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17-02-2020 | Original Paper

Synthesis of 10 and 12 Ring Zeolites (MCM-22, TNU-9 and MCM-68) Modified with Zn and Its Potential Application in the Reaction of Methanol to Light Aromatics and Olefins

Published in: Topics in Catalysis | Issue 5-6/2020

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Abstract

The effect on the incorporation of zinc of three zeolites TNU-9, MCM-22, and MCM-68 was investigated. The physico-chemical properties of zeolites were studied by X‐ray diffraction, N₂-adsorption, temperature‐programmed desorption of NH₃ (TPD), nuclear magnetic resonance of ²⁷Al and ²⁹Si (MAS NMR), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). Then all the samples were characterized and evaluated in the reaction of methanol to aromatics (MTA). The correlation of zinc incorporation method and acidic properties of zeolites with catalytic performance was investigated. The form of zinc incorporation, the acidity, the type of zeolitic structure and the reaction temperature had a great influence on the catalytic activity. Regarding the type of structure, the total aromatics selectivity in this work increased in the followed order for zeolites modified with Zn: MCM-68 > TNU-15 > MCM-22. The medium pore zeolite T9-15 (TNU-9 zeolite and Si/Al 15 ratio) catalysts with the ratio ZnO/ZnO + Al₂O₃ equal to 0.34 (T9-15 0.5 Zn) showed better stability with conversion of methanol completes during 9 h of reaction and 17% to BTX selectivity and 32% to total aromatics compounds at 450 °C and WHSV of 4.24 h⁻¹. In methanol conversion, the selectivity to aromatics over the T9-15 modified-Zn materials (TNU-9 zeolite and Si/Al 15 ratio) under study, increased in the followed order: T9-15 0.5 Zn > ZT9-15 > T9-15 > T9-15 0.2 Zn. The reaction temperature is an important variable in the MTA process. At 450 °C a better activation of acid sites is achieved in zeolite with Zn and therefore a high percentage of BTX selectivity is obtained for TNU-9 zeolite.

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Zhu X (2015) Hierarchical zeolites as catalysts for methanol conversion reactions. Technische Universiteit Eindhoven, Eindhoven

Blomsma E, Martens JA, Jacobs PA (1997) Isomerization and hydrocracking of heptane over bimetallic bifunctional PtPd/H-beta and PtPd/USY zeolite catalysts. J Catal 165(2):241–248

Fraenkel D, Cherniavsky M, Ittah B, Levy M (1986) Shape-selective alkylation of naphthalene and methylnaphthalene with methanol over H-ZSM-5 zeolite catalysts. J Catal 101(2):273–283

Zhang GQ, Bai T, Chen TF, Fan WT, Zhang X (2014) Conversion of methanol to light aromatics on Zn-modified nano-HZSM-5 zeolite catalysts. Ind Eng Chem Res 53:14932–14940

Zhang J, Qian W, Kong C, Wei F (2015) Increasing para-Xylene Selectivity in Making Aromatics from Methanol with a surface-modified Zn/P/ZSM-5 catalyst. ACS Catal 5(5):2982–2988

Wang T, Tang X, Huang X, Qian W, Cui Y, Hui X, Yang W, Wei F (2014) Conversion of methanol to aromatics in fluidized bed reactor. Catal Today 233:8–13

Baliban RC, Elia JA, Floudas CA (2013) Biomass to liquid transportation fuels (BTL) systems: process synthesis and global optimization framework. Energy Environ Sci 6:267–287

Appelt J, Heschel W, Meyer B (2016) Catalytic pyrolysis of central German lignite in a semi-continuous rotary kiln—performance of pulverized one-way ZSM-5 catalyst and ZSM-5-coated beads. Fuel Process Technol 144:56–63

Bjørgen M, Joensen F, Holm MS, Olsbye U, Lillerud KP, Svelle S (2008) Methanol to gasoline over zeolite H-ZSM-5: improved catalyst performance by treatment with NaOH. Appl Catal A 345:43–50

10.

