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Journal of Polymer Research

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01-05-2021 | ORIGINAL PAPER

Synthesis, characterization and rheological properties of copolymer based on poly (para-isobutyl-N-Phenethyl acrylamide -Acrylamide) with drilling mud

Author: Firas Jameel Jabbar

Published in: Journal of Polymer Research | Issue 5/2021

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Abstract

This research focuses on the synthesis and characterization of a new form of hydrophobic modified polyacrylamide copolymer. The new copolymer is synthesized in the laboratory using an alternative polymerization process for acrylamide and para-isobutyl-N-phenylethyl acrylamide reactions. The prepared copolymer is characterized by Fourier transform infrared (FTIR) and proton nuclear magnetic resonance (HNMR) spectroscopy to identify those functional groups present in the copolymer (AM-PIAM). In addition, the mean molecular weight of the copolymer has been calculated. By way of a Gel permeation chromatography, it has been demonstrated that the copolymer has a molecular weight of 3.2 × 105 Da. In this analysis, the impact of adding copolymer on the rheological properties of drilling mud is observed and it is noticed that there is a significant increase in the apparent viscosity (AV)), plastic viscosity (PV), Yield point (YP) and Gel strength (GS) values, while the filtration properties of drilling mud decreased. The effect of the incorporation of sodium and calcium salts on the rheological and filtration properties of drilling mud has also been observed and it has been found that there is a substantial decrease in apparent viscosity values and a comparatively high increase in filtration values. On the other hand, it is observed that the PH feature had an opposite effect on the rheological and filtration properties relative to the effects of sodium and calcium salts.

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Stahl GA, Schulz DN (2012) Water-soluble polymers for petroleum recovery. Springer Science & Business Media

Lai N, Dong W, Ye Z, Dong J, Qin X, Chen W, Chen K (2013) A water-soluble acrylamide hydrophobically associating polymer: synthesis, characterization, and properties as EOR chemical. J Appl Polym Sci 129(4):1888–1896CrossRef

Bai Y, Xiong C, Wei F, Li J, Shu Y, Liu D (2015) Gelation study on a hydrophobically associating polymer/polyethylenimine gel system for water shut-off treatment. Energy Fuels 29(2):447–458CrossRef

Yap RK, Whittaker M, Diao M, Stuetz RM, Jefferson B, Bulmus V, Henderson, RK (2014) Hydrophobically-associating cationic polymers as micro-bubble surface modifiers in dissolved air flotation for cyanobacteria cell separation. Water Res 61:253–262

Wang C, Li X, Li P (2012) Study on preparation and solution properties of hydrophobically associating polyacrylamide by emulsifier-free ultrasonic assisted radical polymerization. J Polym Res 19(8):1–7

Cram SL, Brown HR, Spinks GM, Hourdet D, Creton C (2005) Hydrophobically modified dimethylacrylamide synthesis and rheological behavior. Macromolecules 38(7):2981–2989CrossRef

Chen H, Li EX, Ye ZB, Han LJ, Luo PY (2011) Interaction of hydrophobically associating polyacrylamide with gemini surfactant. Acta Phys Chim Sin 27(3):671–676CrossRef

Yahaya GO, Ahdab AA, Ali SA, Abu-Sharkh BF, Hamad EZ (2001) Solution behavior of hydrophobically associating water-soluble block copolymers of acrylamide and N-benzylacrylamide. Polymer 42(8):3363–3372CrossRef

MacWilliams DC, Rogers JH, West TJ (1973) Water-soluble polymers in petroleum recovery. In: Bikales NM (Ed) Water-soluble Polymers, Polymer Science and Technology, vol. 2. Plenum Press, New York, pp. 105–225

10.

Littman W (1988) Polymer Flooding: Developments in Petroleum Science, No. 24. Elsevier, Amsterdam

11.

Sorbie KS (1991) Polymer-Improved Oil Recovery. CRC Press, Boca Raton, FloridaCrossRef

12.

Yen WS, Coscia AT, Kohen SI (1989) Polyacrylamides. In: Donaldson EC, Chilingarian GV, Yen TF (Eds) Enhanced Oil Recovery, II: Processes and Operations ŽDevelopments in Petroleum Science, 17B.. Elsevier Science Publishers, pp. 189–218

13.

