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Journal of Polymer Research

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01-12-2023 | Original Paper

Synthesis of a novel fluorinated polymer: poly(2-(tetrafluoro(trifluoromethyl)-λ⁶-sulfanyl)ethyl acrylate)

Authors: Muqian Deng, John T. Welch

Published in: Journal of Polymer Research | Issue 12/2023

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Abstract

Tetrafluoro(trifluoromethyl)-λ⁶-sulfanylethyl acrylate, a novel acrylate monomer, was polymerized by initiation with azobisisobutyronitrile (AIBN) at 60 °C to form a soft gel. This novel fluorinated ester was prepared by condensation of excess acryloyl chloride with 2-(tetrafluoro(trifluoromethyl)-λ⁶-sulfanyl)ethan-1-ol. Thermal decomposition of the polymer begins at 180 °C. Aqueous wetting by static contact measurement yielded a contact angle of 98°.

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Title: Synthesis of a novel fluorinated polymer: poly(2-(tetrafluoro(trifluoromethyl)-λ6-sulfanyl)ethyl acrylate)
Authors: Muqian Deng
John T. Welch
Publication date: 01-12-2023
Publisher: Springer Netherlands
Published in: Journal of Polymer Research / Issue 12/2023
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-023-03824-1

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