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Published in: Journal of Polymer Research 7/2020

01-07-2020 | ORIGINAL PAPER

Synthesis of polystyrene/starch/CNT composite and study on its biodegradability

Authors: Ashutosh Kr Chaudhary, R. P. Vijayakumar

Published in: Journal of Polymer Research | Issue 7/2020

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Abstract

This paper presents the preparation of polystyrene-starch- carbon nanotubes composite by solvent casting technique. Phases present in the samples were analyzed using X-ray diffraction (XRD). The changes in the functional group of polystyrene after the addition of starch and carbon nanotubes were analyzed through Fourier-transform infrared spectroscopy (FTIR). An increase in the thermal stability of prepared composite was observed after the addition of starch and carbon nanotubes with respect to pure polystyrene as analyzed by Thermogravimetric analysis (TGA). Further, addition of starch and carbon nanotubes (CNTs) increases the number of decomposition sites. Scanning Electron Microscopy (SEM) analysis revealed the modifications in surface texture of polystyrene after addition of starch and CNTs. The addition of CNTs gave a conductivity of 9.148 × 10−3 1/Ω cm for polystyrene-starch (35%)-CNT (15%) composite. Biodegradation of the polymer composites after 3 months of soil burial period was analyzed by weight loss, XRD, FTIR, TGA and SEM analysis.

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Literature
1.
go back to reference Kaczmarek H, Światek M, Kamińska A (2004) Modification of polystyrene and poly(vinyl chloride) for the purpose of obtaining packaging materials degradable in the natural environment. Polym Degrad Stab 83:35–45 Kaczmarek H, Światek M, Kamińska A (2004) Modification of polystyrene and poly(vinyl chloride) for the purpose of obtaining packaging materials degradable in the natural environment. Polym Degrad Stab 83:35–45
2.
go back to reference Pushpadass HA, Weber RW, Dumais JJ, Hanna MA (2010) Biodegradation characteristics of starch-polystyrene loose-fill foams in a composting medium. Bioresour Technol 101:7258–7264PubMed Pushpadass HA, Weber RW, Dumais JJ, Hanna MA (2010) Biodegradation characteristics of starch-polystyrene loose-fill foams in a composting medium. Bioresour Technol 101:7258–7264PubMed
3.
go back to reference Ahmad JK, Abdul Amer ZJ, Majid A (2012) Effect of γ-radiation on thermal and chemical properties of starch/polystyrene biopolymer blend. J Biomim Biomater Tissue Eng 16:71–81 Ahmad JK, Abdul Amer ZJ, Majid A (2012) Effect of γ-radiation on thermal and chemical properties of starch/polystyrene biopolymer blend. J Biomim Biomater Tissue Eng 16:71–81
4.
go back to reference Sharma K, Kaith BS, Kumar V, Kalia S, Kumar V, Swart HC (2014) Synthesis and biodegradation studies of gamma irradiated electrically conductive hydrogels. Polym Degrad Stab 107:166–177 Sharma K, Kaith BS, Kumar V, Kalia S, Kumar V, Swart HC (2014) Synthesis and biodegradation studies of gamma irradiated electrically conductive hydrogels. Polym Degrad Stab 107:166–177
5.
go back to reference Sheikh N, Akhavan A, Ataeivarjovi E (2013) Radiation grafting of styrene on starch with high efficiency. Radiat Phys Chem 85:189–192 Sheikh N, Akhavan A, Ataeivarjovi E (2013) Radiation grafting of styrene on starch with high efficiency. Radiat Phys Chem 85:189–192
6.
go back to reference Tian L, Kolvenbach B, Corvini N, Wang S, Tavanaie N, Wang L, Ma Y, Scheu S, Corvini PFX, Ji R (2017) Mineralisation of 14C-labelled polystyrene plastics by Penicillium variabile after ozonation pre-treatment. New Biotechnol 38:101–105 Tian L, Kolvenbach B, Corvini N, Wang S, Tavanaie N, Wang L, Ma Y, Scheu S, Corvini PFX, Ji R (2017) Mineralisation of 14C-labelled polystyrene plastics by Penicillium variabile after ozonation pre-treatment. New Biotechnol 38:101–105
7.
go back to reference Ali HE, Ghaffar AMA (2017) Preparation and effect of gamma radiation on the properties and biodegradability of poly ( styrene / starch ) blends. Radiat Phys Chem 130:411–420 Ali HE, Ghaffar AMA (2017) Preparation and effect of gamma radiation on the properties and biodegradability of poly ( styrene / starch ) blends. Radiat Phys Chem 130:411–420
8.
