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Published in: Tribology Letters 1/2010

01-10-2010 | Original Paper

The Effect of Morphology on the Tribological Properties of MoS2 in Liquid Paraffin

Authors: Kun Hong Hu, Xian Guo Hu, Yu Fu Xu, Fei Huang, Jun Sheng Liu

Published in: Tribology Letters | Issue 1/2010

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Abstract

The tribological properties of liquid paraffin (LP) containing molybdenum disulfide (MoS2) additives, including nano-balls, nano-slices, and bulk 2H-MoS2, are evaluated using a four-ball tribometer. Results show that all MoS2 additives used can improve the tribological properties of LP, and that nanosized MoS2 particles function as lubrication additives in LP better than micro-MoS2 particles do. The LP with nano-balls presents the best antifriction and antiwear properties at the MoS2 content of 1.5 wt%. This is ascribed to the chemical stability of the layer-closed spherical structure of nano-balls. The Stribeck curves confirm that the rotation speed of 1,450 rpm used is located at the mixed lubrication region under 300 N. MoS2 nano-slices have small sizes and easily enter into the interface of the friction pair with a roughness of 0.032 μm, functioning as a lubricant in LP better than nano-balls do at the MoS2 content of 1.0 wt%. The Stribeck curves also show that the differences between the two nano samples were magnified at high rotation speeds in hydrodynamic lubrication region. The application of nano-slices in high sliding speeds will be more advantageous. This work furthers the understanding of the relationship between the tribological properties and morphology of MoS2.