Garcia-Ruiz M, Solis-Casados DA, Aguilar-Pliego J, Márquez-Álvarez C, Sastre de Andrés E, Sanjurjo-Tartalo D, Sainz-Vaque R, Grande-Casas M (2020) ZSM-5 zeolites modified with Zn and their effect on the crystal size in the conversion of methanol to light aromatics (MTA). React Kinet Mech Catal. https://doi.org/10.1007/s11144-019-01716-4CrossRef

11.

Yubing X, Puyu Q, Xinping D, Haiqiang L, Youzhu Y (2013) Enhanced performance of Zn–Sn/HZSM-5 catalyst for the conversion of methanol to aromatics. Catal Lett 143:798–806

12.

Gabrienko AA, Arzumanov SS, Toktarev AV, Danilova IG, Prosvirin IP, Kriventsov VV, Zaikovskii VI, Freude D, Stepanov AG (2017) Different efficiency of Zn²⁺ and ZnO species for methane activation on Zn-modified zeolite. ACS Catal 7(3):1–45

13.

Ma D, Shu Y, Han X, Liu X, Xu Y, Bao X (2001) Mo/HMCM-22 catalysts for methane dehydroaromatization: a multinuclear MAS NMR Study. J Phys Chem B 105:1786–1793

14.

Dorset DL, Weston SC, Dhingra SS (2006) Crystal structure of ZEOLITE MCM-68: a new three-dimensional framework with large pores. J Phys Chem B 110:2045–2050PubMed

15.

Ni Y, Sun A, Wu X, Hai G, Hu J, Li T, Li G (2011) The preparation of nano-sized H[Zn, Al]ZSM-5 zeolite and its application in the aromatization of methanol. Micropor Mesopor Mater 143:435–442

16.

Hong SB, Lear EG, Wright PA, Zhou W, Cox PA, Shin CH, Park JH, Nam IS (2004) Synthesis, structure solution, characterization, and catalytic properties of TNU-10: a high-silica zeolite with the STI topology. J Am Chem Soc 126:5817–5826PubMed

17.

Hong SB, Nam IS, Min HK, Shin CH, Warrender SJ, Wright PA, Cox PA, Gramm F, Baerlocher Ch, McCusker LB, Liu Z, Ohsuna T, Terasaki O (2007) TNU-9: a novel medium-pore zeolite with 24 topologically distinct tetrahedral sites. Zeolites to Porous MOF Materials—the 40th Anniversary of International Zeolite Conference

18.

Zhang L, Wang H, Liu G, Gao K, Wu J (2016) Methanol-to-olefin conversion over H-MCM-22 catalyst. J Mol Catal A 411:311–316

19.

Wu Y, Ren X, Lu Y, Wang J (2008) Crystallization and morphology of zeolite MCM-22 influenced by various conditions in the static hydrothermal synthesis. Micropor Mesopor Mater 112:138–146

20.

Hao H, Chang Y, Yu W, Lou LL, Liu S (2018) Hierarchical porous MCM-68 zeolites: synthesis, characterization and catalytic performance in m-xylene isomerization. Micropor Mesopor Mater 263:135–141

21.

Calabro JC, Cheng RA, Crane Jr, Kresge CT, Dhingra SS, Steckel MA, Stern DL. Weston SC (2000) U. S. Patent. 6049018

22.

Kubu M, Zones SI, Cejka J (2010) TUN, IMF and -SVR zeolites; synthesis. Prop Acid Top Catal 53:1330–1339

23.

Corma A, Corell C, Pérez-Pariente J (1995) Synthesis and characterization of the MCM-22 zeolite. Zeolites 15(1):2–8

24.

Delitala C, Alba MD, Becerro AI, Delpiano D, Meloni D, Musu E, Ferino I (2009) Synthesis of MCM-22 zeolites of different Si/Al ratio and their structural, morphological and textural characterization. Micropor Mesopor Mater 118:1–10

25.