go back to reference Chaudhary AK, Vijayakumar RP (2020) Effect of chemical treatment on biological degradation of high density polyethylene ( HDPE ). Environ Dev Sustain 22:1093–1104 Chaudhary AK, Vijayakumar RP (2020) Effect of chemical treatment on biological degradation of high density polyethylene ( HDPE ). Environ Dev Sustain 22:1093–1104
9.
go back to reference Ojeda T, Freitas A, Dalmolin E, Pizzol MD, Vignol L, Melnik J, Jacques R, Bento F, Camargo F (2009) Abiotic and biotic degradation of oxo-biodegradable foamed polystyrene. Polym Degrad Stab 94:2128–2133 Ojeda T, Freitas A, Dalmolin E, Pizzol MD, Vignol L, Melnik J, Jacques R, Bento F, Camargo F (2009) Abiotic and biotic degradation of oxo-biodegradable foamed polystyrene. Polym Degrad Stab 94:2128–2133
10.
go back to reference Dafader NC, Rahman N, Alam MF et al (2017) Preparation and characterization of starch/polyvinyl alcohol blend films by the application of gamma radiation. J Polym Res 11:121–132 Dafader NC, Rahman N, Alam MF et al (2017) Preparation and characterization of starch/polyvinyl alcohol blend films by the application of gamma radiation. J Polym Res 11:121–132
11.
go back to reference Schlemmer D, Sales MJA, Resck IS (2009) Degradation of different polystyrene/thermoplastic starch blends buried in soil. Carbohydr Polym 75:58–62 Schlemmer D, Sales MJA, Resck IS (2009) Degradation of different polystyrene/thermoplastic starch blends buried in soil. Carbohydr Polym 75:58–62
12.
go back to reference Kiatkamjornwong S, Sonsuk M, Wittayapichet S, Prasassarakich P, Vejjanukroh PC (1999) Degradation of styrene-g-cassava starch filled polystyrene plastics. Polym Degrad Stab 66:323–335 Kiatkamjornwong S, Sonsuk M, Wittayapichet S, Prasassarakich P, Vejjanukroh PC (1999) Degradation of styrene-g-cassava starch filled polystyrene plastics. Polym Degrad Stab 66:323–335
13.
go back to reference Oliveira CIR, Cunha FR, Andrade CT (2010) Evaluation of biodegradability of different blends of polystyrene and starch buried in soil. Macromol Symp 290:115–120 Oliveira CIR, Cunha FR, Andrade CT (2010) Evaluation of biodegradability of different blends of polystyrene and starch buried in soil. Macromol Symp 290:115–120
14.
go back to reference Ashamol A, Sailaja RRN (2011) Mechanical, thermal, and biodegradation studies of polystyrene–Phthalated starch blends using epoxy functionalized Compatibilizer. J Appl Polym Sci 125:313–326 Ashamol A, Sailaja RRN (2011) Mechanical, thermal, and biodegradation studies of polystyrene–Phthalated starch blends using epoxy functionalized Compatibilizer. J Appl Polym Sci 125:313–326
15.
go back to reference Nikolic V, Sava Velickovic AP (2014) Biodegradation of polystyrene- graft -starch copolymers in three different types of soil. Environ Sci Pollut Res 21:9877–9886 Nikolic V, Sava Velickovic AP (2014) Biodegradation of polystyrene- graft -starch copolymers in three different types of soil. Environ Sci Pollut Res 21:9877–9886
17.
go back to reference Kaewtatip K, Tanrattanakul V (2008) Preparation of cassava starch grafted with polystyrene by suspension polymerization. Carbohydr Polym 73:647–655PubMed Kaewtatip K, Tanrattanakul V (2008) Preparation of cassava starch grafted with polystyrene by suspension polymerization. Carbohydr Polym 73:647–655PubMed
18.
go back to reference Yu Y, Wang J (2007) Effect of γ-ray irradiation on starch granule structure and physicochemical properties of rice. Food Res Int 40:297–303 Yu Y, Wang J (2007) Effect of γ-ray irradiation on starch granule structure and physicochemical properties of rice. Food Res Int 40:297–303
19.
go back to reference Kumar S, Maiti P (2016) Controlled biodegradation of polymers using nanoparticles and its application. RSC Adv 6:67449–67480 Kumar S, Maiti P (2016) Controlled biodegradation of polymers using nanoparticles and its application. RSC Adv 6:67449–67480
21.
