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Journal of Polymer Research

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01-07-2014 | Original Paper

Synthesis of poly(norbornene-co-styrene) copolymers containing high styrene incorporation using bis(β-ketoamino) copper catalysts

Authors: Qian Feng, Dajun Chen, Danyang Feng, Libin Jiao, Zhigang Peng, Lixia Pei

Published in: Journal of Polymer Research | Issue 7/2014

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Abstract

Poly(norbornene-co-styrene) copolymers were synthesized by copolymerizations of norbornene (NB) and styrene (St) with bis(β-ketoamino) copper complexes [ArNC(R)CHC(R)O]₂Cu (1, Ar = 2,6-dimethylphenyl, R = CH₃; 2, Ar = 2,6-diisopropylphenyl, R = CH₃; 3, Ar = 2,6-diisopropylphenyl, R = CF₃) in the presence of methylaluminoxane (MAO). The influences of catalyst structure, comonomer feeding ratio, n(Al)/n(Cu) molar ratio, and copolymerization temperature on catalytic activity and compositions of the copolymers were typically investigated. Determination of the reactivity ratios shows a much high reactivity for norbornene (r(NB) = 19.52, r(St) = 0.48), which supports a coordination mechanism. The structural characterizations of the obtained poly(NB-co-St) copolymers show that styrene units are successfully incorporated into norbornene sequences, and isolated styrene or very short styrene sequences are randomly distributed on the copolymer chain. A high incorporation of styrene up to 35.6 mol% in the poly(NB-co-St) copolymer can be achieved by bis(β-ketoamino) copper catalyst 1.

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Title: Synthesis of poly(norbornene-co-styrene) copolymers containing high styrene incorporation using bis(β-ketoamino) copper catalysts
Authors: Qian Feng
Dajun Chen
Danyang Feng
Libin Jiao
Zhigang Peng
Lixia Pei
Publication date: 01-07-2014
Publisher: Springer Netherlands
Published in: Journal of Polymer Research / Issue 7/2014
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-014-0497-1

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