Tian ZR, Voigt JA, Liu J, Mckenzie B, Mcdermott MJ, Rodriguez MA, Konishi H, Xu H (2003) Complex and oriented ZnO nanostructures. Nat Mater 2:821–826PubMed

26.

Li J, Lou LL, Yang Y, Hao H, Liu S (2015) Alkylation of phenol with tert-butyl alcohol over dealuminated HMCM-68 zeolites. Micropor Mesopor Mater 207:27–32

27.

Hu J, Wu S, Liu H, Ding H, Li Z, Guan J, Kan Q (2014) Effect of mesopore structure of TNU-9 on methane dehydroaromatization. RSC Adv 4:26577–26584

28.

Ji Y, Yang H, Yan W (2017) Strategies to enhance the catalytic performance of ZSM-5 zeolite in hydrocarbon cracking: a review. Catalysts 7(367):1–31

29.

Ernst S, Elangovan SP, Gerstner M, Hartmann M, Hecht T, Sauerbeck S (2004) Characterization and catalytic evaluation of zeolite MCM-68. Stud Surf Sci Catal 154:2861–2868

30.

Su X, Wang G, Bai X, Wu W, Xiao L, Fang Y, Zhang J (2016) Synthesis of nanosized HZSM-5 zeolites isomorphously substituted by gallium and their catalytic performance in the aromatization. Chem Eng 293:365–375

31.

Jung HJ, Park SS, Shin CH, Park YK, Hong SB (2007) Comparative catalytic studies on the conversion of 1-butene and n-butane to isobutene over MCM-22 and ITQ-2 zeolites. J Catal 245:65–74

32.

Topsøe N, Pedersen K, Derouane E (1981) Infrared and temperature-programmed desorption study of the acidic properties of ZSM-5-type zeolites. J Catal 70:41–52

33.

Wu P, Kan Q, Wang X, Wang D, Xing H, Yang P, Wu T (2005) Acidity and catalytic properties for methane conversion of Mo/HZSM-5 catalyst modified by reacting with organometallic complex. Appl Catal A 282:39–44

34.

Joly JF, Ajot H, Merlen E, Raatz F, Alario F (1991) Parameters affecting the dispersion of the gallium phase of gallium H-MFI aromatization catalysts. Appl Catal A 79:249–263

35.

Xiaoning W, Zhen Z, Chunming X, Aijun D, Li Z, Guiyuan J (2007) Effects of fight rare earth on acidity and catalytic performance of HZSM-5 zeolite for catalytic clacking of butane to light olefins. J Rare Earths 25:321–328

36.

Reddy JK, Motokura K, Koyama T, Miyaji A, Baba T (2012) Effect of morphology and particle size of ZSM-5 on catalytic performance for ethylene conversion and heptane cracking. J Catal 289:53–61

37.

Kolodziejski W, Zicovich-Wilson C, Corell C, Perez-Pariente J, Corma A (1995) ²⁷Al and ²⁹Si MAS NMR Study of Zeolite MCM-22. J Phys Chem 99(18):7002–7008

38.

Song YQ, Feng YL, Liu F, Kang CL, Zhou XL, Xu LY, Yu GX (2009) Effect of variations in pore structure and acidity of alkali treated ZSM-5 on the isomerization performance. J Mol Catal A 310:130–137

39.

Pinilla-Herrero I, Borfecchia E, Holzinger J, Mentz UV, Finn J, Lomachenko KA, Bordiga S, Lamberti C, Berlier G, Olsbye U, Svelle S, Skibsted J, Beato P (2018) High Zn/Al ratios enhance dehydrogenation vs hydrogen transfer reactions of Zn-ZSM-5 catalytic systems in methanol conversion to aromatics. J Catal 362:146–163

40.