go back to reference Goodwin DG, Boyer I, Devahif T et al (2018) Biodegradation of carbon nanotube/polymer nanocomposites using a monoculture. Environ Sci Technol 52:40–51PubMed Goodwin DG, Boyer I, Devahif T et al (2018) Biodegradation of carbon nanotube/polymer nanocomposites using a monoculture. Environ Sci Technol 52:40–51PubMed
22.
go back to reference Nzenguet AM, Aqlil M, Essamlali Y, Amadine O, Snik A, Larzek M, Zahouily M (2018) Novel bionanocomposite films based on graphene oxide filled starch/polyacrylamide polymer blend: structural, mechanical and water barrier properties. J Polym Res 25:86 Nzenguet AM, Aqlil M, Essamlali Y, Amadine O, Snik A, Larzek M, Zahouily M (2018) Novel bionanocomposite films based on graphene oxide filled starch/polyacrylamide polymer blend: structural, mechanical and water barrier properties. J Polym Res 25:86
23.
go back to reference Du JH, Bai J, Cheng HM (2007) The present status and key problems of carbon nanotube based polymer composites. Express Polym Lett 1:253–273 Du JH, Bai J, Cheng HM (2007) The present status and key problems of carbon nanotube based polymer composites. Express Polym Lett 1:253–273
24.
go back to reference Sharif A, Aalaie J, Shariatpanahi H, Hosseinkhanli H, Khoshniyat A (2011) Study on the structure and properties of nanocomposites based on high-density polyethylene/starch blends. J Polym Res 18:1955–1969 Sharif A, Aalaie J, Shariatpanahi H, Hosseinkhanli H, Khoshniyat A (2011) Study on the structure and properties of nanocomposites based on high-density polyethylene/starch blends. J Polym Res 18:1955–1969
25.
go back to reference Smart SK, Cassady AI, Lu GQ, Martin DJ (2006) The biocompatibility of carbon nanotubes. Carbon N Y 44:1034–1047 Smart SK, Cassady AI, Lu GQ, Martin DJ (2006) The biocompatibility of carbon nanotubes. Carbon N Y 44:1034–1047
26.
go back to reference Zhang L, Petersen EJ, Habteselassie MY, Mao L, Huang Q (2013) Degradation of multiwall carbon nanotubes by bacteria. Environ Pollut 181:335–339PubMed Zhang L, Petersen EJ, Habteselassie MY, Mao L, Huang Q (2013) Degradation of multiwall carbon nanotubes by bacteria. Environ Pollut 181:335–339PubMed
27.
go back to reference Bajad GS, Tiwari SK, Vijayakumar RP (2015) Synthesis and characterization of CNTs using polypropylene waste as precursor. Mater Sci Eng B Solid-State Mater Adv Technol 194:68–77 Bajad GS, Tiwari SK, Vijayakumar RP (2015) Synthesis and characterization of CNTs using polypropylene waste as precursor. Mater Sci Eng B Solid-State Mater Adv Technol 194:68–77
28.
go back to reference Al-Shabanat M (2012) Electrical studies of nanocomposites consisting of MWNTs and polystyrene. J Polym Res 19:1–8 Al-Shabanat M (2012) Electrical studies of nanocomposites consisting of MWNTs and polystyrene. J Polym Res 19:1–8
29.
go back to reference Song S, Wang C, Pan Z, Wang X (2008) Preparation and characterization of Amphiphilic starch Nanocrystals. J Appl Polym Sci 107:418–422 Song S, Wang C, Pan Z, Wang X (2008) Preparation and characterization of Amphiphilic starch Nanocrystals. J Appl Polym Sci 107:418–422
30.
go back to reference Sen P, Suresh K, Kumar RV et al (2016) A simple solvent blending coupled sonication technique for synthesis of polystyrene ( PS )/ multi-walled carbon nanotube ( MWCNT ) nanocomposites : effect of modified MWCNT content. J Sci Adv Mater Devices 1:311–323 Sen P, Suresh K, Kumar RV et al (2016) A simple solvent blending coupled sonication technique for synthesis of polystyrene ( PS )/ multi-walled carbon nanotube ( MWCNT ) nanocomposites : effect of modified MWCNT content. J Sci Adv Mater Devices 1:311–323
31.
