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2019 | OriginalPaper | Chapter

5. Upgrade Metallurgical Grade Silicon

Authors : Wen-hui Ma, Ji-Jun Wu, Kui-xian Wei, Yun Lei

Published in: Handbook of Photovoltaic Silicon

Publisher: Springer Berlin Heidelberg

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Abstract

Producing upgraded metallurgical-grade silicon may be the most promising method to replace the modified Siemens process to produce solar-grade silicon, which has many advantages such as no pollution and low cost in the production process. The main process is described in detail, including smelting and secondary refining of metallurgical-grade silicon and acid leaching treatment. Other technologies also are introduced and discussed: solvent refining, vacuum treatment, plasma refining, and electron beam treatment; these technologies are used to refine metallurgical-grade silicon. Purification is also very important in the production process; a solidification process is used in purification to obtain highly pure silicon.

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Literature
go back to reference S.R. Bharadwaj, A.S. Kerkar, S.N. Tripathi, et al., J. Chem. Thermodyn. 22, 453–461 (1990)CrossRef S.R. Bharadwaj, A.S. Kerkar, S.N. Tripathi, et al., J. Chem. Thermodyn. 22, 453–461 (1990)CrossRef
go back to reference Y. Dai, B. Yang (eds.), Nonferrous Metal Vacuum Metallurgy, 2nd edn. (Metallurgical Industry Press, Beijing, 2009) Y. Dai, B. Yang (eds.), Nonferrous Metal Vacuum Metallurgy, 2nd edn. (Metallurgical Industry Press, Beijing, 2009)
go back to reference R.H. Hopkins, A. Rohatgi, Impurity effects in silicon for high efficiency solar cells. J. Cryst. Growth 75, 67–79 (1986)CrossRef R.H. Hopkins, A. Rohatgi, Impurity effects in silicon for high efficiency solar cells. J. Cryst. Growth 75, 67–79 (1986)CrossRef
go back to reference L. Hu, Z. Wang, X. Gong, Z. Guo, H. Zhang, Purification of metallurgical-grade silicon by Sn–Si refining system with calcium addition. Sep. Purif. Technol. 118, 699–703 (2013)CrossRef L. Hu, Z. Wang, X. Gong, Z. Guo, H. Zhang, Purification of metallurgical-grade silicon by Sn–Si refining system with calcium addition. Sep. Purif. Technol. 118, 699–703 (2013)CrossRef
go back to reference J.M. Juneja, G.N.K. Iyengar, K.P. Abraham, J. Chem. Thermodyn. 18, 1025–1035 (1986)CrossRef J.M. Juneja, G.N.K. Iyengar, K.P. Abraham, J. Chem. Thermodyn. 18, 1025–1035 (1986)CrossRef
go back to reference O. Kubaschewski, C.B. Alcock, Metallurgical Thermochemistry, 5th edn. (Pergamon Press, Oxford, 1979) O. Kubaschewski, C.B. Alcock, Metallurgical Thermochemistry, 5th edn. (Pergamon Press, Oxford, 1979)
go back to reference O. Kubaschewski, C.B. Alcock, wrote. Z. Qiu, Y. Liang, X. Li, et al., trans. Metallurgical Thermochemistry (Metallurgical Industry Press, Beijing, 1985), pp. 486–513. O. Kubaschewski, C.B. Alcock, wrote. Z. Qiu, Y. Liang, X. Li, et al., trans. Metallurgical Thermochemistry (Metallurgical Industry Press, Beijing, 1985), pp. 486–513.
go back to reference Y. Lei, W. Ma, L. Sun, J. Wu, Y. Dai, K. Morita, Removal of B from Si by Hf addition during Al–Si solvent refining process. Sci. Technol. Adv. Mater. 17, 12–19 (2016)CrossRef Y. Lei, W. Ma, L. Sun, J. Wu, Y. Dai, K. Morita, Removal of B from Si by Hf addition during Al–Si solvent refining process. Sci. Technol. Adv. Mater. 17, 12–19 (2016)CrossRef