Saito H, Inagaki S, Kojima K, Han Q, Yabe T, Ogo S, Kubota Y, Sekine Y (2018) Preferential dealumination of Zn/H-ZSM-5 and its high and stable activity for ethane dehydroaromatization. Appl Catal A 549:76–81

41.

Machado V, Rocha J, Carvalho AP, Martins A (2012) Modification of MCM-22 zeolite through sequential post-synthesis treatments. Implications on the acidic and catalytic behavior. Appl Catal A 445:329–338

42.

Elyassi B, Zhang X, Tsapatsis M (2014) Long-term steam stability of MWW structure zeolites (MCM-22 and ITQ-1). Micropor Mesopor Mater 193:134–144

43.

Wang P, Huang L, Li J, Dong M, Wang J, Tatsumi T, Fan W (2015) Catalytic properties and deactivation behavior of H-MCM-22 in the conversion of methanol to hydrocarbons. RSC Adv 5:1–28

44.

Bleken F, Skistad W, Barbera K, Kustova M, Bordiga S, Beato P, Lillerud KP, Svellea S, Olsbye U (2011) Conversion of methanol over 10-ring zeolites with differing volumes at channel intersections: comparison of TNU-9, IM-5, ZSM-11 and ZSM-5. Phys Chem Chem Phys 13:2539–2549PubMed

45.

Franch-Martí C, Alonso-Escobar C, Jorda JL, Peral I, Hernández-Fenollosa J, Corma A, Palomares AE, Rey F, Guilera G (2012) TNU-9, a new zeolite for the selective catalytic reduction of NO: an in situ X-ray absorption spectroscopy study. J Catal 295:22–30

46.

Al-Khattaf S, Ali SA, Aitani MA, Žilková N, Kubicka D, Cejka J (2014) Recent advances in reactions of alkylbenzenes over novel zeolites: the effects of zeolite structure and morphology. Catal Rev 56:333–402

47.

Gołąbek K, Tarach KA, Filek U, Góra-Marek K (2018) Ethylene formation by dehydration of ethanol over medium pore zeolites. Spectrochim Acta A 192:464–472

48.

Liu H, Yang S, Wu S, Shang F, Yu X, Xu C, Guan J, Kan Q (2011) Synthesis of Mo/TNU-9 (TNU-9 Taejon National University No. 9) catalyst and its catalytic performance in methane non-oxidative aromatization. Energy 36:1582–1589

49.

Zhao YH, Gao TY, Wang YJ, Zhou YJ, Huang GQ (2018) Zinc supported on alkaline activated HZSM-5 for aromatization reaction. React Kinet Mech Cat 125(2):1085–1098

50.

Schulz H (2010) “Coking” of zeolites during methanol conversion: Basic reactions of the MTO- MTP- and MTG processes. Catal Today 154:183–194

51.

Olsbye U, Svelle S, Bjørgen M, Beato P, Janssens T, Bordiga S, Lillerud K (2012) Conversion of methanol to hydrocarbons: how zeolite cavity and pore size controls product selectivity. Angew Chem Int Ed 51:2–24

52.

Petushkov A, Yoon S, Larsen SC (2011) Synthesis of hierarchical nanocrystalline ZSM-5 with controlled particle size and mesoporosity. Micropor Mesopor Mat 137:92–100

53.

Min KH, Park MB, Hong SB (2010) Methanol-to-olefin conversion over H-MCM-22 and H-ITQ-2 zeolites. J, Catal 271:186–194

54.

Lacarriere A, Luck F, Swierczynski D, Fajula F, Hulea V (2011) Methanol to hydrocarbons over zeolites with MWW topology: Effect of zeolite texture and acidity. Appl. Catal. A-Gen. 402:208–217

Title: Synthesis of 10 and 12 Ring Zeolites (MCM-22, TNU-9 and MCM-68) Modified with Zn and Its Potential Application in the Reaction of Methanol to Light Aromatics and Olefins
Publication date: 17-02-2020
Published in: Topics in Catalysis / Issue 5-6/2020
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-020-01242-x

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