go back to reference Gómez S, Rendtorff NM, Aglietti EF, Sakka Y, Suarez G (2017) Intensity of sulfonitric treatment on multiwall carbon nanotubes. Chem Phys Lett 689:135–141 Gómez S, Rendtorff NM, Aglietti EF, Sakka Y, Suarez G (2017) Intensity of sulfonitric treatment on multiwall carbon nanotubes. Chem Phys Lett 689:135–141
32.
go back to reference Gaur MS, Singh R, Tiwari RK (2014) Study of structural morphology , thermal degradation and surface charge decay in PU + PSF + CNTs polymer hybrid nanocomposite. J Electrost 72:242–251 Gaur MS, Singh R, Tiwari RK (2014) Study of structural morphology , thermal degradation and surface charge decay in PU + PSF + CNTs polymer hybrid nanocomposite. J Electrost 72:242–251
33.
go back to reference Kim SY, Shin KS, Lee SH, Kim KW, Youn JR (2010) Unique crystallization behavior of multi-walled carbon nanotube filled poly(lactic acid). Fibers Polym 11:1018–1023 Kim SY, Shin KS, Lee SH, Kim KW, Youn JR (2010) Unique crystallization behavior of multi-walled carbon nanotube filled poly(lactic acid). Fibers Polym 11:1018–1023
34.
go back to reference Sarmiento AM, Guzmán HL, Morales G, Romero DE, Pataquiva-Mateus AY (2016) Expanded Polystyrene (EPS) and Waste Cooking Oil (WCO): from urban wastes to potential material of construction. Waste Biomass Valorization 7:1245–1254 Sarmiento AM, Guzmán HL, Morales G, Romero DE, Pataquiva-Mateus AY (2016) Expanded Polystyrene (EPS) and Waste Cooking Oil (WCO): from urban wastes to potential material of construction. Waste Biomass Valorization 7:1245–1254
35.
go back to reference Singh B, Sharma N (2007) Optimized synthesis and characterization of polystyrene graft copolymers and preliminary assessment of their biodegradability and application in water pollution alleviation technologies. Polym Degrad Stab 92:876–885 Singh B, Sharma N (2007) Optimized synthesis and characterization of polystyrene graft copolymers and preliminary assessment of their biodegradability and application in water pollution alleviation technologies. Polym Degrad Stab 92:876–885
36.
go back to reference Janarthanan P, Zin Wan Yunus WM, Bin AM (2003) Thermal behavior and surface morphology studies on polystyrene grafted sago starch. J Appl Polym Sci 90:2053–2058 Janarthanan P, Zin Wan Yunus WM, Bin AM (2003) Thermal behavior and surface morphology studies on polystyrene grafted sago starch. J Appl Polym Sci 90:2053–2058
37.
go back to reference Schlemmer D, De Oliveira ER, Sales MJA (2007) Polystyrene/thermoplastic starch blends with different plasticizers : preparation and thermal characterization. J Therm Anal Calorim 87:635–638 Schlemmer D, De Oliveira ER, Sales MJA (2007) Polystyrene/thermoplastic starch blends with different plasticizers : preparation and thermal characterization. J Therm Anal Calorim 87:635–638
38.
go back to reference Chiu F, Li B, Jiang J (2012) Syndiotactic polystyrene / multi-walled carbon nanotube nanocomposites : Polymorphism , thermal properties , electrical conductivity , and rheological properties. Compos Part A 43:2230–2240 Chiu F, Li B, Jiang J (2012) Syndiotactic polystyrene / multi-walled carbon nanotube nanocomposites : Polymorphism , thermal properties , electrical conductivity , and rheological properties. Compos Part A 43:2230–2240
39.
go back to reference McNally T, Potschke P, Halley P et al (2005) Polyethylene multiwalled carbon nanotube composites. Polymer 46:8222–8232 McNally T, Potschke P, Halley P et al (2005) Polyethylene multiwalled carbon nanotube composites. Polymer 46:8222–8232
40.
go back to reference Wang Y, Sotzing GA, Weiss RA (2003) Conductive polymer foams as sensors for volatile amines. Chem Mater 15:375–377 Wang Y, Sotzing GA, Weiss RA (2003) Conductive polymer foams as sensors for volatile amines. Chem Mater 15:375–377
41.
