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Published in: Journal of Materials Science 16/2017

04-05-2017 | Ceramics

Synthesis, photoluminescence properties of Sr1.95Ba0.05CeO4:Eu3+ for LED applications

Authors: Rajesh Narayana Perumal, G. Subalakshmi, G. Vinitha

Published in: Journal of Materials Science | Issue 16/2017

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Abstract

The Sr1.95Ba0.05 CeO4:Eu3+ phosphors are synthesized by the solid-state reaction method. The samples are characterized using X-ray diffraction (XRD), diffuse reflectance spectroscopy and photoluminescence (PL) spectra. The XRD results reveal that the synthesized phosphors are genuine crystalline and belong to the orthorhombic structure. The intense PL emission is optimized from the PL spectra at various doping concentrations of europium ions. The results indicates that the phosphor can be effectively excited under 264 nm wavelength producing on intense emission spectrum of the synthesis material at 484 nm (blue region). The color purity of the phosphor is confirmed by CIE coordinates (x = 0.217, y = 0.265). The experimental data indicate that the prepared phosphors can be used as blue-emitting material in the field of illuminations and display devices.

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Literature
1.
go back to reference Bandi VR, Grandhe BK, Jang K et al (2011) Luminescent properties of a new green emitting of a new green emitting Eu2+ doped CaZrSi2O7 phosphor for WLED applications. J Lumin 131:2414–2418CrossRef Bandi VR, Grandhe BK, Jang K et al (2011) Luminescent properties of a new green emitting of a new green emitting Eu2+ doped CaZrSi2O7 phosphor for WLED applications. J Lumin 131:2414–2418CrossRef
2.
3.
go back to reference Qi L, Lee BI, Kim JM, Jang JE, Choe JY (2003) Synthesis and characterization of ZnS:Cu, Al phosphor prepared by a chemical solution method. J Lumin 104:261–266CrossRef Qi L, Lee BI, Kim JM, Jang JE, Choe JY (2003) Synthesis and characterization of ZnS:Cu, Al phosphor prepared by a chemical solution method. J Lumin 104:261–266CrossRef
4.
go back to reference Liang C, You H, Fua Y, Tenga X, Liua K, He J (2017) Luminescence properties of a tunable blue-green-emitting Ca10(PO4)6S:Ce3+, Tb3+ phosphors for UV-excited white LEDs. Optik 131:335–342CrossRef Liang C, You H, Fua Y, Tenga X, Liua K, He J (2017) Luminescence properties of a tunable blue-green-emitting Ca10(PO4)6S:Ce3+, Tb3+ phosphors for UV-excited white LEDs. Optik 131:335–342CrossRef
5.
go back to reference Su-Hua YANG, Meiso YOKOYAMA (1997) Improvement of cathodoluminescence for ZnGa2O4 phosphor by second fired process. Jpn J Appl Phys 36:5145–5150CrossRef Su-Hua YANG, Meiso YOKOYAMA (1997) Improvement of cathodoluminescence for ZnGa2O4 phosphor by second fired process. Jpn J Appl Phys 36:5145–5150CrossRef
6.
go back to reference Prashantha SC, Lakshminarasappa BN, Nagabhushana BM (2011) Photoluminescence and thermoluminescence studies of Mg2SiO4:Eu3+ nanophosphor. J Alloy Compd 509:10185–10189CrossRef Prashantha SC, Lakshminarasappa BN, Nagabhushana BM (2011) Photoluminescence and thermoluminescence studies of Mg2SiO4:Eu3+ nanophosphor. J Alloy Compd 509:10185–10189CrossRef
7.