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Literature
1.
go back to reference Hu, X.G., Hu, S.L., Zhao, Y.S.: Synthesis of nanometric molybdenum disulphide particles and evaluation of friction and wear properties. Lubr Sci. 17, 295–308 (2005)CrossRef Hu, X.G., Hu, S.L., Zhao, Y.S.: Synthesis of nanometric molybdenum disulphide particles and evaluation of friction and wear properties. Lubr Sci. 17, 295–308 (2005)CrossRef
2.
go back to reference Chhowalla, M., Amaratunga, G.A.J.: Thin films of fullerene-like MoS2 nanoparticles with ultra-low friction and wear. Nature 407, 164–167 (2000)CrossRefADSPubMed Chhowalla, M., Amaratunga, G.A.J.: Thin films of fullerene-like MoS2 nanoparticles with ultra-low friction and wear. Nature 407, 164–167 (2000)CrossRefADSPubMed
3.
go back to reference Wo, H.Z., Hu, K.H., Hu, X.G.: Tribological properties of MoS2 nanoparticles as additive in a machine oil. Tribology 24, 33–37 (2004). (in Chinese) Wo, H.Z., Hu, K.H., Hu, X.G.: Tribological properties of MoS2 nanoparticles as additive in a machine oil. Tribology 24, 33–37 (2004). (in Chinese)
4.
go back to reference Peng, Y.Y., Meng, Z.Y., Zhong, C., Lu, J., Yang, Z.P., Qian, Y.T.: Tube- and ball-like amorphous MoS2 prepared by a solvothermal method. Mater. Chem. Phys. 73, 327–329 (2002)CrossRef Peng, Y.Y., Meng, Z.Y., Zhong, C., Lu, J., Yang, Z.P., Qian, Y.T.: Tube- and ball-like amorphous MoS2 prepared by a solvothermal method. Mater. Chem. Phys. 73, 327–329 (2002)CrossRef
5.
go back to reference Zhan, J.H., Zhan, Z.D., Qian, X.F., Wang, C., Xie, Y., Qian, Y.T.: Solvothermal synthesis of nanocrystalline MoS2 from MoO3 and elemental sulfur. J. Solid State Chem. 141, 270–273 (1998)CrossRefADS Zhan, J.H., Zhan, Z.D., Qian, X.F., Wang, C., Xie, Y., Qian, Y.T.: Solvothermal synthesis of nanocrystalline MoS2 from MoO3 and elemental sulfur. J. Solid State Chem. 141, 270–273 (1998)CrossRefADS
6.
go back to reference Li, W.J., Shi, E.W., Ko, J.M., Chen, Z.Z., Ogino, H., Fukuda, T.: Hydrothermal synthesis of MoS2 nanowires. J. Cryst. Growth 250, 418–422 (2003)CrossRefADS Li, W.J., Shi, E.W., Ko, J.M., Chen, Z.Z., Ogino, H., Fukuda, T.: Hydrothermal synthesis of MoS2 nanowires. J. Cryst. Growth 250, 418–422 (2003)CrossRefADS
7.
go back to reference Nath, M., Govindaraj, A., Rao, C.N.R.: Simple synthesis of MoS2 and WS2 nanotubes. Adv. Mater. 13, 283–286 (2001)CrossRef Nath, M., Govindaraj, A., Rao, C.N.R.: Simple synthesis of MoS2 and WS2 nanotubes. Adv. Mater. 13, 283–286 (2001)CrossRef
8.
go back to reference Zou, T.Z., Tu, J.P., Huang, H.D., Lai, D.M., Zhang, L.L., He, D.N.: Preparation and tribological properties of inorganic fullerene-like MoS2. Adv. Eng. Mater. 8, 289–293 (2006)CrossRef Zou, T.Z., Tu, J.P., Huang, H.D., Lai, D.M., Zhang, L.L., He, D.N.: Preparation and tribological properties of inorganic fullerene-like MoS2. Adv. Eng. Mater. 8, 289–293 (2006)CrossRef
9.
go back to reference Afanasiev, P., Xia, G.F., Berhault, G., Jouguet, B., Lacroix, M.: Surfactant-assisted synthesis of highly dispersed molybdenum sulfide. Chem. Mater. 11, 3216–3219 (1999)CrossRef Afanasiev, P., Xia, G.F., Berhault, G., Jouguet, B., Lacroix, M.: Surfactant-assisted synthesis of highly dispersed molybdenum sulfide. Chem. Mater. 11, 3216–3219 (1999)CrossRef
10.
go back to reference Feldman, Y., Wasserman, E., Srolovitz, D.J., Tenne, R.: High rate, gas phase growth of MoS2 nested inorganic fullerenes and nanotubes. Science 267, 222–225 (1995)CrossRefADSPubMed Feldman, Y., Wasserman, E., Srolovitz, D.J., Tenne, R.: High rate, gas phase growth of MoS2 nested inorganic fullerenes and nanotubes. Science 267, 222–225 (1995)CrossRefADSPubMed
11.