Nasr-El-Din HA, Hawkins BF, Green KA (1991) Viscosity behavior of alkaline, surfactant, polyacrylamide solutions used for enhanced oil recovery. SPE 21028, Proc Int Symp Oilfield Chem, Anaheim, CA, USA

14.

Zaitoun A, Potie B (1983) Limiting conditions for the use of hydrolyzed polyacrylamides in brines containing divalent ions. SPE 11785, Int Symp Oilfield Geothermal Chem, Denver, CO, USA

15.

Hwang FS, Hogen-Esch TE (1995) Effects of water-soluble spacers on the hydrophobic association of fluorocarbon-modified poly (acrylamide). Macromolecules 28(9):3328–3335CrossRef

16.

Li M, Jiang M, Zhang YX, Fang Q (1997) Fluorescence studies of hydrophobic association of fluorocarbon-modified poly (N-isopropylacrylamide). Macromolecules 30(3):470–478CrossRef

17.

Feng Y, Billon L, Grassl B, Bastiat G, Borisov O, François J (2005) Hydrophobically associating polyacrylamides and their partially hydrolyzed derivatives prepared by post-modification. 2. Properties of non-hydrolyzed polymers in pure water and brine. Polymer 46(22):9283–9295

18.

Darley HC, Gray GR (1988) Composition and properties of drilling and completion fluids. Gulf Professional Publishing

19.

Abdou MI, Al-Sabagh AM, Dardir MM (2013) Evaluation of Egyptian bentonite and nano-bentonite as drilling mud. Egypt J Pet 22(1):53–59CrossRef

20.

Vipulanandan C, Mohammed A (2015) Effect of nanoclay on the electrical resistivity and rheological properties of smart and sensing bentonite drilling muds. J Petrol Sci Eng 130:86–95CrossRef

21.

Bergaya F, Lagaly G (2013) Handbook of clay science. Newnes

22.

Vipulanandan C, Mohammed AS (2014) Hyperbolic rheological model with shear stress limit for acrylamide polymer modified bentonite drilling muds. J Petrol Sci Eng 122:38–47CrossRef

23.

Vipulanandan C, Mohammed A (2016) Nanoclay Modified Drilling Muds for HPHT Applications (p. 11). AADE-16-FTCE-85

24.

VERSAN KOK, M. U. S. T. A. F. A. (2004) Rheological and thermal analysis of bentonites for water base drilling fluids. Energy Sources 26(2):145–151CrossRef

25.

Kok MV (2009) Statistical approach of two-three parameters rheological models for polymer type drilling fluid analysis. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects 32(4):336–345CrossRef

26.

Kok MV (2013) Thermal analysis and rheological study of ocma type bentonite used in drilling fluids. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects 35(2):122–133CrossRef

27.

Caenn R, Chillingar GV (1996) Drilling fluids: State of the art. J Petrol Sci Eng 14(3–4):221–230CrossRef

28.

McCormick CL, Branham KD, Davis DL, Middleton JC (1993) A new generation of electrolyte and pH responsive water-soluble polymers for mobility control. Prep Am Chem Soc Div Pet Chem 38(1):146–149

29.

Uhl JT, Ching TY, Bae JH (1993) A laboratory study of new, surfactant-containing polymers for high-salinity reservoirs. SPE 26400, Proc 68th Ann Tech Conf and Exhib Of Soc Pet Eng, Houston, TX, USA

30.

Ma J, Zheng H, Tan M, Liu L, Chen W, Guan Q, Zheng X (2013) Synthesis, characterization, and flocculation performance of anionic polyacrylamide P (AM-AA-AMPS). J Appl Polym Sci 129(4):1984–1991CrossRef

31.

Hietala S, Mononen P, Strandman S, Järvi P, Torkkeli M, Jankova K, Tenhu H (2007) Synthesis and rheological properties of an associative star polymer in aqueous solutions. Polymer 48(14):4087–4096

32.

Bhut PR, Pal N, Mandal A (2019) Characterization of hydrophobically modified polyacrylamide in mixed polymer-gemini surfactant systems for enhanced oil recovery application. ACS Omega 4(23):20164–20177CrossRef

33.

Li MC, Wu Q, Song K, French AD, Mei C, Lei T (2018) pH-responsive water-based drilling fluids containing bentonite and chitin nanocrystals. ACS Sustainable Chemistry & Engineering 6(3):3783–3795CrossRef

34.

