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2015 | Book Series

Topics in Organometallic Chemistry

Topics in Organometallic Chemistry

56 Volumes | 1998 - 2023

Description

Aims and Scope

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience.

The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published Online First with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.

More information about this series is available at https://www.springer.com/series/3418

OnlineFirst Chapters

Copper-Mediated Intermolecular C–H/C–H and C–H/N–H Couplings via Aromatic C–H Cleavage

Copper salts and complexes have recently received significant attention as less expensive and abundant alternatives to some noble transition metal catalysts such as palladium, rhodium, and ruthenium, in the research field of C–H activation. They not only replace the above precious metal catalysts in the known C–H transformations but also mediate unique, otherwise challenging, cross-coupling reactions involving C–H bond cleavage. This chapter mainly focuses on recent advances in the copper-mediated or copper-catalyzed intermolecular C–H/C–H and C–H/N–H aromatic couplings. Seminal mechanistic studies on the copper-mediated C–H functionalization are also discussed.

Catalytic C–H Bond Functionalization of Cyclopropane Derivatives

The present work describes a comprehensive review of the functionalization of cyclopropyl C–H bonds via transition-metal catalysis. Compared to the enormous number of publications related to direct sp

2

and sp

3

bond transformations in the last two decades, the first full account of direct cyclopropyl C(sp

3

)–H bond functionalization was only disclosed in 2011. Both intra- and intermolecular transformations are detailed in the review, including asymmetric reactions. In addition, mechanistic aspects of various Pd-catalyzed cyclopropane functionalizations are discussed.

Nickel-Catalyzed C–H Bond Functionalization Utilizing an N,N′-Bidentate Directing Group

This review discusses the use of nickel catalysts and

N

,

N

′-bidentate directing groups, such as 2-pyridinylmethylamine, 8-aminoquinoline, and derivatives thereof, which constitute a powerful combination for the chelation-assisted functionalization of C–H bonds.

Recent Developments in Pd-Catalyzed Direct Arylations of Heteroarenes with Aryl Halides

The direct arylation of heteroaromatic compounds with aryl halides using palladium catalysts has significantly been developed as an effective method for making (hetero)aryl-heteroaryl bonds, which are frequently found in biologically active compounds and functional materials. However, issues regarding costly reagents, regioselectivity, and harsh reaction conditions have to be solved to really compete with the classical transition metal-mediated cross-coupling procedures involving stoichiometric organometallic reagents. In this review, the most relevant developments aimed at solving these issues are summarized.

Applications of Catalytic Organometallic C(sp3)–H Bond Functionalization

The transition-metal-catalyzed activation of C(sp

3

)–H bonds has emerged as powerful strategy to create bonds and introduce functional groups in a direct fashion. This review focuses on recent applications of C(sp

3

)–H bond functionalization strategies to the synthesis of biologically active and natural compounds.

» alle OnlineFirst Kapitel

All books of the series Topics in Organometallic Chemistry

2023 | Book

Modes of Cooperative Effects in Dinuclear Complexes

This book presents recent advances in dinuclear complexes in which the metal-metal cooperative effect operates for obtaining substrate activation and high performance catalysts. Catalysis continues to be a fast expanding area to design efficient …

2023 | Book

C-C Cross Couplings with 3d Base Metal Catalysts

This volume presents recent progress on 3d base metal catalyzed C-C cross coupling reactions. The contributions provide detailed discussions on the use of cheap metal catalysts such as Cr, Mn, Fe, Co, Ni, Cu, and Zn to construct Csp2-Csp2 …

2023 | Book

Perspectives of Hydrosilylation Reactions

This volume describes the latest advances and perspectives in hydrosilylation, with a focus on new organometallic catalysts and their mechanistic aspects. Hydrosilylation is the reaction of ≡SiH with carbon-carbon, carbon-heteroatom or …

2021 | Book

Iridium Catalysts for Organic Reactions

This new volume “Iridium Catalysts for Organic Reactions” in the series “Topics in Organometallic Chemistry” intends to update several representative well-known reactions and to introduce other less known or new reactions in particular covering …

2021 | Book

Metal-Ligand Co-operativity
Catalysis and the Pincer-Metal Platform

This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer …

2020 | Book

New Directions in the Modeling of Organometallic Reactions

This book focuses on the computational modeling of organometallic reactivity. In recent years, computational methods, particularly those based on Density Functional Theory (DFT) have been fully incorporated into the toolbox of organometallic …

2020 | Book

Nanoparticles in Catalysis

This volume discusses the great potential of metal nanoparticle catalysts for complicated molecular synthesis and reviews the current progress of this field. The development of highly active and stable heterogeneous catalysts is a crucial subject …

2019 | Book

Organometallics for Green Catalysis

This volume presents the latest developments in the use of organometallic catalysis for the formation of bulk chemicals and the production of energy, via green processes including efficient utilization of waste feedstocks from industry. The …

2019 | Book

Organometallic Magnets

This volume highlights the recent advances and state of art in the experimental and theoretical studies of organometallic magnets. A plethora of organic ligands such as Mannich-base derivatives, redox-active chromophores, cyanides, Schiff base …

2019 | Book

Organometallics in Process Chemistry

This volume gives an overview of the applications of organometallic chemistry in process chemistry relevant to the current topics in synthetic chemistry. This volume starts with an introduction on the historical development of organometallics in …

2018 | Book

Rhodium Catalysis

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of …

2018 | Book

Chiral Lewis Acids

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of …

2016 | Book

Carbon Dioxide and Organometallics

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of or

2016 | Book

The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of or

2016 | Book

Organometallic Flow Chemistry

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of …

2016 | Book

Homo- and Heterobimetallic Complexes in Catalysis
Cooperative Catalysis

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of …

2016 | Book

C-H Bond Activation and Catalytic Functionalization I

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of …

2016 | Book

C-H Bond Activation and Catalytic Functionalization II

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of …

2016 | Book

Progress in Enantioselective Cu(I)-catalyzed Formation of Stereogenic Centers

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of …

2015 | Book

Organometallic Fluorine Chemistry

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of or

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