Skip to main content
Top
Published in: Clean Technologies and Environmental Policy 6/2016

25-02-2016 | Original Paper

Tanning performance and environmental effects of nanosized graphene oxide tanning agent

Authors: Shenghua Lv, Qingfang Zhou, Ying Li, Yaya He, Haoran Zhao, Shiyu Sun

Published in: Clean Technologies and Environmental Policy | Issue 6/2016

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Nanosized graphene oxide (GO) with multiple oxygen-containing groups was prepared as a leather tanning agent. Leather tanned with 0.4 % GO can meet the shrinkage temperature (T s) and mechanical properties required for the commercial leather products. The GO nano-tanning effluent had much lower pollution indexes, such as total nitrogen, total organic carbon, chemical oxygen demand, biochemical oxygen demand, protein, oil, and salts, than the control chrome tanning agent. Our results indicate that the GO nano-tanning agent can replace chrome tanning agents to make leather for eliminating chrome pollution and achieving clean leather tanning.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
go back to reference Akhavan O (2015) Bacteriorhodopsin as a superior substitute for hydrazine in chemical reduction of single-layer graphene oxide sheets. Carbon 81:158–166CrossRef Akhavan O (2015) Bacteriorhodopsin as a superior substitute for hydrazine in chemical reduction of single-layer graphene oxide sheets. Carbon 81:158–166CrossRef
go back to reference Ashraf CM, Ahmad S, Malik MT (1998) Supported liquid membrane technique applicability for removal of chromium from tannery wastes. Waste Manag 17:211–218CrossRef Ashraf CM, Ahmad S, Malik MT (1998) Supported liquid membrane technique applicability for removal of chromium from tannery wastes. Waste Manag 17:211–218CrossRef
go back to reference Bao Y, Ma JZ (2012) Preparation of nanocomposites containing montmorillonite and SiO2 particle for leather tanning agent. J Am Leather Chem Assoc 107:429–434 Bao Y, Ma JZ (2012) Preparation of nanocomposites containing montmorillonite and SiO2 particle for leather tanning agent. J Am Leather Chem Assoc 107:429–434
go back to reference Chattopadhyay B, Aich A, Mukhopadhyay SK (2012) Chromium in the Tanning Industry: an Odyssey from Cradle to Grave. J Soc Leather Technol Chem 96(4):133–140 Chattopadhyay B, Aich A, Mukhopadhyay SK (2012) Chromium in the Tanning Industry: an Odyssey from Cradle to Grave. J Soc Leather Technol Chem 96(4):133–140
go back to reference Fan HJ, Shi B, He Q, Peng BY (2004) Tanning characteristics and tanning mechanism of nano-SiO2. J Soc Leather Technol Chem 88:139–142 Fan HJ, Shi B, He Q, Peng BY (2004) Tanning characteristics and tanning mechanism of nano-SiO2. J Soc Leather Technol Chem 88:139–142
go back to reference Fathima A, Rao Aravindhan RJR, Nair BU (2015) Biomass of Termitomyces clypeatus for chromium(III) removal from chrome tanning waste water. Clean Technol Environ Policy 17:541–547CrossRef Fathima A, Rao Aravindhan RJR, Nair BU (2015) Biomass of Termitomyces clypeatus for chromium(III) removal from chrome tanning waste water. Clean Technol Environ Policy 17:541–547CrossRef
go back to reference Filice S, D’Angelo D, Spano SF (2016) Modification of graphene oxide and graphene oxide-TiO2 solutions by pulsed laser irradiation for dye removal from water. Mater Sci Semicond Proc 42:50–53CrossRef Filice S, D’Angelo D, Spano SF (2016) Modification of graphene oxide and graphene oxide-TiO2 solutions by pulsed laser irradiation for dye removal from water. Mater Sci Semicond Proc 42:50–53CrossRef
