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Topics in Catalysis
Published in: Topics in Catalysis 6-7/2009

01-06-2009 | Original Paper

Ti-Containing Silsesquioxane Gels with Tunable Porosity: Preparation and Catalytic Activity for the Epoxidation of Cyclooctene by Aqueous Hydrogen Peroxide

Authors: Kenji Wada, Kazuhiko Hirabayashi, Naoki Watanabe, Shingo Yamamoto, Teruyuki Kondo, Take-aki Mitsudo, Masashi Inoue

Published in: Topics in Catalysis | Issue 6-7/2009

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Abstract

Novel Ti-containing silsesquioxane gel catalysts were prepared by the hydrosilylative condensation of Ti-containing silsesquioxanes together with cubic silsesquioxanes and spherosilicates. The porosity of gels was controlled by changing the composition and the mixing order of the starting materials. Both porous and nonporous gels were found to act as excellent heterogeneous catalysts towards the selective epoxidation of cyclooctene by the use of aqueous hydrogen peroxide as an oxidant.
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Metadata
Title
Ti-Containing Silsesquioxane Gels with Tunable Porosity: Preparation and Catalytic Activity for the Epoxidation of Cyclooctene by Aqueous Hydrogen Peroxide
Authors
Kenji Wada
Kazuhiko Hirabayashi
Naoki Watanabe
Shingo Yamamoto
Teruyuki Kondo
Take-aki Mitsudo
Masashi Inoue
Publication date
01-06-2009
Publisher
Springer US
Published in
Topics in Catalysis / Issue 6-7/2009
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-009-9214-4

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