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Polymer Science, Series C
Published in: Polymer Science, Series C 2/2020

01-09-2020

The Effect of the Stabilization and Carbonization Temperatures on the Properties of Microporous Carbon Nanofiber Cathodes for Fuel Cells on Polybenzimidazole Membrane

Authors: K. M. Skupov, I. I. Ponomarev, Yu. M. Vol’fkovich, A. D. Modestov, Iv. I. Ponomarev, Yu. A. Volkova, D. Yu. Razorenov, V. E. Sosenkin

Published in: Polymer Science, Series C | Issue 2/2020

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Abstract

Materials based on pyrolyzed electrospun nanofiber polyacrylonitrile were studied by the method of standard contact porosimetry. An influence of oxidation and pyrolysis temperatures on specific surface area. It was shown that an increase of oxidation temperature from 300 to 350°C and of pyrolysis temperature from 900 to 1000°C leads to a decrease of pore specific surface area and to a decrease of a part of micropore specific surface area. Platinated samples showed sufficient values of electrochemically active platinum surface area (12‒35 m2 g\(_{{{\text{Pt}}}}^{{ - 1}}\)) and were tested as cathodes for high temperature polymer electrolyte membrane fuel cell. An increase in power density was found when a part of electrode micropore specific surface area was decreasing.
previous article Sulfonated Polyphenylquinoxalines: Synthesis, Thermal Stability, and Proton Conductivity
next article Highly Permeable Polyheteroarylenes for Membrane Gas Separation: Recent Trends in Chemical Structure Design

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Metadata
Title
The Effect of the Stabilization and Carbonization Temperatures on the Properties of Microporous Carbon Nanofiber Cathodes for Fuel Cells on Polybenzimidazole Membrane
Authors
K. M. Skupov
I. I. Ponomarev
Yu. M. Vol’fkovich
A. D. Modestov
Iv. I. Ponomarev
Yu. A. Volkova
D. Yu. Razorenov
V. E. Sosenkin
Publication date
01-09-2020
Publisher
Pleiades Publishing
Published in
Polymer Science, Series C / Issue 2/2020
Print ISSN: 1811-2382
Electronic ISSN: 1555-614X
DOI
https://doi.org/10.1134/S1811238220020149

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