go back to reference Gao DG, Ma JZ, Chu Y, Lv B, Dai JF (2005) Preparation and application of organic/inorganic nano tanning agent. China Leather 34:9–14 Gao DG, Ma JZ, Chu Y, Lv B, Dai JF (2005) Preparation and application of organic/inorganic nano tanning agent. China Leather 34:9–14
go back to reference George N, Chauhan PS, Kumar V, Puri N, Gupta N (2014) Approach to ecofriendly leather: characterization and application of an alkaline protease for chemical free dehairing of skins and hides at pilot scale. J Clean Prod 79:249–257CrossRef George N, Chauhan PS, Kumar V, Puri N, Gupta N (2014) Approach to ecofriendly leather: characterization and application of an alkaline protease for chemical free dehairing of skins and hides at pilot scale. J Clean Prod 79:249–257CrossRef
go back to reference Hedberg Y, Lidén C, Wallinder IO (2014) Correlation between bulk- and surface chemistry of Cr-tanned leather and the release of Cr(III) and Cr(VI). J Hazard Mater 280:654–661CrossRef Hedberg Y, Lidén C, Wallinder IO (2014) Correlation between bulk- and surface chemistry of Cr-tanned leather and the release of Cr(III) and Cr(VI). J Hazard Mater 280:654–661CrossRef
go back to reference Huang X, Qi XY, Boey F, Zhang H (2012) Graphene-based composites. Chem Soc Rev 41:666–686CrossRef Huang X, Qi XY, Boey F, Zhang H (2012) Graphene-based composites. Chem Soc Rev 41:666–686CrossRef
go back to reference Li Y (2013) Synthesis of amphoteric vinyl polymer/inorganic nanocomposite tanning agent and its modification of collagen fiber. Dissertation, Shaanxi University of Science and Technology Li Y (2013) Synthesis of amphoteric vinyl polymer/inorganic nanocomposite tanning agent and its modification of collagen fiber. Dissertation, Shaanxi University of Science and Technology
go back to reference Li H, Fierens K, Zhang ZY, Vanparijs N, Schuijs MJ (2016) Spontaneous protein adsorption on graphene oxide nanosheets allowing efficient intracellular vaccine protein delivery. ACS Appl Mater Interfaces 8(2):1147–1155CrossRef Li H, Fierens K, Zhang ZY, Vanparijs N, Schuijs MJ (2016) Spontaneous protein adsorption on graphene oxide nanosheets allowing efficient intracellular vaccine protein delivery. ACS Appl Mater Interfaces 8(2):1147–1155CrossRef
go back to reference Lu SH, Duan JP, Gong R, Yan XL (2011) Preparation and properties of modified starch by glutaraldehyde and citric acid. J Am Leather Chem Assoc 106:287–293 Lu SH, Duan JP, Gong R, Yan XL (2011) Preparation and properties of modified starch by glutaraldehyde and citric acid. J Am Leather Chem Assoc 106:287–293
go back to reference Marcilioa NR, Godinhob M, Masottia L, Martinsa CB (2010) Iron and chromium sulfates from ferrochromium alloy for tanning. Chem Eng J 165:17–25CrossRef Marcilioa NR, Godinhob M, Masottia L, Martinsa CB (2010) Iron and chromium sulfates from ferrochromium alloy for tanning. Chem Eng J 165:17–25CrossRef
go back to reference Mert BK, Kestioglu K (2014) Recovery of Cr(III) from tanning process using membrane separation processes. Clean Technol Environ Policy 16:1615–1624CrossRef Mert BK, Kestioglu K (2014) Recovery of Cr(III) from tanning process using membrane separation processes. Clean Technol Environ Policy 16:1615–1624CrossRef
go back to reference Mkhoyan KA, Contryman AW, Silcox J, Stewart DA, Mattevl C, Miller S, Chhowalla M (2009) Atomic and electronic structure of graphene-oxide. Nano Lett 9:1058–1063CrossRef Mkhoyan KA, Contryman AW, Silcox J, Stewart DA, Mattevl C, Miller S, Chhowalla M (2009) Atomic and electronic structure of graphene-oxide. Nano Lett 9:1058–1063CrossRef
