Polymer Research | Issue 1/2024

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Abstract

In this study, the cyclic trimer of hexachlorocyclotriphosphazene (HCCP) was used as the starting material for the thermal ring opening polymerization (T-ROP) method, which was followed by a macromolecular substitution reaction to create three Polyphosphazene derivatives with aromatic side groups. FTIR, 1HNMR, 31PNMR, DSC, elemental analysis, and gel permeation chromatography were used to characterise the synthesised polymer (GPC). The hydrolytic breakdown using shaker bath was studied at various pH at 37 °C for 42 days. Significant degradation products were noticed at different pH values. Studies on degradation revealed that synthetic polymers offer a wide range of potential uses in the biological field.

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Title: Synthesis, characterization and hydrolytic degradation studies of aromatic polyphosphazenes derivatives
Authors: Tanzeela G. Shahzady
Hajira Rehman
Ahmad Shuaib
Zulfiqar Ali
Shazia Khurshid
Amir Mushtaq
Publication date: 01-01-2024
Publisher: Springer Netherlands
Published in: Journal of Polymer Research / Issue 1/2024
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-023-03841-0

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