go back to reference Y. Liang, Y. Che (eds.), Inorganic Thermodynamics Data Sheet (Northeastern University Press, Shenyang, 1993) Y. Liang, Y. Che (eds.), Inorganic Thermodynamics Data Sheet (Northeastern University Press, Shenyang, 1993)
go back to reference N. Nakamura, H. Baba, Y. Sakaguchi, Y. Kato, Boron removal in molten silicon by a steam-added plasma melting method. Mater. Trans. 45(3), 858 (2004)CrossRef N. Nakamura, H. Baba, Y. Sakaguchi, Y. Kato, Boron removal in molten silicon by a steam-added plasma melting method. Mater. Trans. 45(3), 858 (2004)CrossRef
go back to reference A. Schei, H. Rong, A.G. Forwald, Impurity distribution in silicon (Silicon for Chemical Industry, Geiranger, 1992), pp. 16–18 A. Schei, H. Rong, A.G. Forwald, Impurity distribution in silicon (Silicon for Chemical Industry, Geiranger, 1992), pp. 16–18
go back to reference Y. Tan, X. Guo, S. Shi, W. Dong, D. Jiang, Study on the removal process of phosphorus from silicon by electron beam melting. Vacuum 93, 65–70 (2013)CrossRef Y. Tan, X. Guo, S. Shi, W. Dong, D. Jiang, Study on the removal process of phosphorus from silicon by electron beam melting. Vacuum 93, 65–70 (2013)CrossRef
go back to reference K. Tang, E.J. Øvrelid, G. Tranell, M. Tangstad, Thermochemical and kinetic databases for the solar cell silicon materials, in The Twelfth International Ferroalloys Congress, Sustainable Future, Helsinki, 6–9 June 2010 K. Tang, E.J. Øvrelid, G. Tranell, M. Tangstad, Thermochemical and kinetic databases for the solar cell silicon materials, in The Twelfth International Ferroalloys Congress, Sustainable Future, Helsinki, 6–9 June 2010
go back to reference K. Tang, S. Andersson, E. Nordstrand, M. Tangstad, Removal of boron in silicon by H2–H2O gas mixtures. J. Miner. Met. Mater. Soc. 64(8), 952–956 (2012)CrossRef K. Tang, S. Andersson, E. Nordstrand, M. Tangstad, Removal of boron in silicon by H2–H2O gas mixtures. J. Miner. Met. Mater. Soc. 64(8), 952–956 (2012)CrossRef
go back to reference K. Wei, W. Ma, B. Yang, D. Liu, Y. Dai, K. Morita, Study on volatilization rate of silicon in multicrystalline silicon preparation from metallurgical grade silicon. Vacuum 85, 749–754 (2011)CrossRef K. Wei, W. Ma, B. Yang, D. Liu, Y. Dai, K. Morita, Study on volatilization rate of silicon in multicrystalline silicon preparation from metallurgical grade silicon. Vacuum 85, 749–754 (2011)CrossRef
go back to reference J. Wu, Y. Li, W. Ma, K. Liu, K. Wei, K. Xie, B. Yang, Y. Dai, Impurities removal from metallurgical grade silicon using gas blowing refining techniques. Silicon 6, 79–85 (2014a)CrossRef J. Wu, Y. Li, W. Ma, K. Liu, K. Wei, K. Xie, B. Yang, Y. Dai, Impurities removal from metallurgical grade silicon using gas blowing refining techniques. Silicon 6, 79–85 (2014a)CrossRef
go back to reference S. Zhang (ed.), Vacuum Technology Physical Basis (Northeast Institute of Technology Press, Shenyang, 1988) S. Zhang (ed.), Vacuum Technology Physical Basis (Northeast Institute of Technology Press, Shenyang, 1988)
Metadata
Title
Upgrade Metallurgical Grade Silicon
Authors
Wen-hui Ma
Ji-Jun Wu
Kui-xian Wei
Yun Lei
Copyright Year
2019
Publisher
Springer Berlin Heidelberg
DOI
https://doi.org/10.1007/978-3-662-56472-1_7