go back to reference Zhang H, Zhang G, Tang M, Zhou L, Li J, Fan X, Shi X, Qin J (2018) Synergistic effect of carbon nanotube and graphene nanoplates on the mechanical, electrical and electromagnetic interference shielding properties of polymer composites and polymer composite foams. Chem Eng J 353:381–393 Zhang H, Zhang G, Tang M, Zhou L, Li J, Fan X, Shi X, Qin J (2018) Synergistic effect of carbon nanotube and graphene nanoplates on the mechanical, electrical and electromagnetic interference shielding properties of polymer composites and polymer composite foams. Chem Eng J 353:381–393
43.
go back to reference Mor R, Sivan A (2008) Biofilm formation and partial biodegradation of polystyrene by the actinomycete Rhodococcus ruber: biodegradation of polystyrene. Biodegradation 19:851–858PubMed Mor R, Sivan A (2008) Biofilm formation and partial biodegradation of polystyrene by the actinomycete Rhodococcus ruber: biodegradation of polystyrene. Biodegradation 19:851–858PubMed
44.
go back to reference Aslan S, Loebick CZ, Kang S, Elimelech M, Pfefferle LD, van Tassel PR (2010) Antimicrobial biomaterials based on carbon nanotubes dispersed in poly(lactic-co-glycolic acid). Nanoscale 2:1789–1794PubMed Aslan S, Loebick CZ, Kang S, Elimelech M, Pfefferle LD, van Tassel PR (2010) Antimicrobial biomaterials based on carbon nanotubes dispersed in poly(lactic-co-glycolic acid). Nanoscale 2:1789–1794PubMed
45.
go back to reference Yang C, Mamouni J, Tang Y, Yang L (2010) Antimicrobial activity of single-walled carbon nanotubes: length effect. Langmuir 26:16013–16019PubMed Yang C, Mamouni J, Tang Y, Yang L (2010) Antimicrobial activity of single-walled carbon nanotubes: length effect. Langmuir 26:16013–16019PubMed
46.
go back to reference Restrepo-flórez J, Bassi A, Thompson MR (2014) Microbial degradation and deterioration of polyethylene- a review. Int Biodeterior Biodegradation 88:83–90 Restrepo-flórez J, Bassi A, Thompson MR (2014) Microbial degradation and deterioration of polyethylene- a review. Int Biodeterior Biodegradation 88:83–90
47.
go back to reference Niculăescua P, Olarb L, Stefanb R et al (2018) XRD and IR investigations of some commercial polystyrene samples thermally degraded. Stud UBB Chem 2:63–70 Niculăescua P, Olarb L, Stefanb R et al (2018) XRD and IR investigations of some commercial polystyrene samples thermally degraded. Stud UBB Chem 2:63–70
48.
go back to reference Wu Y, Xiong W, Zhou H, Li H, Xu G, Zhao J (2016) Biodegradation of poly ( butylene succinate ) film by compost microorganisms and water soluble product impact on mung beans germination. Polym Degrad Stab 126:22–30 Wu Y, Xiong W, Zhou H, Li H, Xu G, Zhao J (2016) Biodegradation of poly ( butylene succinate ) film by compost microorganisms and water soluble product impact on mung beans germination. Polym Degrad Stab 126:22–30
49.
go back to reference Syranidou E, Karkanorachaki K, Amorotti F et al (2017) Biodegradation of weathered polystyrene films in seawater microcosms. Sci Rep 7:1–12 Syranidou E, Karkanorachaki K, Amorotti F et al (2017) Biodegradation of weathered polystyrene films in seawater microcosms. Sci Rep 7:1–12
50.
go back to reference Sudhakar M, Doble M, Murthy PS, Venkatesan R (2008) Marine microbe-mediated biodegradation of low and high-density polyethylenes. Int Biodeterior Biodegrad 61:203–213 Sudhakar M, Doble M, Murthy PS, Venkatesan R (2008) Marine microbe-mediated biodegradation of low and high-density polyethylenes. Int Biodeterior Biodegrad 61:203–213
51.
go back to reference Jeyakumar D, Chirsteen J, Doble M (2013) Synergistic effects of pretreatment and blending on fungi mediated biodegradation of polypropylenes. Bioresour Technol 148:78–85PubMed Jeyakumar D, Chirsteen J, Doble M (2013) Synergistic effects of pretreatment and blending on fungi mediated biodegradation of polypropylenes. Bioresour Technol 148:78–85PubMed
Metadata
Title
Synthesis of polystyrene/starch/CNT composite and study on its biodegradability
Authors
Ashutosh Kr Chaudhary
R. P. Vijayakumar
Publication date
01-07-2020
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 7/2020
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-020-02164-8

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