go back to reference Wilcoxon, J.P., Newcomer, P.P., Samara, G.A.: Synthesis and optical properties of MoS2 and isomorphous nanoclusters in the quantum confinement regime. J. Appl. Phys. 81, 7934–7944 (1997)CrossRefADS Wilcoxon, J.P., Newcomer, P.P., Samara, G.A.: Synthesis and optical properties of MoS2 and isomorphous nanoclusters in the quantum confinement regime. J. Appl. Phys. 81, 7934–7944 (1997)CrossRefADS
12.
go back to reference Huang, H.D., Tu, J.P., Zou, T.Z., Zhang, L.L., He, D.N.: Friction and wear properties of IF–MoS2 as additive in paraffin oil. Tribol. Lett. 20, 247–250 (2005)CrossRef Huang, H.D., Tu, J.P., Zou, T.Z., Zhang, L.L., He, D.N.: Friction and wear properties of IF–MoS2 as additive in paraffin oil. Tribol. Lett. 20, 247–250 (2005)CrossRef
13.
go back to reference Rapoport, L., Feldman, Y., Homyonfer, M., Cohen, H., Sloan, J., Hutchison, J.L., Tenne, R.: Inorganic fullerene-like material as additives to lubricants: structure–function relationship. Wear 225–229, 975–982 (1999)CrossRef Rapoport, L., Feldman, Y., Homyonfer, M., Cohen, H., Sloan, J., Hutchison, J.L., Tenne, R.: Inorganic fullerene-like material as additives to lubricants: structure–function relationship. Wear 225–229, 975–982 (1999)CrossRef
14.
go back to reference Cizaire, L., Vacher, B., Mogne, T.L., Martin, J.M., Rapoport, L., Margolin, A., Tenne, R.: Mechanisms of ultra-low friction by hollow inorganic fullerene-like MoS2 nanoparticles. Surf. Coat. Technol. 160, 282–287 (2002)CrossRef Cizaire, L., Vacher, B., Mogne, T.L., Martin, J.M., Rapoport, L., Margolin, A., Tenne, R.: Mechanisms of ultra-low friction by hollow inorganic fullerene-like MoS2 nanoparticles. Surf. Coat. Technol. 160, 282–287 (2002)CrossRef
15.
go back to reference Rapoport, L., Fleischer, N., Tenne, R.: Applications of WS2 (MoS2) inorganic nanotubes and fullerene-like nanoparticles for solid lubrication and for structural nanocomposites. J. Mater. Chem. 15, 1782–1788 (2005)CrossRef Rapoport, L., Fleischer, N., Tenne, R.: Applications of WS2 (MoS2) inorganic nanotubes and fullerene-like nanoparticles for solid lubrication and for structural nanocomposites. J. Mater. Chem. 15, 1782–1788 (2005)CrossRef
16.
go back to reference Hu, J.J., Bultman, J.E., Zabinski, J.S.: Inorganic fullerene-like nanoparticles produced by arc discharge in water with potential lubricating ability. Tribol. Lett. 17, 543–546 (2004)CrossRef Hu, J.J., Bultman, J.E., Zabinski, J.S.: Inorganic fullerene-like nanoparticles produced by arc discharge in water with potential lubricating ability. Tribol. Lett. 17, 543–546 (2004)CrossRef
17.
go back to reference Rosentsveig, R., Gorodnev, A., Feuerstein, N., Friedman, H., Zak, A., Fleischer, N., Tannous, J., Dassenoy, F., Tenne, R.: Fullerene-like MoS2 nanoparticles and their tribological behavior. Tribol. Lett. 36, 175–182 (2009)CrossRef Rosentsveig, R., Gorodnev, A., Feuerstein, N., Friedman, H., Zak, A., Fleischer, N., Tannous, J., Dassenoy, F., Tenne, R.: Fullerene-like MoS2 nanoparticles and their tribological behavior. Tribol. Lett. 36, 175–182 (2009)CrossRef
18.
go back to reference Rapoport, L., Nepomnyashchy, O., Verdyan, A., Popovitz-Biro, R., Volovik, Y., Ittah, B., Tenne, R.: Polymer nanocomposites with fullerene-like solid lubricant. Adv. Eng. Mater. 6, 44–48 (2004)CrossRef Rapoport, L., Nepomnyashchy, O., Verdyan, A., Popovitz-Biro, R., Volovik, Y., Ittah, B., Tenne, R.: Polymer nanocomposites with fullerene-like solid lubricant. Adv. Eng. Mater. 6, 44–48 (2004)CrossRef
19.
go back to reference Hu, K.H., Hu, X.G.: Formation, exfoliation and restacking of MoS2 nanostructures. Mater. Sci. Technol. 25, 407–414 (2009)CrossRef Hu, K.H., Hu, X.G.: Formation, exfoliation and restacking of MoS2 nanostructures. Mater. Sci. Technol. 25, 407–414 (2009)CrossRef
