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Journal of Materials Science

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18-02-2016 | Original Paper

Thermoelectric and mechanical properties of ZnSb/SiC nanocomposites

Authors: Funing Tseng, Siyang Li, Chaofeng Wu, Yu Pan, Liangliang Li

Published in: Journal of Materials Science | Issue 11/2016

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Abstract

Intermetallic compound ZnSb is a promising thermoelectric (TE) material with the advantages of low toxicity, abundance, and low cost; however, the relatively low figure of merit ZT and the brittleness of ZnSb limit its applications in TE devices. In this study, ZnSb/SiC nanocomposites were synthesized in order to improve both the TE and mechanical properties of ZnSb. ZnSb-based nanocomposites with x vol% SiC nanoparticles (x = 0, 0.3, 0.5, and 0.7) were prepared by mechanical alloying and spark plasma sintering. The power factor of ZnSb/SiC nanocomposite with 0.3 vol% SiC is increased. The thermal conductivity of all ZnSb/SiC nanocomposites is decreased due to the increase of interface scattering for phonons. More importantly, the fracture toughness of the nanocomposites is enhanced due to the addition of SiC. The largest ZT value and fracture toughness are found in the sample with 0.7 vol% SiC. The maximum ZT value of 0.68 is obtained at 400 °C, which is 35 % higher than that of the reference sample without SiC. The largest fracture toughness is 0.64 MPa m^1/2, which is 31 % larger than that of the reference sample. The experimental data demonstrate that ZnSb/SiC nanocomposites with simultaneous enhancement of TE and mechanical properties are favorable for practical TE applications.

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Wang H, Hwang J, Snedaker ML, Kim IH, Kang C, Kim J, Stucky GD, Bowers J, Kim W (2015) High thermoelectric performance of a heterogeneous PbTe nanocomposite. Chem Mater 27:944–949. doi:10.1021/cm5042138 CrossRef

Zhang Q, Ai X, Wang L, Chang Y, Luo W, Jiang W, Chen L (2015) Improved thermoelectric performance of silver nanoparticles-dispersed Bi₂Te₃ composites deriving from hierarchical two-phased heterostructure. Adv Funct Mater 25:966–976. doi:10.1002/adfm.201402663 CrossRef

He Y, Day T, Zhang T, Liu H, Shi X, Chen L, Snyder GJ (2014) High thermoelectric performance in non-toxic earth-abundant copper sulfide. Adv Mater 26:3974–3978. doi:10.1002/adma.201400515 CrossRef

Zhao LD, Lo SH, Zhang YS, Sun H, Tan GJ, Uher C, Wolverton C, Dravid VP, Kanatzidis MG (2014) Ultralow thermal conductivity and high thermoelectric figure of merit in SnSe crystals. Nature 508:373–377. doi:10.1038/nature13184 CrossRef

Poudel B, Hao Q, Ma Y, Lan YC, Minnich A, Yu B, Yan XA, Wang DZ, Muto A, Vashaee D, Chen XY, Liu JM, Dresselhaus MS, Chen G, Ren ZF (2008) High-thermoelectric performance of nanostructured bismuth antimony telluride bulk alloys. Science 320:634–638. doi:10.1126/science.1156446 CrossRef

Xiong D-B, Okamoto NL, Inui H (2013) Enhanced thermoelectric figure of merit in p-type Ag-doped ZnSb nanostructured with Ag₃Sb. Scr Mater 69:397–400. doi:10.1016/j.scriptamat.2013.05.029 CrossRef

Fedorov MI, Prokof’eva LV, Pshenay-Severin DA, Shabaldin AA, Konstantinov PP (2014) New interest in intermetallic compound ZnSb. J Electron Mater 43:2314–2319. doi:10.1007/s11664-014-3053-1 CrossRef

Valset K, Bottger PHM, Tafto J, Finstad TG (2012) Thermoelectric properties of Cu doped ZnSb containing Zn₃P₂ particles. J Appl Phys 111:023703. doi:10.1063/1.3675505 CrossRef

Sottmann J, Valset K, Karlsen OB, Tafto J (2013) Synthesis and measurement of the thermoelectric properties of multiphase composites: ZnSb matrix with Zn₄Sb₃, Zn₃P₂, and Cu₅Zn₈. J Electron Mater 42:1820–1826. doi:10.1007/s11664-012-2441-7 CrossRef

10.