go back to reference Nayak C, Nigam S, Pandey M, Sudarsan V, Majumder C, Jha SN, Bhatacharyya D, Vatsa RK, Kshirsagar RJ (2014) Nano-size effects on the nature of bonding in Y2Sn2O7: EXAFS and Raman spectroscopic investigations. Chem Phys Lett 597:51–56CrossRef Nayak C, Nigam S, Pandey M, Sudarsan V, Majumder C, Jha SN, Bhatacharyya D, Vatsa RK, Kshirsagar RJ (2014) Nano-size effects on the nature of bonding in Y2Sn2O7: EXAFS and Raman spectroscopic investigations. Chem Phys Lett 597:51–56CrossRef
go back to reference Pan H, Qi M, Zhang ZJ (2008) Preparation and application of PMBA/RNS nano-composites tanning agent. China Leather 37:25–28 Pan H, Qi M, Zhang ZJ (2008) Preparation and application of PMBA/RNS nano-composites tanning agent. China Leather 37:25–28
go back to reference Raghava RJ, Kanthimathi M, Thanikaivelan P, Sreeram KJ, Ramesh R, Ramalingam S, Chandrababu NK, Nair BU, Ramasami R (2004) Pickle-free chrome tanning using a polymeric synthetic tanning agent for cleaner leather processing. Clean Technol Enivron Policy 6:243–249 Raghava RJ, Kanthimathi M, Thanikaivelan P, Sreeram KJ, Ramesh R, Ramalingam S, Chandrababu NK, Nair BU, Ramasami R (2004) Pickle-free chrome tanning using a polymeric synthetic tanning agent for cleaner leather processing. Clean Technol Enivron Policy 6:243–249
go back to reference Ramamurthy G, Krishnamoorthy G, Sastry TP (2014) Rationalized method to enhance the chromium uptake in tanning process: role of Gallic acid. Clean Technol Environ Policy 16:647–654CrossRef Ramamurthy G, Krishnamoorthy G, Sastry TP (2014) Rationalized method to enhance the chromium uptake in tanning process: role of Gallic acid. Clean Technol Environ Policy 16:647–654CrossRef
go back to reference Rao RJ, Thanikaivelan P, Nair B (2002) An eco-friendly option for less-chrome and dye-free leather processing: in situ generation of natural colours in leathers tanned with Cr–Fe complex. Clean Technol Environ Policy 4:115–121CrossRef Rao RJ, Thanikaivelan P, Nair B (2002) An eco-friendly option for less-chrome and dye-free leather processing: in situ generation of natural colours in leathers tanned with Cr–Fe complex. Clean Technol Environ Policy 4:115–121CrossRef
go back to reference Rehman MA, Yusoff I, Alias Y (2016) Structural, morphological and magnetic investigations of CuCe0.2Fe1.8O4 graphene-supported nanocomposites. Chem Int 42:1399–1407 Rehman MA, Yusoff I, Alias Y (2016) Structural, morphological and magnetic investigations of CuCe0.2Fe1.8O4 graphene-supported nanocomposites. Chem Int 42:1399–1407
go back to reference Seabra AB, Paula AJ, de Lima R, Alves OL, Duran N (2014) Nanotoxicity of graphene and graphene oxide. Chem Res Toxicol 27:159–168CrossRef Seabra AB, Paula AJ, de Lima R, Alves OL, Duran N (2014) Nanotoxicity of graphene and graphene oxide. Chem Res Toxicol 27:159–168CrossRef
go back to reference Seggiani M, Puccini M, Vitolo S, Chiappe C, Pomelli CS, Castiello D (2014) Eco-friendly titanium tanning for the manufacture of bovine upper leathers: pilot-scale studies. Clean Technol Environ Policy 16(8):1795–1803CrossRef Seggiani M, Puccini M, Vitolo S, Chiappe C, Pomelli CS, Castiello D (2014) Eco-friendly titanium tanning for the manufacture of bovine upper leathers: pilot-scale studies. Clean Technol Environ Policy 16(8):1795–1803CrossRef