20.
go back to reference Hu, K.H., Wang, Y.R., Hu, X.G., Wo, H.Z.: Preparation and characterisation of ball-like MoS2 nanoparticles. Mater. Sci. Technol. 23, 242–246 (2007)CrossRef Hu, K.H., Wang, Y.R., Hu, X.G., Wo, H.Z.: Preparation and characterisation of ball-like MoS2 nanoparticles. Mater. Sci. Technol. 23, 242–246 (2007)CrossRef
21.
go back to reference Hu, K.H., Wang, J., Schraube, S., Xu, Y.F., Hu, X.G., Stengler, R.: Tribological properties of MoS2 nano-balls as filler in plastic layer of three-layer self-lubrication bearing materials. Wear 266, 1198–1207 (2009)CrossRef Hu, K.H., Wang, J., Schraube, S., Xu, Y.F., Hu, X.G., Stengler, R.: Tribological properties of MoS2 nano-balls as filler in plastic layer of three-layer self-lubrication bearing materials. Wear 266, 1198–1207 (2009)CrossRef
22.
go back to reference Hu, K.H., Hu, X.G., Sun, X.J.: Morphological effect of MoS2 nanoparticles on catalytic oxidation and vacuum lubrication. Appl. Surf. Sci. 256, 2517–2523 (2010)CrossRefADS Hu, K.H., Hu, X.G., Sun, X.J.: Morphological effect of MoS2 nanoparticles on catalytic oxidation and vacuum lubrication. Appl. Surf. Sci. 256, 2517–2523 (2010)CrossRefADS
23.
go back to reference Daage, M., Chianelli, R.R.: Structure-function relations in molybdenum sulfide catalysts: the “rim-edge” model. J. Catal. 149, 414–427 (1994)CrossRef Daage, M., Chianelli, R.R.: Structure-function relations in molybdenum sulfide catalysts: the “rim-edge” model. J. Catal. 149, 414–427 (1994)CrossRef
24.
go back to reference Rapoport, L., Bilik, Y., Feldman, Y., Homyonfer, M., Cohen, S.R., Tenne, R.: Hollow nanoparticles of WS2 as potential solid-state lubricants. Nature 387, 791–793 (1997)CrossRefADS Rapoport, L., Bilik, Y., Feldman, Y., Homyonfer, M., Cohen, S.R., Tenne, R.: Hollow nanoparticles of WS2 as potential solid-state lubricants. Nature 387, 791–793 (1997)CrossRefADS
25.
go back to reference Wang, T.M., Shao, X., Wang, Q.H., Liu, W.M.: Preparation and tribological behavior of polyimide MoS2 intercalation composite. Tribology 25, 322–327 (2005). (in Chinese) Wang, T.M., Shao, X., Wang, Q.H., Liu, W.M.: Preparation and tribological behavior of polyimide MoS2 intercalation composite. Tribology 25, 322–327 (2005). (in Chinese)
26.
go back to reference Hu, K.H., Hu, X.G., Xu, Y.F., Pan, X.Z.: The effect of morphology and size on the photocatalytic properties of MoS2. React. Kinet. Mech. Catal. 100, 153–163 (2010) Hu, K.H., Hu, X.G., Xu, Y.F., Pan, X.Z.: The effect of morphology and size on the photocatalytic properties of MoS2. React. Kinet. Mech. Catal. 100, 153–163 (2010)
27.
go back to reference Wang, W.Z., Huang, P.: Study on the lubrication state of frictional pairs with different surface roughness based on Stribeck curves. Tribology 24, 254–257 (2004). (in Chinese) Wang, W.Z., Huang, P.: Study on the lubrication state of frictional pairs with different surface roughness based on Stribeck curves. Tribology 24, 254–257 (2004). (in Chinese)
28.
go back to reference Li, H.Z., Zhang, X.H.: Study on the evaluation method of lubricating oils based on Stribeck curves. Lubr. Oil 24, 61–64 (2009). (in Chinese) Li, H.Z., Zhang, X.H.: Study on the evaluation method of lubricating oils based on Stribeck curves. Lubr. Oil 24, 61–64 (2009). (in Chinese)
Metadata
Title
The Effect of Morphology on the Tribological Properties of MoS2 in Liquid Paraffin
Authors
Kun Hong Hu
Xian Guo Hu
Yu Fu Xu
Fei Huang
Jun Sheng Liu
Publication date
01-10-2010
Publisher
Springer US
Published in
Tribology Letters / Issue 1/2010
Print ISSN: 1023-8883
Electronic ISSN: 1573-2711
DOI
https://doi.org/10.1007/s11249-010-9651-z

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