Snyder GJ, Christensen M, Nishibori E, Caillat T, Iversen BB (2004) Disordered zinc in Zn₄Sb₃ with phonon-glass and electron-crystal thermoelectric properties. Nat Mater 3:458–463. doi:10.1038/nmat1154 CrossRef

11.

Caillat T, Fleurial J-P, Borshchevsky A (1997) Preparation and thermoelectric properties of semiconducting Zn₄Sb₃. J Phys Chem Solids 58:1119–1125. doi:10.1016/S0022-3697(96)00228-4 CrossRef

12.

Zhu GH, Liu WS, Lan YC, Joshi G, Wang H, Chen G, Ren ZF (2013) The effect of secondary phase on thermoelectric properties of Zn₄Sb₃ compound. Nano Energy 2:1172–1178. doi:10.1016/j.nanoen.2013.04.010 CrossRef

13.

Wang Q, Qin X, Li D, Zou T (2013) Enhancement of thermopower and thermoelectric performance through resonant distortion of electronic density of states of β-Zn₄Sb₃ doped with Sm. Appl Phys Lett 102:154101. doi:10.1063/1.4801851 CrossRef

14.

Li J-B, Record M-C, Tedenac J-C (2007) A thermodynamic assessment of the Sb–Zn system. J Alloys Compd 438:171–177. doi:10.1016/j.jallcom.2006.08.035 CrossRef

15.

Adjadj F, E-d Belbacha, Bouharkat M (2007) Differential calorimetric analysis of the binary system Sb–Zn. J Alloys Compd 430:85–91. doi:10.1016/j.jallcom.2006.04.051 CrossRef

16.

Mozharivskyj Y, Pecharsky AO, Bud’ko S, Miller GJ (2004) Promising thermoelectric material: Zn₄Sb₃ or Zn_6−δSb₅. Its composition, structure, stability, and polymorphs. Structure and stability of Zn_1-δSb. Chem Mater 16:1580–1589. doi:10.1021/cm035274a CrossRef

17.

Yin H, Christensen M, Pedersen B, Nishibori E, Aoyagi S, Iversen BB (2010) Thermal stability of thermoelectric Zn₄Sb₃. J Electron Mater 39:1957–1959. doi:10.1007/s11664-009-1053-3 CrossRef

18.

Yin H, Johnsen S, Borup KA, Kato K, Takata M, Iversen BB (2013) Highly enhanced thermal stability of Zn₄Sb₃ nanocomposites. Chem Commun 49:6540–6542. doi:10.1039/C3CC42340A CrossRef

19.

Zhang T, Zhou K, Li XF, Chen ZQ, Su XL, Tang XF (2016) Reversible structural transition in spark plasma-sintered thermoelectric Zn₄Sb₃. J Mater Sci 51:2041–2048. doi:10.1007/s10853-015-9514-y CrossRef

20.

Valset K, Song X, Finstad TG (2015) A study of transport properties in Cu and P doped ZnSb. J Appl Phys 117:045709. doi:10.1063/1.4906404 CrossRef

21.

Guo Q, Luo S (2015) Improved thermoelectric efficiency in p-type ZnSb through Zn deficiency. Funct Mater Lett 8:1550028. doi:10.1142/S1793604715500289 CrossRef

22.

Niedziolka K, Jund P (2015) Influence of the exchange-correlation functional on the electronic properties of ZnSb as a promising thermoelectric material. J Electron Mater 44:1540–1546. doi:10.1007/s11664-014-3459-9 CrossRef

23.

Song X, Valset K, Graff JS, Thogersen A, Gunnaes AE, Luxsacumar S, Lovvik OM, Snyder GJ, Finstad TG (2015) Nanostructuring of undoped ZnSb by cryo-milling. J Electron Mater 44:2578–2584. doi:10.1007/s11664-015-3708-6 CrossRef

24.