go back to reference Sfaksi Z, Azzouz N, Abdelwahab A (2014) Removal of Cr(VI) from water by cork waste. Arab J Chem 7:37–42CrossRef Sfaksi Z, Azzouz N, Abdelwahab A (2014) Removal of Cr(VI) from water by cork waste. Arab J Chem 7:37–42CrossRef
go back to reference Singh V, Joung D, Zhai L, Das S, Khondaker SI, Seal S (2011) Graphene based materials: past, present and future. Prog Mater Sci 56:1178–1271CrossRef Singh V, Joung D, Zhai L, Das S, Khondaker SI, Seal S (2011) Graphene based materials: past, present and future. Prog Mater Sci 56:1178–1271CrossRef
go back to reference Sun YC, Ma JZ, Bao Y, Yu YL (2010) Tanning properties of chrome tanning agent modified by carbon nanotubes. China Leather 39:18–21 Sun YC, Ma JZ, Bao Y, Yu YL (2010) Tanning properties of chrome tanning agent modified by carbon nanotubes. China Leather 39:18–21
go back to reference Yan L, Luo ZY, Fan HJ, Liu YS, Li H, Peng BY, Shi B (2008) Nano-SiO2/oxazolidine combination tannage: potential for chrome-free leather. J Soc Leather Technol Chem 92:252–257 Yan L, Luo ZY, Fan HJ, Liu YS, Li H, Peng BY, Shi B (2008) Nano-SiO2/oxazolidine combination tannage: potential for chrome-free leather. J Soc Leather Technol Chem 92:252–257
go back to reference Yolanda S, Hedberg CL, Inger OW (2014) Correlation between bulk- and surface chemistry of Cr-tanned leather and the release of Cr(III) and Cr(VI). J Hazard Mater 280:654–661CrossRef Yolanda S, Hedberg CL, Inger OW (2014) Correlation between bulk- and surface chemistry of Cr-tanned leather and the release of Cr(III) and Cr(VI). J Hazard Mater 280:654–661CrossRef
go back to reference Yu HS (2015) Research progress on tannery wastewater treatment technology. Leather Chem 32(3):22–25 Yu HS (2015) Research progress on tannery wastewater treatment technology. Leather Chem 32(3):22–25
go back to reference Zheng YC, Liu WT, Li GY (2015) Preparation of chrome tanning agent using the chrome sludge from tanning effluent. Leather Science and Engineering 25(6):11–15 Zheng YC, Liu WT, Li GY (2015) Preparation of chrome tanning agent using the chrome sludge from tanning effluent. Leather Science and Engineering 25(6):11–15
go back to reference Zouboulis AI, Samaras P, Krestou A, Tzoupanos ND (2012) Leather production modification methods towards minimization of tanning pollution: “green tanning”. Fresenius Environ Bull 2:2406–2412 Zouboulis AI, Samaras P, Krestou A, Tzoupanos ND (2012) Leather production modification methods towards minimization of tanning pollution: “green tanning”. Fresenius Environ Bull 2:2406–2412
go back to reference Zuriaga-Agustí E, Galiana-Aleixandre MV, Bes-Piá A, Mendoza-Roca JA, Risueño-Puchades V, Segarra V (2015) Pollution reduction in an eco-friendly chrome-free tanning and evaluation of the biodegradation by composting of the tanned leather wastes. J Clean Prod 87:874–881CrossRef Zuriaga-Agustí E, Galiana-Aleixandre MV, Bes-Piá A, Mendoza-Roca JA, Risueño-Puchades V, Segarra V (2015) Pollution reduction in an eco-friendly chrome-free tanning and evaluation of the biodegradation by composting of the tanned leather wastes. J Clean Prod 87:874–881CrossRef
Metadata
Title
Tanning performance and environmental effects of nanosized graphene oxide tanning agent
Authors
Shenghua Lv
Qingfang Zhou
Ying Li
Yaya He
Haoran Zhao
Shiyu Sun
Publication date
25-02-2016
Publisher
Springer Berlin Heidelberg
Published in
Clean Technologies and Environmental Policy / Issue 6/2016
Print ISSN: 1618-954X
Electronic ISSN: 1618-9558
DOI
https://doi.org/10.1007/s10098-016-1128-9

Other articles of this Issue 6/2016

Clean Technologies and Environmental Policy 6/2016 Go to the issue