go back to reference Zuoling F, Zhou S, Yingning Yu, Zhang S (2005) Photoluminescence properties and analysis of spectral structure of Eu3+ -doped SrY2O4. J Phys Chem B 109:23320–23325CrossRef Zuoling F, Zhou S, Yingning Yu, Zhang S (2005) Photoluminescence properties and analysis of spectral structure of Eu3+ -doped SrY2O4. J Phys Chem B 109:23320–23325CrossRef
8.
9.
go back to reference Hussain SK, Nagaraju G, Pavitra E, Raju G Seeta Rama, Yu JS (2015) La(OH)3:Eu3+ and La2O3:Eu3+ nanorod bundles: growth mechanism and luminescence properties. Cryst Eng Comm 17:9431–9442CrossRef Hussain SK, Nagaraju G, Pavitra E, Raju G Seeta Rama, Yu JS (2015) La(OH)3:Eu3+ and La2O3:Eu3+ nanorod bundles: growth mechanism and luminescence properties. Cryst Eng Comm 17:9431–9442CrossRef
10.
go back to reference Tian B, Chen B, Tian Y et al (2013) Excitation pathway and temperature dependent luminescence in color tunable Ba5Gd8Zn4O21:Eu3+ phosphors. J Mater Chem. C 1:2338–2344CrossRef Tian B, Chen B, Tian Y et al (2013) Excitation pathway and temperature dependent luminescence in color tunable Ba5Gd8Zn4O21:Eu3+ phosphors. J Mater Chem. C 1:2338–2344CrossRef
11.
go back to reference Zhu H, Li R, Luo W, Chen X (2011) Eu3+-doped β-Ga2O3 nanophosphors: annealing effect, electronic structure and optical spectroscopy. Phys Chem Chem Phys 13:4411–4419CrossRef Zhu H, Li R, Luo W, Chen X (2011) Eu3+-doped β-Ga2O3 nanophosphors: annealing effect, electronic structure and optical spectroscopy. Phys Chem Chem Phys 13:4411–4419CrossRef
12.
go back to reference Lee JH, Kim YJ (2008) Photoluminescent properties of Sr2SiO4: Eu2+ phosphors prepared by solid-state reaction method. Mater Sci Eng B 146:99–102CrossRef Lee JH, Kim YJ (2008) Photoluminescent properties of Sr2SiO4: Eu2+ phosphors prepared by solid-state reaction method. Mater Sci Eng B 146:99–102CrossRef
13.
go back to reference Hao Y-J, Lai Qiong-Yu, Ji-Zheng L et al (2006) Synthesis and characterization of spinel Li4Ti5O12 anode material by oxalic acid-assisted sol–gel method. J Power Sour 158:1358–1364CrossRef Hao Y-J, Lai Qiong-Yu, Ji-Zheng L et al (2006) Synthesis and characterization of spinel Li4Ti5O12 anode material by oxalic acid-assisted sol–gel method. J Power Sour 158:1358–1364CrossRef
14.
go back to reference Shabbir G, Qureshi AH, Saeed K (2006) Nano-crystalline LaFeO3 powders synthesized by the citrate–gel method. Mater Lett 60:3706–3709CrossRef Shabbir G, Qureshi AH, Saeed K (2006) Nano-crystalline LaFeO3 powders synthesized by the citrate–gel method. Mater Lett 60:3706–3709CrossRef
15.
go back to reference Chang C, Jie X, Jiang L et al (2006) Luminescence of long-lasting CaAl2O4: Eu2+, Nd3+ phosphor by co-precipitation method. Mater Chem Phys 98:509–513CrossRef Chang C, Jie X, Jiang L et al (2006) Luminescence of long-lasting CaAl2O4: Eu2+, Nd3+ phosphor by co-precipitation method. Mater Chem Phys 98:509–513CrossRef
16.
go back to reference Jung KY, Han KH, Kang YC, Jung H-K (2006) Preparation of CaMgSi2O6: Eu blue phosphor particles by spray pyrolysis and its VUV characteristics. Mater Chem Phys 98:330–336CrossRef Jung KY, Han KH, Kang YC, Jung H-K (2006) Preparation of CaMgSi2O6: Eu blue phosphor particles by spray pyrolysis and its VUV characteristics. Mater Chem Phys 98:330–336CrossRef
17.