Ma JM, Firdosy SA, Kaner RB, Fleurial J-P, Ravi VA (2014) Hardness and fracture toughness of thermoelectric La_3−xTe₄. J Mater Sci 49:1150–1156. doi:10.1007/s10853-013-7794-7 CrossRef

25.

Akao T, Fujiwara Y, Tarui Y, Onda T, Chen Z-C (2014) Fabrication of Zn₄Sb₃ bulk thermoelectric materials reinforced with SiC whiskers. J Electron Mater 43:2047–2052. doi:10.1007/s11664-013-2946-8 CrossRef

26.

Liu DW, Li JF, Chen C, Zhang BP, Li L (2010) Fabrication and evaluation of microscale thermoelectric modules of Bi₂Te₃-based alloys. J Micromech Microeng 20:125031. doi:10.1088/0960-1317/20/12/125031 CrossRef

27.

Zhao LD, Zhang BP, Li JF, Zhou M, Liu WS, Liu J (2008) Thermoelectric and mechanical properties of nano-SiC-dispersed Bi₂Te₃ fabricated by mechanical alloying and spark plasma sintering. J Alloys Compd 455:259–264. doi:10.1016/j.jallcom.2007.01.015 CrossRef

28.

Schmidt RD, Fan XF, Case ED, Sarac PB (2015) Mechanical properties of Mg₂Si thermoelectric materials with the addition of 0–4 vol% silicon carbide nanoparticles (SiC_NP). J Mater Sci 50:4034–4046. doi:10.1007/s10853-015-8960-x CrossRef

29.

Schmidt RD, Case ED, Ni JE, Trejo RM, Lara-Curzio E, Korkosz RJ, Kanatzidis MG (2013) High-temperature elastic moduli of thermoelectric SnTe_1±x–ySiC nanoparticulate composites. J Mater Sci 48:8244–8258. doi:10.1007/s10853-013-7637-6 CrossRef

30.

Hicks L, Harman T, Sun X, Dresselhaus M (1996) Experimental study of the effect of quantum-well structures on the thermoelectric figure of merit. Phys Rev B 53:R10493–R10496. doi:10.1103/PhysRevB.53.R10493 CrossRef

31.

Venkatasubramanian R, Siivola E, Colpitts T, O’Quinn B (2001) Thin-film thermoelectric devices with high room-temperature figures of merit. Nature 413:597–602. doi:10.1038/35098012 CrossRef

32.

Hsu KF, Loo S, Guo F, Chen W, Dyck JS, Uher C, Hogan T, Polychroniadis EK, Kanatzidis MG (2004) Cubic AgPb_mSbTe_2+m: bulk thermoelectric materials with high figure of merit. Science 303:818–821. doi:10.1126/science.1092963 CrossRef

33.

Li JH, Tan Q, Li JF, Liu DW, Li F, Li ZY, Zou MM, Wang K (2013) BiSbTe-based nanocomposites with high ZT: the effect of SiC nanodispersion on thermoelectric properties. Adv Funct Mater 23:4317–4323. doi:10.1002/adfm.201300146 CrossRef

34.

Li ZY, Li JF, Zhao WY, Tan Q, Wei TR, Wu CF, Xing ZB (2014) PbTe-based thermoelectric nanocomposites with reduced thermal conductivity by SiC nanodispersion. Appl Phys Lett 104:113905. doi:10.1063/1.4869220 CrossRef

35.

Misra DK, Rajput A, Bhardwaj A, Chauhan NS, Singh S (2015) Enhanced power factor and reduced thermal conductivity of a half-Heusler derivative Ti₉Ni₇Sn₈: a bulk nanocomposite thermoelectric material. Appl Phys Lett 106:103901. doi:10.1063/1.4914504 CrossRef

36.

Dresselhaus MS, Gang Chen, Tang MY, Yang RG, Lee H, Wang DZ, Ren ZF, Fleurial JP, Gogna P (2007) New directions for low-dimensional thermoelectric materials. Adv Mater 19:1043–1053. doi:10.1002/adma.200600527 CrossRef

37.

Niihara K (1991) New design concept of structural ceramics—ceramic nanocomposites. J Ceram Soc Jpn 99:974–982. doi:10.2109/jcersj.99.974 CrossRef

38.