Landoll LM (1982) Nonionic polymer surfactants. J Polym Sci Polym Chem Ed 20:443–455CrossRef

35.

McCormick CL, Bock J, Schulz DN (1989) Water-soluble polymers. Encyclopedia of Polymer Science and Engineering, vol 17, 2nd edn. John Wiley and Sons, New York, pp 730–784

36.

Landoll LM (1985) Hydrophobically Modified Polymers. U.S. Pat 4(529):523

37.

Sau AC, Landoll LM (1989) Synthesis and solution properties of hydrophobically modified Žhydroxyethyl. cellulose. In: Glass JE (Ed) Polymers in Aqueous Media: Performance through Association. Advances in Chemistry Series No. 223, Am Chem Soc, Washington, DC, pp. 343–364

38.

Evani S (1984) Water-dispersible Hydrophobic Thickening Agent. U.S. Pat 4(432):881

39.

van Phung K, Evani S (1988) Amphiphilic Monomer and Hydrophobe Associative Composition containing a Polymer of a Water-soluble Monomer and said Amphiphilic Monomer. U.S. Pat. 4(728):696

40.

Goodwin JW, Hughes RW, Lam CK, Miles JA, Warren BCH (1989) The rheological properties of a hydrophobically modified cellulose. In: Glass JE (Ed) Polymers in Aqueous Media: Performance through Association. Advances in Chemistry Series No. 223, Am Chem Soc, Washington, DC, pp. 365–37

41.

Dersch R (1994) Associative thickeners past present and future. Surf Coat Aust 31(5):18–22

42.

Guan T, Du Z, Chang X, Zhao D, Yang S, Sun N, Ren B (2019) A reactive hydrophobically modified ethoxylated urethane (HEUR) associative polymer bearing benzophenone terminal groups: Synthesis, thickening and photo-initiating reactivity. Polymer 178:121552CrossRef

43.

Weber JB (1970) Adsorption of s-triazines by montmorillonite as a function of pH and molecular structure. Soil Science Society of America Proceedings 34:401–404CrossRef

44.

Rogers WF (1963) Composition and properties of oil well drilling fluids., 3rd ed Gulf Publishing Company: Houston, Texas

45.

Goud M (2017) Mud Engineering Simplified, BecomeShakespeare.com, ISBN: 9789386487674. [https://books.google.com/books?id=9P5CDwAAQBAJ]

46.

Elkatatny S (2019) Assessing the Effect of Micronized Starch on Rheological and Filtration Properties of Water-Based Drilling Fluid. In Proceedings of the SPE Middle East Oil and Gas Show and Conference, Manama, Bahrain,18–21

47.

Amani M, Hassiba KJ (2012) Salinity Effect on the Rheological Properties of Water Based Mud under High Pressures and High Temperatures of Deep Wells. In Proceedings of the SPE Kuwait International Petroleum conference and Exhibition, Kuwait City, Kuwait, 10–12

48.

Amirian E, Dejam M, Chen Z (2018) Performance forecasting for polymer flooding in heavy oil reservoirs. Fuel 216:83–100CrossRef

49.

Beck FE, Powell JW, Zamora M (1995) The Effect of Rheology on Rate of Penetration. In Proceedings of the SPE/IADC Drilling Conference, Amsterdam, The Netherlands

50.

Rabaioli MR, Miano F, Lockhart TP, Burrafato G (1993) Physical/Chemical Studies on the Surface Interactions of Bentonite with Polymeric Dispersing Agents. Society of Petroleum Engineers. In Proceedings of the SPE International Symposium on Oilfield Chemistry, New Orleans, LA, USA

51.

Zamora M, Power D (2002) Making a Case for AADE Hydraulics and the Unified Rheological Model; Paper AADE-02-DFWM-HO-13. In Proceedings of the AADE 2002 Technology Conference “Drilling & Completion Fluids and Waste Management”, Radisson Astrodome, Houston, TX, USA, 2–3

Title: Synthesis, characterization and rheological properties of copolymer based on poly (para-isobutyl-N-Phenethyl acrylamide -Acrylamide) with drilling mud
Author: Firas Jameel Jabbar
Publication date: 01-05-2021
Publisher: Springer Netherlands
Published in: Journal of Polymer Research / Issue 5/2021
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-021-02531-z

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