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Journal of Materials Science
Published in: Journal of Materials Science 7/2019

11-12-2018 | Polymers

Vapor-based synthesis of bilayer anti-corrosion polymer coatings with excellent barrier property and superhydrophobicity

Authors: Ying Chen, Yumin Ye, Zhong-Ren Chen

Published in: Journal of Materials Science | Issue 7/2019

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Abstract

Bilayer polymer coatings that consisted of a highly cross-linked polyethylene glycol diacrylate (PEGDA) bottom layer and nanostructured poly(perfluorodecyl acrylate-co-ethylene glycol diacrylate) (P(PFDA-co-EGDA)) top layer were synthesized via a single-step vapor deposition method. The vapor-synthesized PEGDA single-layer film exhibits excellent barrier performance with oxygen permeability of 0.0066 Barrer, which is more than 16-fold smaller than that of commercial PET packaging film. The P(PFDA-co-EGDA) layer, grown on top of PEGDA, shows conical array structure. Such nanostructure combined with the low surface energy of PFDA moiety enables superhydrophobicity of the coating with water contact angle of 159°. The achieved superhydrophobicity is stable over more than 168 h upon immersion in NaCl solution. The bilayer coating structure imparts a synergistic effect to minimize both the diffusion of water and ions and permeation of oxygen, resulting in a significant drop of corrosion rate to 2.19 × 10−7 mm year−1, a more than 104-fold decrease compared to bare copper.
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Appendix
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Metadata
Title
Vapor-based synthesis of bilayer anti-corrosion polymer coatings with excellent barrier property and superhydrophobicity
Authors
Ying Chen
Yumin Ye
Zhong-Ren Chen
Publication date
11-12-2018
Publisher
Springer US
Published in
Journal of Materials Science / Issue 7/2019
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-03232-7

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