Wang L, Jiang W, Chen L (2004) Fabrication and characterization of nano-SiC particles reinforced TiC/SiC_nano composites. Mater Lett 58:1401–1404. doi:10.1016/j.matlet.2003.09.053 CrossRef

39.

Liu Q, Han W, Han J (2010) Influence of SiCnp content on the microstructure and mechanical properties of ZrB₂–SiC nanocomposite. Scr Mater 63:581–584. doi:10.1016/j.scriptamat.2010.06.005 CrossRef

40.

Duan B, Zhai P, Wen P, Zhang S, Liu L, Zhang Q (2012) Enhanced thermoelectric and mechanical properties of Te-substituted skutterudite via nano-TiN dispersion. Scr Mater 67:372–375. doi:10.1016/j.scriptamat.2012.05.028 CrossRef

41.

Anstis G, Chantikul P, Lawn BR, Marshall D (1981) A critical evaluation of indentation techniques for measuring fracture toughness: I, Direct crack measurements. J Am Ceram Soc 64:533–538. doi:10.1111/j.1151-2916.1981.tb10320.x CrossRef

42.

Hassan S, Gupta M (2007) Development of nano-Y₂O₃ containing magnesium nanocomposites using solidification processing. J Alloys Compd 429:176–183. doi:10.1016/j.jallcom.2006.04.033 CrossRef

43.

Wang D, De Cicco MP, Li X (2012) Using diluted master nanocomposites to achieve grain refinement and mechanical property enhancement in as-cast Al–9Mg. Mater Sci Eng A 532:396–400. doi:10.1016/j.msea.2011.11.002 CrossRef

44.

Augustine G, Hobgood M, Balakrishna V, Dunne G, Hopkins R (1997) Physical vapor transport growth and properties of SiC monocrystals of 4H polytype. Phys Status Solidi B 202:137–148. doi:10.1002/1521-3951(199707)202:1<137:AID-PSSB137>3.0.CO;2-Y CrossRef

45.

Goldsmid HJ (2009) Introduction to thermoelectricity. Springer, Heidelberg

46.

Minnich A, Dresselhaus M, Ren Z, Chen G (2009) Bulk nanostructured thermoelectric materials: current research and future prospects. Energy Environ Sci 2:466–479. doi:10.1039/b822664b CrossRef

47.

Böttger P, Pomrehn GS, Snyder GJ, Finstad TG (2011) Doping of p-type ZnSb: single parabolic band model and impurity band conduction. Phys Status Solidi A 208:2753–2759. doi:10.1002/pssa.201127211 CrossRef

48.

Pan Y, Wei T-R, Cao Q, Li J-F (2015) Mechanically enhanced p-and n-type Bi₂Te₃-based thermoelectric materials reprocessed from commercial ingots by ball milling and spark plasma sintering. Mater Sci Eng B 197:75–81. doi:10.1016/j.mseb.2015.03.011 CrossRef

49.

May AF, Toberer ES, Saramat A, Snyder GJ (2009) Characterization and analysis of thermoelectric transport in n-type Ba₈Ga_16−xGe_30+x. Phys Rev B 80:125205. doi:10.1103/PhysRevB.80.125205 CrossRef

50.

Kvetková L, Duszová A, Hvizdoš P, Dusza J, Kun P, Balázsi C (2012) Fracture toughness and toughening mechanisms in graphene platelet reinforced Si₃N₄ composites. Scr Mater 66:793–796. doi:10.1016/j.scriptamat.2012.02.009 CrossRef

51.

Awaji H, Choi S-M, Yagi E (2002) Mechanisms of toughening and strengthening in ceramic-based nanocomposites. Mech Mater 34:411–422. doi:10.1016/S0167-6636(02)00129-1 CrossRef

Title: Thermoelectric and mechanical properties of ZnSb/SiC nanocomposites
Authors: Funing Tseng
Siyang Li
Chaofeng Wu
Yu Pan
Liangliang Li
Publication date: 18-02-2016
Publisher: Springer US
Published in: Journal of Materials Science / Issue 11/2016
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-016-9830-x

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