go back to reference Peng T, Yang H, Xuli P et al (2004) Combustion synthesis and photoluminescence of SrAl2O4:Eu, Dy phosphor nanoparticles. Mater Lett 58:352–356CrossRef Peng T, Yang H, Xuli P et al (2004) Combustion synthesis and photoluminescence of SrAl2O4:Eu, Dy phosphor nanoparticles. Mater Lett 58:352–356CrossRef
18.
go back to reference Vadivel Murugan A, Viswanath AK, Ravi V et al (2006) Photoluminescence studies of Eu3+ doped Y2O3 nanophosphor prepared by microwave hydrothermal method. Appl Phys Lett 89:123120CrossRef Vadivel Murugan A, Viswanath AK, Ravi V et al (2006) Photoluminescence studies of Eu3+ doped Y2O3 nanophosphor prepared by microwave hydrothermal method. Appl Phys Lett 89:123120CrossRef
19.
go back to reference Das S, Kar S, Chaudhuri S (2006) Optical properties of SnO2 nanoparticles and nanorods synthesized by solvothermal process. J Appl Phys 99:114303CrossRef Das S, Kar S, Chaudhuri S (2006) Optical properties of SnO2 nanoparticles and nanorods synthesized by solvothermal process. J Appl Phys 99:114303CrossRef
20.
go back to reference Stefani R, Maia AD, Teotonio EES et al (2006) Photoluminescent behavior of SrB4O7:RE2+ (RE = Sm and Eu) prepared by Pechini, combustion and ceramic methods. J Solid State Chem 179:1086–1092CrossRef Stefani R, Maia AD, Teotonio EES et al (2006) Photoluminescent behavior of SrB4O7:RE2+ (RE = Sm and Eu) prepared by Pechini, combustion and ceramic methods. J Solid State Chem 179:1086–1092CrossRef
21.
go back to reference Goubin F, Rocquefelte X, Whangbo M-H et al (2004) Experimental and theoretical characterization of the optical properties of CeO2, SrCeO3, and Sr2CeO4 containing Ce4+ (f0) ions. Chem Mater 16:662–669CrossRef Goubin F, Rocquefelte X, Whangbo M-H et al (2004) Experimental and theoretical characterization of the optical properties of CeO2, SrCeO3, and Sr2CeO4 containing Ce4+ (f0) ions. Chem Mater 16:662–669CrossRef
22.
go back to reference Pieterson L, Meijerink A (2000) Charge transfer luminescence of Yb3+ in orthophosphates. J Alloy Compd 300–301:426–429CrossRef Pieterson L, Meijerink A (2000) Charge transfer luminescence of Yb3+ in orthophosphates. J Alloy Compd 300–301:426–429CrossRef
23.
go back to reference Danielson E, Devenney M, Giaquinta DM et al (1998) A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods. Science 279:837CrossRef Danielson E, Devenney M, Giaquinta DM et al (1998) A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods. Science 279:837CrossRef
24.
go back to reference Ting C-C, Chen S-Y, Hsieh W-F, Lee H-Y (2001) Effects of yttrium codoping on photoluminescence of erbium-doped TiO2 films. J Appl Phys 90:5564CrossRef Ting C-C, Chen S-Y, Hsieh W-F, Lee H-Y (2001) Effects of yttrium codoping on photoluminescence of erbium-doped TiO2 films. J Appl Phys 90:5564CrossRef
25.
go back to reference Binnemans K (2015) Interpretation of europium(III) spectra. Coord Chem Rev 295:1–45CrossRef Binnemans K (2015) Interpretation of europium(III) spectra. Coord Chem Rev 295:1–45CrossRef
Metadata
Title
Synthesis, photoluminescence properties of Sr1.95Ba0.05CeO4:Eu3+ for LED applications
Authors
Rajesh Narayana Perumal
G. Subalakshmi
G. Vinitha
Publication date
04-05-2017
Publisher
Springer US
Published in
Journal of Materials Science / Issue 16/2017
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1126-2

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